Control of Air Pollution From New and In-Use Motor Vehicles and New and In-Use Motor Vehicle Engines; Technical Amendments to the Test Procedures for Methanol-Fueled Motor Vehicles and Motor Vehicle Engines and Petroleum-Fueled Motor Vehicles; Final Rule

Federal RegisterJun 30, 1995

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SUMMARY: This rule changes the test procedures previously promulgated

for methanol-fueled vehicles (April 11, 1989). These revisions make

minor corrections to the procedures, provide additional options, and

clarify the Agency's regulatory intent. The changes are expected to

allow manufacturers more flexibility in complying with the applicable

regulations, without sacrificing accuracy of test results. This action

is a part of an ongoing cooperative interaction between Agency staff

and the affected automobile and engine manufacturers to develop the

most efficient test procedures possible for alternative fuels such as

methanol. Among the most significant changes are revisions to the

testing requirements for flexible fuel vehicles (FFVs), the allowance

of electronic mass flow controllers for methanol and formaldehyde

sample systems, the allowance of lower temperatures for some heated

components, establishment of wider tolerances for SHED and CVS

(Constant Volume Sampler) verifications, and specification of the fuel

to be used with all flame ionization detectors. It should be noted that

the revision related to flame ionization detectors affects all light-

duty vehicles, including gasoline-fueled vehicles.

In compliance with the Paperwork Reduction Act, this rule also

displays the Office of Management and Budget (OMB) control numbers

issued under the Paperwork Reduction Act (PRA) for the final rules

titled ``Emission Standards for Clean-fuel Vehicles and Engines,

Requirements for Clean-Fuel Vehicle Conversions, and California Pilot

Test Program'' and the ``Standards for Emissions from Natural Gas-

Fueled, and Liquified Petroleum Gas-Fueled Motor Vehicles and Motor

Vehicle Engines, and Certification Procedures for Aftermarket

Conversions''. Also included in this Final Rule are minor changes that

were proposed in the ``Gaseous-Fueled Vehicles'' and ``Clean Fuel

Fleets'' Notices of Proposed Rulemaking, but were not finalized in the

respective Final Rules.

EFFECTIVE DATE: This final rule is effective July 31, 1995, except the

amendments to part 9 are effective June 30, 1995.

Sections 85.503, 85.505, 86.094-23, 86.094-24, 86.095-35 86.098-28,

86.113-94, 86.142-90, 86.150-98, 86.513-94, 86.542-90, 86.1242-90,

86.1344-94 published at 59 FR 48472 and Sec. 600.113-93 published at 59

FR 39638 and 48472, containing information collection requirements

which have now been approved by OMB, are effective June 30, 1995.

Sections 88.104 (b) and (d), 88.201-94 through 88.206-94, and

88.306-94(b) (1),(2), and (4) published at 59 FR 50042, containing

information collection requirements which have been now approved by

OMB, are effective June 30, 1995.

ADDRESSES: Material relevant to this rulemaking is contained in the

Docket A-92-02. The docket is located at the Air Docket Section (LE-

131), U.S. Environmental Protection Agency, Room M-1500, 401 M Street

SW., Washington, DC 20460, and may be inspected between 8 a.m. and 3

p.m. Monday through Friday. Information may also be obtained from the

U.S. Environmental Protection Agency, Office of Mobile Sources,

Regulation Development and Support Division, Engine and Vehicle

Regulation Branch, 2565 Plymouth Road, Ann Arbor, MI 48105.

FOR FURTHER INFORMATION CONTACT: Charles Moulis, Regulation Development

and Support Division, U.S. Environmental Protection Agency, 2565

Plymouth Road, Ann Arbor, MI 48105. Telephone: (313) 741-7826

SUPPLEMENTARY INFORMATION:

Introduction

On April 11, 1989, EPA published final regulations which extended

the Federal Motor Vehicle Control Program to methanol-fueled vehicles

(54 FR 14427). Where possible, the regulations simply applied the

existing petroleum-fueled vehicle test procedures to methanol-fueled

vehicles. In some cases where that was not possible, it was necessary

to incorporate procedures that were more complicated than the

procedures used to test petroleum-fueled vehicles. Since that time,

several methanol-fueled vehicles have been certified. Overall, the

methanol-fueled vehicle test procedures have proven to be accurate and

reliable, though some minor issues have been raised.

On March 1, 1993, EPA published a Notice of Proposed Rulemaking

(NPRM) proposing several revisions to the test procedures that were

established for methanol-fueled vehicles in 1989 (58 FR 11816). This

rulemaking was initiated to address the minor issues which arose while

implementing the previously promulgated certification procedures for

methanol-fueled vehicles. Some of the issues require only a

clarification of the Agency's regulatory intent, while others require

changes to the test procedures specified in the CFR. The revisions

being promulgated today are essentially the same revisions that were

proposed, though some of proposed revisions are not being finalized.

Also, some of the revisions were modified slightly in response to

public comments on the proposal.

The test procedure changes being finalized today include both

changes to the existing procedures and allowances for different

procedures to be used in place of some of those procedures previously

required. The substantive changes are described below. However, the

reader is advised to read the actual regulatory language, which is also

printed here, for the complete changes.

Also included in this action are minor changes that were proposed

in the ``Gaseous-Fueled Vehicles'' (57 FR 52912, November 5, 1992) and

``Clean Fuel Fleets'' (58 FR 32474, June 10, 1993) Notices of Proposed

Rulemaking, but were omitted from the regulations of the respective

Final Rules. For details, see ``Issues'' 12 and 16

The following discussion is organized by issue. For each issue,

there are separate sections describing what was proposed, the public

comments and EPA's response to them, and a summary of the changes that

are actually being finalized by today's action.

Issues: Proposal, Public Comments, and Final Action

1. Test Fuels

Proposal

Manufacturers of methanol-fueled flexible fuel vehicles (FFVs) have

been required to comply with the methanol-fueled vehicle standards when

using any fuel mixture within the vehicle's design range. (FFVs are

vehicles that are designed to operate using a methanol fuel, gasoline

and all mixtures of the two). In order to ensure that such vehicles

meet the standards over the full range of fuel mixtures, the previous

regulations (e.g., 40 CFR 86.113) required that manufacturers submit

test data for worst case fuel mixtures. However, it became apparent

that implementation of such an approach is

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problematic, because the worst case fuel mixture may vary for the

various pollutants. Therefore, rather than attempting to identify a

single worst case fuel, the Agency proposed that manufacturers

demonstrate compliance by submitting test data for three fuel mixtures

during certification. The three proposed mixtures were: the methanol

fuel expected to be found in use, gasoline, and the highest volatility

mixture. The use of straight methanol fuel (e.g., M85 1) and

straight gasoline would demonstrate compliance at the two extremes of

operation. The high volatility mixture would ensure proper evaporative

emissions controls. This mixture was proposed to be approximately M10.

The Agency indicated that it would retain the right to perform its

confirmatory testing using any mixtures within the design range and to

continue to require compliance with the standards over the full range

as well.

\1\ Methanol fuels are commonly identified by their methanol

content using the abbreviation MXX, where XX is the volumetric

percent of the fuel which is methanol. M85, which is currently the

most common methanol fuel for light-duty vehicles, contains 85

percent methanol and 15 percent gasoline.

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For mileage accumulation of FFVs, the previous regulations also

required the use of the worst case fuel mixtures. For reasons similar

to those discussed above, the Agency proposed to allow manufacturers to

alternate between the methanol fuel (e.g., M85) and gasoline, at

mileage intervals not to exceed 5000 miles. The Agency also proposed

requiring that the total volume of the methanol fuel used for mileage

accumulation be at least 25 percent, but not more than 75 percent of

the total fuel volume used.

The original regulations specified that methanol test fuels be

representative of in-use fuels, did not include detailed specifications

of test fuel composition, as has been done for gasoline. This issue was

discussed in the NPRM, but no revisions to this requirement were

proposed.

Public Comments

The American Automobile Manufacturers Association (AAMA)

recommended that EPA not require manufacturers to use all three fuels

(gasoline, M10, and M85) to demonstrate compliance for each engine

family, when the manufacturers certify many methanol-fueled engine

families. They argued that the testing burden associated with using

three fuels for a large number of engine families would be too great.

Instead, AAMA recommended that EPA allow the manufacturers to certify

most methanol-fueled engine families using only M85, as long as they

tested one or two engine families using all three fuels. While the

Agency recognizes that the testing burden using three fuels can be

significantly more than using one fuel (as is the case with gasoline),

the Agency does not believe the AAMA recommendation is sufficient to

demonstrate compliance over the entire range of fuel mixtures for all

engine families. Compliance using M85 does not ensure compliance using

either gasoline, or M10; and compliance of one FFV engine family using

gasoline and M10 does not ensure compliance for all other FFV engine

families.

AAMA also disagreed with EPA's proposal to not adopt a permanent

and well defined methanol certification fuel specification. They stated

that ``it would become difficult, if not impossible, to demonstrate

compliance with all fuels if the fuel properties are allowed to drift

at random.'' The Agency, however, feels strongly that certification

fuel must be representative of in-use fuels. EPA recognizes that test

reproducibility is very important, and thus does not wish to have test

fuel properties varying randomly. The Agency will issue guidance as to

the fuel property specifications which define the representative

methanol fuel(s). The specifications will only change to the extent

that the fuel market as a whole changes, and EPA does not expect that

changes in the specifications will be significant from one year to the

next.

A related point that is worth clarifying pertains to the

possibility of EPA regulating in-use methanol fuels. While the Agency

recognizes that fuel properties such as chloride content (which effects

the corrosivity of the fuel), sulfur content (which can effect catalyst

efficiency), or vapor pressure (which can effect cold-starting) could

impact emissions, it has stated previously that it currently has no

plans to regulate commercial methanol fuels. This position has been

misinterpreted to mean that EPA has already decided that it will not

regulate commercial methanol fuels at any time in the future. However,

it is actually probable that EPA would regulate commercial methanol

fuels if it became apparent that in-use methanol fuel quality was

adversely affecting the environment. The Agency has no current plans to

regulate commercial methanol fuels because it is optimistic that

methanol fuel suppliers will voluntarily adopt industry-wide standards

that will make EPA regulation unnecessary.

Final Action

The Agency will still require that FFVs comply with the standards

when operating on any fuel mixture within the design range, but the

means by which this compliance is demonstrated is being changed. Rather

than attempting to identify a single worst case fuel, manufacturers

will now be required to demonstrate compliance by submitting test data

for three fuel mixtures during certification. These three mixtures are:

the methanol fuel expected to be found in use, gasoline, and the

highest volatility mixture. The highest volatility mixture will be M10

(more specifically, it will contain between nine and thirteen percent

methanol).

While the Agency will accept testing on the above fuels as an

adequate demonstration for certification, it should be emphasized that

the Agency will retain the right to perform its confirmatory testing

using any mixtures within the design range and will require compliance

with the standards over the full range as well.

For mileage accumulation of FFVs, EPA will require manufacturers to

alternate between the methanol fuel (e.g., M85) and gasoline, at

mileage intervals not to exceed 5000 miles. There is an additional

requirement that the total volume of the methanol fuel (e.g., M85) used

for mileage accumulation be at least 25 percent, but not more than 75

percent of the total fuel volume used. The Agency believes that these

requirements will be sufficient to demonstrate the durability of FFVs

in use, where the vehicles may be operated on only methanol, only

gasoline, or alternately on both fuels. EPA is not dictating which test

fuel mixtures should be used for the emissions tests performed to

determine deteriorations factors, but the Agency is currently

recommending that deterioration factors be determined for both the

alcohol fuel and the gasoline fuel.

Implicit in the rationale for the approach discussed above is the

assumption that there would be a reasonable possibility that a

significant number of in-use FFVs would be operated using both M85 and

gasoline. This assumption, however, would not necessarily be valid for

FFV models which had a very significant drop in performance when fueled

with gasoline. If the drop in performance were so drastic that the

vehicle became only marginally functional, then it would be very

unlikely that the vehicle operator would fuel the vehicle with gasoline

unless it were an emergency situation,

[[Page 34328]]

where the fuel tank was empty and no methanol fuel was available. Such

a vehicle is said to have only ``limp home'' capability when operated

with gasoline. The Agency recognizes that it would be reasonable for

these vehicles to be considered dedicated methanol-fueled vehicles for

the purposes of certification, and thus to be certified using only

methanol fuel (M85) for emissions testing and mileage accumulation. The

regulations have been modified to make this clear. Manufacturers should

obtain written approval to classify such vehicles as dedicated vehicles

from the Administrator prior to the start of testing. In determining

how to classify such vehicles, the Administrator would consider the

significance of the drop in performance using gasoline, the expected

availability of methanol fuel, and the expected vehicle use (i.e,

personal, taxi fleets, delivery vehicles, etc.). For example, a

methanol-fueled vehicle which lost 80 percent of its normal power when

using gasoline could be considered a dedicated vehicle; although, if

the vehicle was designed to be significantly overpowered, and still had

adequate acceleration with only 20 percent of its normal power, it

would not be considered a dedicated vehicle.

The regulations still do not specify methanol test fuels more

precisely than to require that the methanol test fuels be

representative of in-use fuels. The broad nature of this requirement is

the result of EPA's previous experience with gasoline. Because in-use

gasolines changed so significantly from the fuel used in certification,

especially in the area of vapor pressure, it became necessary for the

Agency to promulgate extensive regulations for in-use gasoline. The

Agency hopes that regulation of in-use methanol fuel quality will not

be necessary, and that industry-wide methanol fuel standards will be

adopted on a voluntary basis. Such standards would be accepted by EPA

as appropriate certification fuel standards, assuming that in-use fuels

consistently complied with the standards, since it would ensure that

the certification fuel is representative of in-use fuels. EPA

recognizes that, since the current market for methanol fuels is not

well defined, it is not possible at this time to determine one methanol

fuel that is truly representative of in-use fuels in all respects. For

previous certification of methanol-fueled vehicles, the Agency decided

that mixtures of chemical grade methanol and certification gasoline

were sufficiently representative to ensure that certification emissions

results would accurately reflect the behavior of in-use methanol-fueled

vehicles using market fuels. This approach is consistent with the

California Air Resources Board certification fuel specifications,

except that California's specification 2 does not require that the

methanol be chemical grade, and that it requires the use of

California's certification gasoline. Therefore, until such time that

the methanol fuel market is large enough to allow a better

determination of a representative fuel or until industry-wide standards

are adopted by fuel suppliers, the Agency will use, and require

manufacturers to use either a combination of chemical grade methanol

and certification gasoline in proportions that reflect the composition

of the intended in-use fuel, or California's certification methanol

fuel. For current M85-fueled vehicles this will be 84-88 percent (by

volume) methanol and the remainder gasoline. For M100-fueled vehicles,

the fuel will be neat chemical grade methanol, although it may contain

small amounts of fuel additives, provided that the manufacturer can

demonstrate that those same additives will be included in the in-use

fuel.

\2\ California Code of Regulations, Title 13, Section 2292.

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2. Methanol and Formaldehyde Sampling and Analysis

Proposal

The original regulations for methanol-fueled vehicles specified

separate sampling systems for methanol and formaldehyde. In the NPRM

for this action, the Agency proposed revisions in several areas related

to these requirements, although the most basic aspects of the

requirements remain unchanged. Under the proposed regulations, the

samples would still be collected by bubbling the sample gas through two

impingers, or, in the case of formaldehyde, through a cartridge

impregnated with dinitrophenylhydrazine (DNPH); and the impinger fluid

or cartridge would still be analyzed for methanol or formaldehyde using

chromatographic methods.

The most significant of the proposed changes affected the required

sampling flow rates. The previous regulations included minimum

requirements for flow rates through impingers and cartridges. They were

included to ensure that sufficient amounts of methanol and formaldehyde

are collected to allow for accurate detection by the chromatographic

instruments. Because there can be significant variations from system to

system, however, a single minimum flow rate is not appropriate for all

systems. To correct this, the Agency proposed to eliminate these

minimum flow rates, and to instead establish minimum concentrations for

the primary impingers and cartridges. More specifically, EPA proposed

that systems (and procedures) be required to be designed such that

testing of a vehicle or engine that emitted the maximum allowable level

of methanol, or emitted formaldehyde at a level that was ten percent of

the maximum emission level of methanol would result in analyte

concentrations that were 25 times higher than the levels of detection

for the instruments used. Systems that did not meet this requirement

due to high limits of detection were to be allowed, provided that the

resultant methanol concentration was greater than 25 mg/l, and the

resultant formaldehyde concentration is greater than 2.5 mg/l. For any

vehicles or engines that have an applicable formaldehyde standard, the

analyte concentrations used for design would be those that would result

from the maximum emission level allowed by that standard. The Agency

also proposed to add an additional design requirement that the amount

of methanol collected in the secondary impinger not be more than ten

percent of the total amount collected.

Another set of proposed revisions dealt with the method of flow

measurement. In several parts of the previous regulations, dry gas

meters were specifically required for sampling and calibration systems.

This was because dry gas meters were considered to be the most

appropriate type of flow meter for these applications at the time the

test procedures for methanol-fueled vehicles were originally developed.

It has became apparent, however, that these specifications were no

longer necessary. Therefore, the Agency proposed to allow other types

of flow meters to be used, provided that they meet an accuracy

specification of 2 percent.

Public Comments

The comments received regarding methanol and formaldehyde sampling

and analysis were generally supportive of the Agency's proposals. Some

of the comments, however, requested clarification of regulatory

language. In response, EPA has modified the regulatory language

regarding the design requirements for sample flow rates, the use of

secondary impingers and cartridges, and the accuracy specifications for

sample flow meters.

[[Page 34329]]

Final Action

Sampling systems (and procedures) will be required to be designed

such that testing of a vehicle or engine that emitted the maximum

allowable level of methanol (e.g., 0.95 g/mi methanol, or 14 g/FTP, for

a 0.41 g/mi THCE 3 standard), or emitted formaldehyde at a level

that was twenty percent of the maximum emission level of the lowest

applicable THCE or NMHCE (e.g., 0.082 g/mi formaldehyde, or 1.2 g/FTP,

for a 0.41 THCE standard) during the first phase of the test would

result in analyte concentrations that were at least 25 times higher

than the levels of detection for the instruments used. As proposed,

systems that do not meet this requirement due to high limits of

detection will be allowed, provided that the resultant methanol

concentration is greater than 25 mg/l, and the resultant formaldehyde

concentration is greater than 2.5 mg/l. For any vehicles or engines

that have an applicable formaldehyde standard, the analyte

concentrations used for design would be those that would result from

the maximum emission level allowed by that standard. The Agency is also

requiring that the amount of methanol collected in the secondary

impinger not be more than ten percent of the total amount collected.

\3\ THCE and NMHCE are replacing OMHCE and OMNMHCE; see

discussion in ``15. Other Issues.''

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Also, the Agency will allow other types of flow meters to be used,

provided that they meet the accuracy specifications of Secs. 86.120-90

or 86.1320-90. The specifications of these sections require accuracy of

1 percent of the maximum operating range and 2

percent of the reading.

3. Proportional Sampling

Proposal

Prior to this action, there were only two methods allowed by the

regulations for obtaining proportional samples when testing light-duty

vehicles: the Positive Displacement Pump-Constant Volume Sampler (PDP-

CVS) method and the Critical Flow Venturi-Constant Volume Sampler (CFV-

CVS) method. However, EPA proposed a third option for methanol-fueled

vehicles. This method is based on the current CFV-CVS system, but

allows proportional sampling of methanol and formaldehyde to be

maintained by electronically monitoring the CVS flow rate and

electronically controlling the sample flows. Similar approaches have

been used for some years in heavy-duty diesel testing and in light-duty

research testing. When using this approach, the ratio of sample flow to

CVS flow was to be required to remain within 5 percent of

the set-point ratio.

Public Comments

AAMA supported the Agency's proposals, and added that flow

controllers should vary the sample flow rate inversely with the square

root of the bulk stream temperature. EPA agrees, and has added such

language to the regulations.

Final Action

EPA is finalizing this revision as proposed. The Agency is not

requiring that these electronically-controlled sampling systems also

include separate flow meters to measure total sample volumes, but will

allow them. It should be emphasized that even though this option is

only being specified for methanol and formaldehyde sampling systems,

the Agency would consider allowing similar approaches for other samples

as equivalent procedures. (For example, paragraph (a)(5) of

Sec. 86.109-94 specifically allows the use of sampling procedures other

than those specified in that section, provided that they can be shown

to ``yield equivalent or superior results''.)

4. Prevention of Condensation

Proposal

Exhaust from methanol-fueled vehicles generally has much higher

water vapor content than conventional vehicles, which can lead to water

condensation under certain testing conditions, when the gas comes into

contact with surfaces at temperatures below its dew point. Such

condensation can create very significant problems with respect to

testing accuracy, since both methanol and formaldehyde are soluble in

water. However, if the gas comes into contact with very hot surfaces,

the methanol can undergo decomposition reactions. For these reasons, in

the previous rulemaking, EPA required that sample lines and transfer

systems be heated to 23515 deg.F (as measured at the

surface in contact with the raw and diluted exhaust gases). Some

manufacturers, however, have indicated a concern that this temperature

requirement may be too high for their systems. The Agency proposed to

change its regulatory focus from specifying the temperature

requirement, toward allowing manufacturers to determine the most

appropriate temperatures for their own individual systems. The

requirements to heat many of the components remained, but EPA proposed

changing the lower limit to the maximum dew point of the exhaust

mixture. Comments were requested on whether it will be necessary to

measure dew point continuously for each test.

It had also been suggested that heavy-duty engine manufacturers

should be allowed to use ducts up to 32 feet in length to transfer the

exhaust from the engine to the dilution tunnel. Testing by Southwest

Research Institute (SwRI) showed no significant difference between the

emission results from test systems using ducts 13 and 32 feet in

length.4 Therefore, the Agency proposed to allow transfer ducts up

to 32 feet in length (as is currently allowed for petroleum-fueled

engines). However, since the SwRI testing did not provide data for

systems in which the duct temperature exceeded 315 deg.C, this

allowance required that the maximum duct temperature not exceed 315

deg.C.

\4\ ``Effect of Exhaust Pipe Length on Emissions From a Heavy-

Duty Methanol Engine,'' SwRI-4962, May 1992, Docket Item A-92-02-II-

D-7.

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EPA also proposed allowing heating and dehumidifying the dilution

air, with some restrictions. The proposed restrictions limited the

maximum temperature and affect how the dilution air flow rate is

calculated.

Public Comments

The comments received regarding the prevention of condensation were

generally supportive of the Agency's proposals. AAMA stated that, based

on their testing experience, measurement of the dew point is not

necessary, provided that dilution systems are designed properly. EPA

agrees that continuous measurement of the dew point is not necessary,

and thus will also allow the absence of condensation to be demonstrated

through engineering analyses.

Detroit Diesel Corporation (DDC) supported EPA's proposal to allow

longer unheated exhaust transfer ducts for heavy-duty engines, but

requested that the Agency raise the maximum temperature from 315 deg.C

(as proposed) to 350 deg.C. Further, they indicated that they believed

that a limit on the average temperature of the duct would be more

appropriate than a limit on the maximum temperature.

EPA recognizes that the 315 deg.C limit was based on testing of

only one engine, and that other larger engines could easily result in

higher temperatures of the duct. However, the Agency does not consider

it to be unreasonable to expect manufacturers to make the slight

modifications to the duct that would be necessary to prevent the

maximum duct temperature from exceeding 315 deg.C. Simple

modifications such as the

[[Page 34330]]

addition of fins, or the use of cooling fans, should be able to

increase the heat transfer away from the duct sufficiently to allow the

systems to comply with this requirement even when testing larger

engines. The Agency also does not agree that a limit on the average

temperature would be more appropriate. While it is true that

controlling the average temperature would account for the length of

time that the exhaust is exposed to the higher temperatures, it would

allow the exhaust to be exposed to very high temperatures. Therefore,

EPA has decided that a limit on the maximum temperature is appropriate

at this time, especially given the increased complexity of determining

the average temperature of the duct instead of only the maximum

temperature.

Final Action

The Agency has changed its regulatory focus from specifying the

temperature requirement, to allowing manufacturers to determine the

most appropriate temperatures for their own individual systems.

However, EPA is establishing a lower limit of 5 deg.F above the

maximum dew point of the exhaust mixture, instead of the maximum dew

point as was proposed. The previously established maximum upper

temperature of 250 deg.F remains in effect. Although these limits

provide slightly less additional flexibility than was proposed, the

Agency believes that they allow for a sufficiently wide range of

temperatures. This revision is not intended to imply that the Agency no

longer believes that the appropriate temperature range for most systems

is 220-250 deg.F, but rather it is intended only to allow the

manufacturers more flexibility. Manufacturers must demonstrate that

their systems will prevent condensation from occurring, and will be

allowed to do so using engineering analyses, such as dew point data

from testing under some worst case conditions (e.g., with a large

engine during a period of high ambient humidity).

EPA is also revising the regulations to allow heavy-duty engine

manufacturers to use longer unheated ducts to transfer the exhaust from

the engine to the dilution tunnel. The Agency will allow transfer ducts

up to 32 feet in length, but will require that the maximum duct

temperature not exceed 315 deg.C. EPA recommends that steps be taken

to minimize the temperature increase in the transfer duct to reduce the

possibility of the methanol and formaldehyde reacting on the walls of

the transfer duct.

Today's rule also specifically allows heating and dehumidifying the

dilution air, with some minor restrictions. Allowing such pretreatment

of the dilution air may help to eliminate some of the condensation

problems associated with methanol-fueled vehicles, and may allow the

use of lower system temperatures as discussed above. The restrictions

limit the maximum temperature and affect how the dilution air flow rate

is calculated.

5. CVS and SHED Calibration and Retention Tests

Proposal

The regulations promulgated in 1989 required that, in addition to

tests previously required for propane, tests also be perfomed to ensure

that there are no losses of methanol in the CVS or SHED. The

regulations specified injecting a known quantity of methanol or propane

into the CVS or SHED, collecting a sample and comparing the amount

calculated from the measured value to the amount injected. The

regulations required, for methanol, that the measured value be within

two percent of injected value. However, actual testing experience by

both EPA and industry has shown that consistently obtaining results

within two percent can be problematic given the current state of

development of methanol test procedures. Therefore, EPA proposed to

establish wider limits (6 percent) for methanol recoveries

during the calendar years 1992-1995. For SHED testing, these wider

limits were to apply to both agreement between the amount injected and

the initial measured amounts (recovery tests) and between the initial

and final (after four hours) measured amounts (retention tests). EPA

requested comments regarding whether it was sufficient to widen the

tolerances through 1995, or if a longer period were required.

The Agency also proposed to require the use of a correction factor

that would be derived from the four-hour retention test. This was to be

a means of accounting for potential losses without increasing the

testing burden.

Public Comments

AAMA supported permanently widening the tolerances for CVS and SHED

recovery and retention tests for methanol to 6 percent.

They stated in their comments that they ``do not believe that a 2

percent limit will be achievable in the near future.'' EPA recognizes

that, at this time, complying with a 2 percent tolerance is not

possible without an unreasonable test burden. This is due in large part

to the imprecision of the GC analysis, which AAMA estimated at

5 percent. This imprecision could be reduced by performing

multiple GC analyses, although this would lead to a significant

increase in costs. When the vehicles are tested for compliance with a

carbon equivalence-based standard, however, the accuracy of the

methanol measurement becomes less important. Since the test procedure

determines the emissions of non-oxygenated HC by subtracting the

methanol FID response from the total FID response, an undermeasurement

of methanol will lead to an overmeasurement of HC, and vice versa. Thus

the net impact of the accuracy of the methanol measurement on the

accuracy of the calculated THCE emission rate is reduced. However, EPA

continues to believe that the 2 percent tolerance will ultimately be

achievable, and that this level of accuracy is appropriate. Therefore,

the Agency will maintain this specification, but will allow

manufacturers to request a waiver from the required 2 percent tolerance

after 1995, as described below.

AAMA opposed the use of correction factors for SHED testing. They

argued that correction factors are not necessary, and would be

``inconsistent with previous test requirements.'' EPA recognizes AAMA's

concerns. More importantly, however, the Agency believes that the

potential for losses can be addressed under the waiver provisions being

established today (see Final Action section below). Therefore, EPA is

not finalizing the proposed correction factor requirements.

Final Action

EPA is establishing a wider tolerance of 6 percent for

methanol recovery and retention during the calendar years 1992-1995, as

was proposed. After 1995, the Agency will allow manufacturers to

request a waiver from the required tolerance (e.g., 2

percent), provided that:

(1) The Administrator determines that compliance with the specified

tolerance is not practically feasible, and

(2) The manufacturer makes information available to the

Administrator which indicates that the calibration tests and their

results are consistent with good laboratory practice, and that the

results are consistent with the results of calibration testing

conducted by the Administrator, and

(3) The manufacturer complies with higher tolerances (up to

6 percent for recoveries and 8 for retention),

as specified by the Administrator.

In deciding whether to grant the waiver, and what the tolerances

should be under the waiver, EPA will be

[[Page 34331]]

concerned primarily with the degree to which any imprecision and

inaccuracy in the methanol sampling and measurement techniques would

affect its ability to determine compliance with emission standards.

More specifically, this means that the precision (repeatability) of

methanol measurements should be as good as is practically feasible, and

that there should be no losses in the system that would lead to a

significant undermeasurement of methanol. The determination of

practical feasibility will depend on the degree to which variability

can be reduced and the costs associated with the reduction. EPA

recognizes that the standard for precision that is ``consistent with

good laboratory practice'' will change with time, and will use its own

testing as the standard. That means that manufacturers will be required

to have precision that, in the Administrator's judgement, is

essentially as good as that of EPA.

6. Fuels for Flame Ionization Detectors

Proposal

Flame ionization detectors measure hydrocarbons and other organics

by ionizing the carbon atoms with a supplemental fuel source. At one

time, the primary fuel was a mixture of hydrogen in nitrogen (H2/

N2), but now the more commonly used fuel is a mixture of hydrogen

in helium (H2/He), which is thought to give a more accurate

response. In the previous regulations, it was somewhat unclear what

type of fuels were to be used with the heated flame ionization

detectors (heated FID or HFID) required for methanol-fueled vehicle

testing. Evaporative emissions testing and heavy-duty exhaust testing

required the use of H2/He, while the fuel for light-duty exhaust

testing was previously unspecified. Since the light-duty fuel was

unspecified, many testing facilities have used a mixture of hydrogen in

nitrogen. To eliminate this confusion, the Agency proposed to clearly

require that H2/He fuel be used for all FIDs when testing

methanol-fueled vehicles. Moreover, to provide consistent testing of

both alternatively-fueled and conventionally-fueled vehicles, the

Agency proposed to require the use of H2/He fuel for all heated

and unheated FIDs. The Agency also requested comments on whether

revisions are needed to the FID calibration procedure as outlined in

the CFR.

Public Comments

AAMA agreed with EPA's proposal to require that hydrogen/helium

mixtures be used as the fuel for all flame ionization detectors (FIDs).

AAMA also recommended that EPA add a requirement to optimize the FID to

make the response of methane (relative to propane) as close to one as

possible. The Agency agrees that optimizing the FID to reduce

variations in response factors is good engineering practice. However,

EPA has not seen evidence that FIDs are currently being improperly

calibrated, and thus does not believe that it is necessary to include

such a provision in the regulations at this time. EPA will continue to

consider this issue, and may propose further specifications for the

calibration of FIDs at a later time.

Final Action

EPA is finalizing this revision as proposed, and will require the

use of H2/He fuel for all heated and unheated FIDs.

7. Background Measurements

Proposal

The test procedures call for measurement of background

concentrations of various gases, including methanol and formaldehyde,

to be subtracted from the concentrations measured in the diluted

exhaust. Previously, only a single sample was required for

formaldehyde, while separate phase-by-phase samples were required for

methanol. However, for the purpose of consistency, EPA proposed to also

require only a single sample be collected to determine the methanol

concentration in the dilution air. It was also noted that, since

methanol levels in the dilution air will generally be very low, a

single impinger is sufficient to measure the methanol concentration in

the sample.

Public Comments

The comments received regarding the background measurements were

generally supportive of the Agency's proposals. DDC requested that EPA

clearly state in the regulations that background measurements are

optional for manufacturers. EPA agrees, and has added such language.

Final Action

EPA is finalizing this revision as proposed, and is also adding

regulatory language that states that background measurements are

optional for manufacturers.

8. Determination of Fuel Composition

Proposal

The regulations previously did not specify a procedure to determine

the carbon:hydrogen:oxygen ratio for methanol fuels and fuel mixtures,

other than to state that the ratio was to be measured. However, if the

methanol fuel and/or fuel mixtures are made from fuels for which the

ratios are known (such as chemical grade methanol and Indolene), then

the ratio for the resultant mixture can be calculated and no

measurement is necessary. EPA proposed to revise the regulations to

allow for calculation of the ratio for methanol fuels and fuel

mixtures.

Public Comments

The comments received regarding the determination of fuel

composition were supportive of the Agency's proposals.

Final Action

EPA is finalizing this revision as proposed.

9. NOX Humidity Correction Factor

Proposal

The humidity of the air in a test area is known to have an effect

on emissions of NOX, and EPA has established a correction factor

for NOX test results. It became apparent that the correction

factor established for heavy-duty methanol-fueled engines is erroneous.

EPA proposed to correct this by applying the correction factor

currently specified for gasoline-fueled engines to Otto-cycle methanol-

fueled engines, and the one currently specified for petroleum-fueled

diesel engines to methanol-fueled diesel engines, as was originally

intended.

Public Comments

EPA received no comments regarding this issue.

Final Action

EPA is finalizing this revision as proposed.

10. Heated Flame Ionization Detectors

Proposal

The regulations previously required that heated FIDs (HFIDs) be

used when testing methanol-fueled vehicles. The reason for this

requirement was that HFIDs provide a stable response for methanol more

quickly than unheated FIDs. Some manufacturers have suggested, however,

that in many cases the HFID is not necessary and that an unheated FID

is adequate. EPA proposed to allow unheated FIDs to be used in place of

heated FIDs for methanol-fueled vehicle testing.

Public Comments

The Agency received mixed comments in response to this proposed

revision. AAMA supported the use of

[[Page 34332]]

unheated FIDs for methanol-fueled vehicle testing, though they

indicated that they believe that it would be appropriate to require

that each test lab provide data to demonstrate equivalence between

their unheated FID and a heated FID, for their exhaust systems. The New

York State Department of Environmental Conservation (NYDEC) commented

that aromatic organics and large aliphatics can be lost to unheated

surfaces in sampling systems. They recommended that heated FIDs should

be used not only for testing methanol-fueled vehicles, but for testing

petroleum-fueled vehicles as well. Based on these comments, and data

from EPA testing (see Docket A-92-02), it is clear that unheated FIDs

can be used for methanol testing in some systems, but that there is the

potential for measurement problems in other systems. EPA will allow

unheated FIDs to be used in place of heated FIDs for evaporative

testing of methanol-fueled vehicles. The Agency will also allow the use

of unheated FIDs for exhaust testing, where there appears to be a

greater potential for measurement problems, but only after the

manufacturer demonstrates equivalence with the heated FID for its

system. EPA did not propose requiring heated FIDs for gasoline-fueled

vehicle testing and has not yet received sufficient information that it

is necessary.

Final Action

EPA will allow unheated FIDs to be used in place of heated FIDs for

evaporative testing of methanol-fueled vehicle testing. The Agency will

also allow the use of unheated FIDs for exhaust testing, provided that

the manufacturer can demonstrate equivalence with the heated FID for

its system.

11. Gaseous Standards for Methanol and Formaldehyde

Proposal

Gaseous standards of many gases have been specified in the

regulations and have been routinely used in calibration procedures;

however, such standards were not allowed for methanol and formaldehyde.

EPA proposed to allow the use of gaseous methanol standards for

response factor calculation, with the requirement that the

concentration of methanol in the standard gas not vary by more than two

percent over its useful lifetime (i.e., from the time it is prepared

until it is no longer used for testing).

Public Comments

AAMA supported EPA's proposal to allow the use of gaseous methanol

standards for the determination of the FID response to methanol.

However, they suggested that EPA widen the tolerance for stability to

4 percent (instead of 2 percent) to account for

variability in the measurement of methanol. They also suggested that

EPA allow bottles that exceed this tolerance to be renamed with the new

concentration. The Agency recognizes that the variability associated

with measuring methanol makes it possible that the measured

concentration of methanol could be outside the 2 percent

tolerance, even though the true concentration had not changed by more

than 2 percent. Therefore, EPA has added regulatory language that

clarifies that the 2 percent tolerance is for a reasonable

estimate of the true concentration, taking into account measurement

variability, not necessarily a single measurement. The Agency envisions

that manufacturers will use an average of multiple measurements to

determine the concentration, and will make enough measurements so that

the precision of the estimate is 2 percent. Also, EPA

agrees that standards that change by more than 2 percent can be renamed

with the new concentration, provided that the change is not greater

than 10 percent.

Final Action

EPA will allow the use of gaseous methanol standards for response

factor calculation, with the requirement that the concentration of

methanol in the standard gas shall not vary by more than two percent,

without being relabeled with the new concentration.

12. Idle CO Testing

Proposal

In the 1989 FRM, EPA established idle CO emission standards for all

methanol-fueled light-duty trucks and heavy-duty engines, including

heavy-duty diesel engines. In the NPRM for this current rulemaking, EPA

proposed to modify the testing provisions to allow for continuous

analysis instead of bag sampling and analysis. This was done to be

consistent with Sec. 86.1310, which allows continuous CO analysis for

transient testing of diesel cycle engines.

Public Comments

EPA received no comments regarding this issue.

Final Action

EPA is finalizing this revision as proposed.

In a related matter, EPA is correcting Secs. 86.094-9 and 86.097-9

to clarify that the idle CO standards of those sections are applicable

to gasoline-fueled, methanol-fueled, LPG-fueled and CNG-fueled light-

duty trucks. The applicability of these standards to LPG-fueled and

CNG-fueled light-duty trucks was specified in the Preamble of the FRM

which established standards and test procedures for gaseous-fueled

vehicles ( FR ), but the regulatory text of these sections was not

revised to reflect this requirement.

13. Direct Measurement of Non-Oxygenated Hydrocarbons

Proposal

Evaporative non-oxygenated hydrocarbon emissions from methanol-

fueled vehicles have been measured by separately measuring total

organic emissions and methanol emissions: the non-oxygenated

hydrocarbon emissions are the difference between these two

measurements. It had been suggested, however, that non-oxygenated

hydrocarbons can be measured directly by installing water-filled

impingers upstream of an FID calibrated on propane. The impingers would

be expected to remove the methanol from the gas as it is bubbled

through the water, but not the non-oxygenated hydrocarbons. The Agency

proposed to revise the regulations to allow this option.

Public Comments

The comments received indicate that the technique which was

proposed to measure non-oxygenated HC directly for methanol-fueled

vehicles is not sufficiently accurate at this time.

Final Action

EPA is not finalizing this option in this action.

14. FID Measurement of Methanol Emissions From M100 Vehicles

Proposal

Methanol emissions from M100 vehicles have been measured with an

impinger system. The combined emissions of methanol and non-oxygenated

HC have been measured by a FID and the non-oxygenated HC emissions have

been determined by subtracting the methanol (after correcting for FID

response) from the total. However, when the non-oxygenated HC emissions

are small, there is a significant potential for errors. Because the

amount of non-oxygenated HC emissions from M100 vehicles and engines is

generally small, EPA proposed to allow measurement of the

[[Page 34333]]

total emissions with an FID calibrated on methanol, as has already been

allowed through model year 1994.

Public Comments

AAMA supported this option to some extent, but felt that EPA should

not use this option for its testing. At this time, EPA believes that

the available information is not sufficient to support continuation of

this option beyond the 1994 model year.

Final Action

EPA is not finalizing this option in this action.

15. Collection of Methanol Samples

As noted above, methanol samples have been collected using

impingers. EPA also proposed, however, allowing two alternative

methods. The first was the allowance to measure methanol concentrations

from SHED testing by direct GC analysis of the bag samples. The second

alternative was the allowance of the use of cartridges, which are

designed to collect methanol, for both exhaust and evaporative testing.

Public Comments

The comments received regarding the measurement of methanol by GC-

bag analysis or from methanol cartridges do not support either of the

proposed approaches at this time.

Final Action

EPA is not finalizing either approach in this action.

16. Other Issues

AAMA indicated that the tolerance of 0.5 percent for

the liquid methanol injection device used during CVS and SHED

calibration may not be achievable at this time. EPA agrees, especially

since manufacturers will still be required to comply with the recovery

and retention tolerances specified by the Administrator. Thus, the

Agency is allowing less precise methods to be used. This change will

not effect the accuracy or precision of certification emissions tests.

AAMA requested that the Agency require the determination of the FID

response to methanol only twice annually, instead of monthly. However,

EPA believes that the response factor should be calculated each time

the FID is recalibrated, on a monthly basis.

EPA is replacing the terms ``Organic Material Hydrocarbon

Equivalent'' (OMHCE) and ``Organic Material Non-Methane Hydrocarbon

Equivalent'' (OMNMHCE) with ``Total Hydrocarbon Equivalent'' (THCE) and

``Non-Methane Hydrocarbon Equivalent'' (NMHCE). These new terms are

simpler and are more obviously related to the comparable terms being

used for petroleum-fueled vehicles (THC and NMHC). This change does not

have any substantive effect on the certification process.

Finally, included among the regulatory revisions in this FRM are

minor changes that allow the test procedures specified for measuring

formaldehyde from methanol-fueled heavy-duty engines to be used to

measure formaldehyde from other types of engines. These changes were

originally proposed in the ``Clean Fueled Fleets'' NPRM (58 FR 32474,

June 10, 1993), but were not finalized. The purpose of the changes is

to provide a means of measuring formaldehyde from non-methanol fueled

heavy-duty ULEV engines that have to comply with a separate

formaldehyde standard. In general, the changes are nothing more than

removing references such as ``for methanol-fueled engines'' that are

associated with the formaldehyde measurement procedures, and replacing

those references with ``as applicable.''

OMB Approval of Information Collection Requirements for CFV Emission

Standards and Gaseous Fuels Rulemakings

EPA is also amending the table of currently approved information

collection request (ICR) control numbers issued by OMB for various

regulations. Today's amendment updates the table to accurately display

those information requirements promulgated under Emission Standards for

Clean-fuel Vehicles and Engines, Requirements for Clean-Fuel Vehicle

Conversions, and California Pilot Test Program which appeared in the

Federal Register on September 30, 1994 (59 FR 50042) and under

Standards for Emissions From Natural Gas-Fueled, and Liquefied

Petroleum Gas-Fueled Motor Vehicles and Motor Vehicle Engines, and

Certification Procedures for Aftermarket Conversions which appeared in

the Federal Register on September 21, 1994 (59 FR 48472). The affected

regulations are codified at 40 CFR Parts 9, 85, 86, 88, and 600. EPA

will continue to present OMB control numbers in a consolidated table

format to be codified in 40 CFR part 9 of the Agency's regulations, and

in each CFR volume containing EPA regulations. The table lists the

section numbers with reporting and recordkeeping requirements, and the

current OMB control numbers. This display of the OMB control numbers

and its subsequent codification in the Code of Federal Regulations

satisfies the requirements of the Paperwork Reduction Act (44 U.S.C.

3501 et seq.) and OMB's implementing regulations at 5 CFR part 1320.

Environmental and Economic Impacts

This regulation is intended only to reduce the administrative and

testing burden of certifying methanol-fueled vehicles. It does not

affect the stringency of emission standards. Thus, it should have no

impact on the environment.

This regulation does provide manufacturers some additional

flexibility, and will result in minor economic benefits. These economic

benefits, however, are expected to be small.

Statutory Authority

The statutory authority for this action is provided by sections

202(a) (1)-(2), 206, 301(a) of the Clean Air Act (42 U.S.C. 7521(a),

7525, and 7601(a)).

Administrative Designation and Regulatory Analysis

Under Executive Order 12866, EPA must judge whether a regulation is

``significant'' and, therefore, subject to OMB review and the

requirements of the Executive Order. This regulation is not a

``significant regulatory action'' because the amendments make only

minor and technical changes.

This Amendment to the final rule is not subject to the Office of

Management and Budget's review under the Executive Order and no

Regulatory Impact Analysis was prepared.

Reporting and Recordkeeping Requirements

The information collection requirements in this rule have been

approved by the Office of Management and Budget (OMB) under the

Paperwork Reduction Act, 44 U.S.C. 3501 et seq and have been assigned

control number 2060-0104. An Information Collection Request document

has been prepared by EPA (ICR No. 783.21) and a copy may be obtained

from Sandy Farmer, Information Policy Branch; EPA; 401 M St., SW.

(2136); Washington, DC 20460 or by calling (202) 260-2740.

Public reporting burden for this collection of information is

estimated to have a negligible effect on the existing clearance which

averages 15,900 hours per response, including time for reviewing

instructions, searching existing data sources, gathering and

maintaining the data needed, and completing the collection of the

information.

Send comments regarding the burden estimate or any other aspect of

this collection of information, including

[[Page 34334]]

suggestions for reducing this burden to Chief, Information Policy

Branch; EPA; 401 M St., SW. (2136); Washington, DC 20460; and to the

Office of Information and Regulatory Affairs, Office of Management and

Budget, Washington, DC 20503, marked ``Attention: Desk Officer for

EPA.''

All the information collection requirements for both the CFV

Emission Standards and Gaseous Fuels Emission Standards rulemakings

have been approved by the Office of Management and Budget under the

Paperwork Reduction Act, 44 U.S.C. 3501 et seq. and have been assigned

either control number 2060-0104 or 2060-0314.

Regulatory Flexibility Act

Under the Regulatory Flexibility Act. 5 U.S.C. 601 et seq., the

Administrator of EPA is required to determine whether a regulation will

have a significant economic impact on a substantial number of small

entities and, if so, to perform a regulatory flexibility analysis. The

technical amendments contained in this rulemaking will not increase the

burden or cost of compliance for any segment of the automotive

industry. Therefore, pursuant to 5 U.S.C. 605(b), I hereby certify that

this rule will not have a significant economic impact on a substantial

number of small entities.

List of Subjects

40 CFR Part 9

Reporting and recordkeeping requirements.

40 CFR Part 86

Environmental protection, Administrative practice and procedure,

Air pollution control, Gasoline, Labeling, Motor vehicles, Motor

vehicle pollution, Reporting and recordkeeping requirements.

Dated: April 28, 1995.

Carol M. Browner,

Administrator.

For the reasons set forth in the preamble, parts 9 and 86 of title

40 of the Code of Federal Regulations are amended as follows:

PART 9--[AMENDED]

1. The authority citation for part 9 continues to read as follows:

Authority: 7 U.S.C. 135 et seq., 136-136y; 15 U.S.C. 2001, 2003,

2005, 2006, 2601-2671; 21 U.S.C. 331j, 346a, 348; 31 U.S.C. 9701; 33

U.S.C. 1251 et seq., 1311, 1313d, 1314, 1321, 1326, 1330, 1344, 1345

(d) and (e), 1361; E.O. 11735, 38 FR 21243, 3 CFR, 1971-1975 Comp.

p. 973; 42 U.S.C. 241, 242b, 243, 246, 300f, 300g, 300g-1, 300g-2,

300g-3, 300g-4, 300g-5, 300g-6, 300j-1, 300j-2, 300j-3, 300j-4,

300j-9, 1857 et seq., 6901-6992k, 7401-7671q, 7542, 9601-9657,

11023, 11048.

1a. Section 9.1 is amended in the table by adding in numerical

order new entries under the center headings ``Control of Air Pollution

From Motor Vehicles and Motor Vehicle Engines,'' ``Control of Air

Pollution from New and In-Use Motor Vehicles and New and In-Use Motor

Vehicle Engines: Certification and Test Procedures,'' ``Clean-Fuel

Vehicles'' and ``Fuel Economy of Motor Vehicles,'' to read as follows:

Sec. 9.1 OMB approvals under the Paperwork Reduction Act.

* * * * *

------------------------------------------------------------------------

OMB control

40 CFR citation No.

------------------------------------------------------------------------

* * * * *

------------------------------------------------------------------------

Control of Air Pollution From Motor Vehicles and Motor Vehicle Engines

------------------------------------------------------------------------

85.503.................................................. 2060-0104

85.505.................................................. 2060-0104

* * * * *

------------------------------------------------------------------------

Control of Air Pollution From New and In-Use Motor Vehicles and New and

In-Use Motor Vehicle Engines: Certification and Test Procedures

------------------------------------------------------------------------

* * * * *

86.094-24(a)(3)(iii).................................... 2060-0314

* * * * *

86.098-28............................................... 2060-0104

* * * * *

86.150-98............................................... 2060-0104

* * * * *

86.513-94............................................... 2060-0104

* * * * *

86.1344-94.............................................. 2060-0104

* * * * *

------------------------------------------------------------------------

Clean-Fuel Vehicles

------------------------------------------------------------------------

* * * * *

88.204-94(b)(1)......................................... 2060-0314

88.204-94(c)............................................ 2060-0314

* * * * *

88.306-94(b)(1)......................................... 2060-0314

88.306-94(b)(2)......................................... 2060-0314

88.306-94(b)(4)......................................... 2060-0314

88.306-94(c)............................................ 2060-0314

88.306-94(f)............................................ 2060-0314

* * * * *

------------------------------------------------------------------------

Fuel Economy of Motor Vehicles

------------------------------------------------------------------------

* * * * *

600.113-93.............................................. 2060-0104

* * * * *

------------------------------------------------------------------------

PART 86--CONTROL OF AIR POLLUTION FROM NEW AND IN-USE MOTOR

VEHICLES AND NEW AND IN-USE MOTOR VEHICLE ENGINES: CERTIFICATION

AND TEST PROCEDURES

1b. The authority citation for part 86 continues to read as

follows:

Authority: Secs 202, 203, 205, 206, 207, 208, 215, 216, 217 and

301(a), Clean Air Act, as amended (42 U.S.C. 7521, 7522, 7524, 7525,

7541, 7542, 7549, 7550, 7552 and 7601(a)).

2. Section 86.001-21 of Subpart A is amended by removing paragraphs

(c) through (k) and adding paragraphs (c) through (l) to read as

follows:

Sec. 86.001-21 Application for certification.

* * * * *

(c) through (j) [Reserved]. For guidance see Sec. 86.094-21.

(k) and (l) [Reserved]. For guidance see Sec. 86.096-21.

3. Section 86.090-2 of Subpart A is amended by revising the

definition of ``Flexible fuel vehicle (or engine)'', removing the

definition of ``Organic Material Hydrocarbon Equivalent'' and adding

the definitions of ``Dedicated vehicle (or engine)'' and ``Total

Hydrocarbon Equivalent'' in alphabetical order to read as follows:

Sec. 86.090-2 Definitions.

* * * * *

Dedicated vehicle (or engine) means any motor vehicle (or motor

vehicle engine) engineered and designed to be operated using a single

fuel. Flexible fuel vehicles and multi-fuel vehicles are not dedicated

vehicles.

* * * * *

Flexible fuel vehicle (or engine) means any motor vehicle (or motor

vehicle engine) engineered and designed to be operated on a petroleum

fuel, a methanol fuel, or any mixture of the two. Methanol-fueled

vehicles that are only marginally functional when using gasoline (e.g.,

the engine has a drop in power output of more than 80 percent) are not

flexible fuel vehicles.

* * * * *

[[Page 34335]]

Total Hydrocarbon Equivalent means the sum of the carbon mass

emissions of non-oxygenated hydrocarbons, methanol, formaldehyde or

other organic compounds that are separately measured, expressed as

gasoline-fueled vehicle hydrocarbons. In the case of exhaust emissions,

the hydrogen-to-carbon ratio of the equivalent hydrocarbon is 1.85:1.

In the case of diurnal and hot soak emissions, the hydrogen-to-carbon

ratios of the equivalent hydrocarbons are 2.33:1 and 2.2:1,

respectively.

* * * * *

4. Section 86.090-3 of Subpart A is amended by removing the entry

for OMHCE in paragraph (b) and adding an entry for THCE in alphabetical

order to read as follows:

Sec. 86.090-3 Abbreviations.

* * * * *

(b) * * *

THCE--Total Hydrocarbon Equivalent

* * * * *

5. Section 86.094-2 of Subpart A is amended by adding the

definition of ``Non-Methane Hydrocarbon Equivalent'' in alphabetical

order to read as follows:

Sec. 86.094-2 Definitions.

* * * * *

Non-Methane Hydrocarbon Equivalent means the sum of the carbon mass

emissions of non-oxygenated non-methane hydrocarbons, methanol,

formaldehyde, or other organic compounds that are separately measured,

expressed as gasoline-fueled vehicle hydrocarbons. In the case of

exhaust emissions, the hydrogen-to-carbon ratio of the equivalent

hydrocarbon is 1.85:1. In the case of diurnal and hot soak emissions,

the hydrogen-to-carbon ratios of the equivalent hydrocarbons are 2.33:1

and 2.2:1, respectively.

* * * * *

6. Section 86.094-3 of Subpart A is amended in paragraph (b) by

placing the entries in alphabetical order, removing the entry for

OMNMHCE and adding an entry for NMHCE in alphabetical order to read as

follows:

Sec. 86.094-3 Abbreviations.

* * * * *

(b) * * *

* * * * *

NMHCE--Non-Methane Hydrocarbon Equivalent

* * * * *

7. Section 86.094-9 of Subpart A is amended by revising paragraph

(a)(1)(iii) to read as follows:

Sec. 86.094-9 Emission standards for 1994 and later model year light-

duty trucks.

(a) * * *

(1) * * *

(iii) Exhaust emissions of carbon monoxide from 1994 and later

model year light-duty trucks shall not exceed 0.50 percent of exhaust

gas flow at curb idle at a useful life of 11 years or 120,000 miles,

whichever first occurs (for Otto-cycle and methanol-natural gas- and

liquefied petroleum gas-fueled diesel-cycle light-duty trucks only).

* * * * *

8. Section 86.094-21 of Subpart A is amended by adding paragraph

(j) to read as follows:

Sec. 86.094-21 Application for certification.

* * * * *

(j) For methanol-fueled vehicles, the manufacturer shall specify:

(1) Whether the vehicle is a flexible fuel vehicle or a dedicated

vehicle (manufacturers must obtain advance approval from the

Administrator to classify methanol-fueled vehicles that can use

gasoline as dedicated vehicles); and

(2) The fuel(s) (i.e., the percent methanol) for which the vehicle

was designed.

9. Section 86.096-21 of Subpart A is amended by redesignating

paragraphs (j) and (k) as paragraphs (k) and (l), respectively,

removing paragraphs (c) through (i), and adding paragraphs (c) through

(j) to read as follows:

Sec. 86.096-21 Application for certification.

* * * * *

(c) through (j) [Reserved]. For guidance see Sec. 86.094-21.

* * * * *

10. Section 86.097-9 of Subpart A is amended by revising paragraph

(a)(1)(iii) to read as follows:

Sec. 86.097-9 Emission standards for 1997 and later model year light-

duty trucks.

(a) * * *

(1) * * *

(iii) Exhaust emissions of carbon monoxide from 1997 and later

model year light-duty trucks shall not exceed 0.50 percent of exhaust

gas flow at curb idle at a useful life of 11 years or 120,000 miles,

whichever first occurs (for Otto-cycle and methanol-natural gas- and

liquefied petroleum gas-fueled diesel-cycle light-duty trucks only).

* * * * *

11. Section 86.098-21 of Subpart A is amended by removing

paragraphs (c) through (k) and adding paragraphs (c) through (l) to

read as follows:

Sec. 86.098-21 Application for certification.

* * * * *

(c) through (j) [Reserved]. For guidance see Sec. 86.094-21.

(k) and (l) [Reserved]. For guidance see Sec. 86.096-21.

12. Section 86.107-90 of Subpart B is amended by revising the

introductory text of paragraph (a)(2)(i) and adding paragraph

(a)(2)(iii) to read as follows:

Sec. 86.107-90 Sampling and analytical system; evaporative emissions.

(a) * * *

(2) * * * (i) For gasoline- and methanol-fueled vehicles a

hydrocarbon analyzer utilizing the hydrogen flame ionization principle

(FID) shall be used to monitor the atmosphere within the enclosure (a

heated FID (HFID)(235 deg. 15 deg.F (113

8 deg.C)) is recommended for methanol-fueled vehicles).

Instrument bypass flow may be returned to the enclosure. The FID shall

have a response time to 90 percent of final reading of less than 1.5

seconds, and be capable of meeting performance requirements expressed

as a function of Cstd: where Cstd is the specific enclosure hydrocarbon

level, in ppm, corresponding to the evaporative emission standard:

* * * * *

(iii) The methanol sampling system shall be designed such that, if

a test vehicle emitted the maximum allowable level of methanol (based

on all applicable standards) during any phase of the test, the measured

concentration in the primary impinger would exceed either 25 mg/l or a

concentration equal to 25 times the limit of detection for the GC

analyzer, and such that the primary impinger collects at least 90

percent of the analyte in the samples. The remaining analyte shall be

collected by the secondary impinger. This requirement does not apply to

dilution air samples, since they do not require secondary impingers, or

to samples in which the concentrations approach the limit of detection.

The provisions of this paragraph apply to the design of sampling

systems, not to individual tests.

* * * * *

13. Section 86.107-96 of Subpart B is amended by revising paragraph

(b)(1) and adding paragraph (b)(3) to read as follows:

Sec. 86.107-96 Sampling and analytical systems; evaporative emissions.

* * * * *

(b) * * *

(1) For gasoline fueled, natural gas-fueled, liquefied petroleum

gas-fueled and methanol-fueled vehicles a hydrocarbon analyzer

utilizing the hydrogen flame ionization principle (FID) shall be used

to monitor the

[[Page 34336]]

atmosphere within the enclosure (a heated FID (HFID)(235 deg.

15 deg.F (113 8 deg.C)) is recommended for

methanol-fueled vehicles). For natural gas-fueled vehicles, the FID may

be calibrated using methane, or if calibrated using propane the FID

response to methane shall be determined and applied to the FID

hydrocarbon reading. Provided evaporative emission results are not

effected, a probe may be used to detect or verify hydrocarbon sources

during a running loss test. Instrument bypass flow may be returned to

the enclosure. The FID shall have a response time to 90 percent of

final reading of less than 1.5 seconds.

* * * * *

(3) The methanol sampling system shall be designed such that, if a

test vehicle emitted the maximum allowable level of methanol (based on

all applicable standards) during any phase of the test, the measured

concentration in the primary impinger would exceed either 25 mg/l or a

concentration equal to 25 times the limit of detection for the GC

analyzer, and such that the primary impinger collects at least 90

percent of the analyte in the samples. The remaining analyte shall be

collected by the secondary impinger. This requirement does not apply to

dilution air samples, since they do not require secondary impingers, or

to samples in which the concentrations approach the limit of detection.

The provisions of this paragraph apply to the design of sampling

systems, not to individual tests.

* * * * *

14. Section 86.109-94 of Subpart B is amended by revising

paragraphs (a)(2)(i) through (a)(2)(iv), text of paragraph (a)(3)

preceding figures, text of paragraph (a)(4) preceding figure,

paragraphs (a)(5), (b) introductory text, (b)(4), (b)(5), (b)(6), (c)

introductory text, (c)(4), (c)(5), and (c)(6), and adding paragraphs

(a)(6) and (d), and revising Figures B94-2 and B94-3 to read as

follows:

Sec. 86.109-94 Exhaust gas sampling system; Otto-cycle vehicles not

requiring particulate emissions measurement.

(a) * * *

(2) * * *

(i) Using a duct of unrestricted length maintained at a temperature

above the maximum dew point of the exhaust, but below 250 deg.F

(121 deg.C); heating and possibly cooling capabilities are required; or

(ii) Using a short duct (up to 12 feet long) constructed of smooth

wall pipe with a minimum of flexible sections, maintained at a

temperature above the maximum dew point of the exhaust, but below

250 deg.F (121 deg.C), prior to the test and during the 10 minute hot

soak segment and uninsulated during the test (insulation may remain in

place and/or heating may occur during testing provided maximum

temperature is not exceeded); or

(iii) Using smooth wall duct less than five feet long with no

required heating. A maximum of two short flexible connectors are

allowed under this option; or

(iv) Omitting the duct and performing the exhaust gas dilution

function at the vehicle tailpipe exit.

(3) Positive displacement pump. The Positive Displacement Pump-

Constant Volume Sampler (PDP-CVS), Figure B94-1 satisfies the first

condition by metering at a constant temperature and pressure through

the pump. The total volume is measured by counting the revolutions made

by the calibrated positive displacement pump. The proportional samples

for the bag sample, and for methanol-fueled vehicles, the methanol

sample (Figure B94-2) and the formaldehyde sample (Figure B94-3), are

achieved by sampling at a constant flow rate. For methanol-fueled

vehicles, the sample lines for the methanol and formaldehyde samples

are heated to prevent condensation. The temperature of the sample lines

shall be more than 5 deg.F (3 deg.C) above the maximum dew point of the

sample, but below 250 deg.F (121 deg.C). (Note: For 1990 through 1994

model year methanol-fueled vehicles, methanol and formaldehyde sampling

may be omitted provided the bag sample (hydrocarbons and methanol) is

analyzed using a HFID calibrated with methanol.)

* * * * *

BILLING CODE 6560-50-P

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[GRAPHIC][TIFF OMITTED]TR30JN95.042

[[Page 34338]]

[GRAPHIC][TIFF OMITTED]TR30JN95.043

BILLING CODE 6560-50-C

[[Page 34339]]

(4) Critical flow venturi. The operation of the Critical Flow

Venturi-Constant Volume Sampler (CFV-CVS) sample system, Figure B94-4,

is based upon the principles of fluid dynamics associated with critical

flow. Proportional sampling throughout temperature excursions is

maintained by use of small CFVs in the sample lines (for methanol-

fueled vehicles, one line supplies sample for the bag sample, another

line supplies sample for the methanol sample, and a third line supplies

sample for the formaldehyde sample.) The methanol and formaldehyde

sample lines are heated to prevent condensation. The temperature of the

sample lines shall be more than 5 deg.F (3 deg.C) above the maximum dew

point of the sample, but below 250 deg.F (121 deg.C). Care should be

taken to ensure that the CFVs of the sample probes are not heated since

heating of the CFVs would cause loss of proportionality. The variable

mixture flow rate is maintained at sonic velocity, is inversely

proportional to the square root of the gas temperature, and is computed

continuously. Since the pressure and temperature are the same at all

venturi inlets, the sample volume is proportional to the total volume.

(Note: For 1990 through 1994 model year methanol-fueled vehicles,

methanol and formaldehyde sampling may be omitted provided the bag

sample (hydrocarbons and methanol) is analyzed using a HFID calibrated

with methanol.)

* * * * *

(5) Electronic flow control. The Critical Flow Venturi-Electronic

Flow Control-Constant Volume Sampler (CFV-EFC-CVS) system is identical

to the CFV-CVS system described in paragraphs (a)(4) and (c) of this

section, except that it maintains proportional sampling for methanol

and formaldehyde by measuring the CVS flow rate, and electronically

controlling sample flow rates. For methanol-fueled vehicles, the

samples lines for the methanol and formaldehyde samples are heated to

prevent condensation. The temperature of the sample lines shall be more

than 5 deg.F (3 deg.C) above the maximum dew point of the sample, but

below 250 deg.F (121 deg.C).

(6) Other systems. Other sampling systems may be used if shown to

yield equivalent or superior results, and if approved in advance by the

Administrator.

(b) Component description, PDP-CVS. The PDP-CVS, Figure B94-1,

consists of a dilution air filter and mixing assembly, heat exchanger,

positive displacement pump, sampling systems (see Figure B94-2 for

methanol sampling system and Figure B94-3 for formaldehyde sampling

system) sampling lines which are heated to a temperature that is more

than 5 deg.F (3 deg.C) above the maximum dew point of the sample, but

below 250 deg.F (121 deg.C) in the case of the methanol-fueled vehicles

(heating of the sample lines may be omitted, provided the methanol and

formaldehyde sample collection systems are close coupled to the probes

thereby preventing loss of sample due to cooling and resulting

condensation in the sample lines), and associated valves, pressure and

temperature sensors. The PDP-CVS shall conform to the following

requirements:

* * * * *

(4) The flow capacity of the CVS shall be large enough to

completely eliminate water condensation in the dilution and sampling

systems. (300 to 350 cfm (0.142 to 0.165 m3/s) is sufficient for

most petroleum-fueled vehicles. Higher flow rates are required for

methanol-fueled vehicles and may be required for natural gas-fueled and

liquefied petroleum gas-fueled vehicles. Procedures for determining CVS

flow rates are detailed in ``Calculation of Emissions and Fuel Economy

When Using Alternative Fuels,'' EPA 460/3-83-009.) (Copies may be

obtained from U.S. Department of Commerce, NTIS, Springfield, Virginia

22161; order PB 84104702.) Dehumidifying the dilution air

before entering the CVS is allowed. Hearing the dilution air is also

allowed, provided:

(i) The air (or air plus exhaust gas) temperature does not exceed

250 deg.F.

(ii) Calculation of the CVS flow rate necessary to prevent water

condensation is based on the lowest temperature encountered in the CVS

prior to sampling. (It is recommended that the CVS system be insulated

when heated dilution air is used.)

(iii) The dilution ratio is sufficiently high to prevent

condensation in bag samples as they cool to room temperature.

(5) Sample collection bags for dilution air and exhaust samples

shall be of sufficient size so as not to impede sample flow. A single

dilution air sample, covering the total test period, may be collected

for the determination of methanol and formaldehyde background

(methanol-fueled vehicles).

(6) The methanol sample collection system and the formaldehyde

sample collection system shall each be of sufficient capacity so as to

collect samples of adequate size for analysis without significant

impact on the volume of dilute exhaust passing through the PDP. The

systems shall also comply with the following requirements that apply to

the design of the systems, not to individual tests.

(i) The methanol system shall be designed such that, if a test

vehicle emitted the maximum allowable level of methanol (based on all

applicable standards) during the first phase of the test, the measured

concentration in the primary impinger would exceed either 25 mg/l or a

concentration equal to 25 times the limit of detection for the GC

analyzer. Sampling systems for all phases shall be identical.

(ii) The formaldehyde system shall be designed such that, if a test

vehicle emitted formaldehyde at a rate equal to twenty percent of the

maximum allowable level of NMHCE (i.e., 0.05 g/mi for a 0.25 g/mi NMHCE

standard), or the maximum formaldehyde level allowed by a specific

formaldehyde standard, whichever is less, during the first phase of the

test, the concentration of formaldehyde in the DNPH solution of the

primary impinger, or solution resulting from the extraction of the DNPH

cartridge, shall exceed either 2.5 mg/l or a concentration equal to 25

times the limit of detection for the HPLC analyzer. Sampling systems

for all phases shall be identical.

(iii) The methanol and formaldehyde impinger systems shall be

designed such that the primary impinger collects at least 90 percent of

the analyte in the samples. The remaining analyte shall be collected by

the secondary impinger. This requirement does not apply to dilution air

samples, since they do not require secondary impingers, or to samples

in which the concentrations approach the limit of detection.

(c) Component description, CFV-CVS. The CFV-CVS sample system,

Figure B94-4, consists of a dilution air filter and mixing assembly, a

cyclone particulate separator, unheated sampling venturies for the bag

samples, and for the methanol and formaldehyde samples from methanol-

fueled vehicles, samples lines heated to a temperature that is more

than 5 deg.F (3 deg.C) above the maximum dew point of the sample, but

below 250 deg.F (121 deg.C) for the methanol and formaldehyde samples

from methanol fueled vehicles (heating of the sample lines may be

omitted provided, the methanol and formaldehyde sample collection

systems are close coupled to the probes thereby preventing loss of

sample due to cooling and resulting condensation in the sample lines),

a critical flow venturi, and assorted valves, and pressure and

temperature sensors. The CFV sample system shall conform to the

following requirements:

* * * * *

[[Page 34340]]

(4) The flow capacity of the CVS shall be large enough to

completely eliminate water condensation in the dilution and sampling

systems. (300 to 350 cfm (0.142 to 0.165 m3/s) is sufficient for

most petroleum-fueled vehicles. Higher flow rates are required for

methanol-fueled vehicles and may be required for natural gas-fueled and

liquefied petroleum gas-fueled vehicles. Procedures for determining CVS

flow rates are detailed in ``Calculation of Emissions and Fuel Economy

When Using Alternative Fuels,'' EPA 460/3-83-009.) Dehumidifying the

dilution air before entering the CVS is allowed. Heating the dilution

air is also allowed, provided:

(i) The air (or air plus exhaust gas) temperature does not exceed

250 deg.F (121 deg.C).

(ii) Calculation of the CVS flow rate necessary to prevent water

condensation is based on the lowest temperature encountered in the CVS

prior to sampling. (It is recommended that the CVS system be insulated

when heated dilution air is used.)

(iii) The dilution ratio is sufficiently high to prevent

condensation in bag samples as they cool to room temperature.

(5) Sample collection bags for dilution air and exhaust samples

shall be of sufficient size so as not to impede sample flow. A single

dilution air sample, covering the total test period, may be collected

for the determination of methanol and formaldehyde background

(methanol-fueled vehicles).

(6) The methanol sample collection system and the formaldehyde

sample collection system shall each be of sufficient capacity so as to

collect samples of adequate size for analysis without significant

impact on the volume of dilute exhaust passing through the CVS. The

systems shall also comply with the following requirements that apply to

the design of the systems, not to individual tests.

(i) The methanol system shall be designed such that, if a test

vehicle emitted the maximum allowable level of methanol (based on all

applicable standards) during the first phase of the test, the measured

concentration in the primary impinger would exceed either 25 mg/l or a

concentration equal to 25 times the limit of detection for the GC

analyzer. Sampling systems for all phases shall be identical.

(ii) The formaldehyde system shall be designed such that, if a test

vehicle emitted formaldehyde at a rate equal to twenty percent of the

maximum allowable level of NMHCE (i.e., 0.05 g/mi for a 0.25 g/mi NMHCE

standard), or the maximum formaldehyde level allowed by a specific

formaldehyde standard, whichever is less, during the first phase of the

test, the concentration of formaldehyde in the DNPH solution of the

primary impinger, or solution resulting from the extraction of the DNPH

cartridge, shall exceed either 2.5 mg/l or a concentration equal to 25

times the limit of detection for the HPLC analyzer. Sampling systems

for all phases shall be identical.

(iii) The methanol and formaldehyde systems shall be designed such

that the primary impinger collects at least 90 percent of the analyte

in the samples. The remaining analyte shall be collected by the

secondary impinger. This requirement does not apply to dilution air

samples, since they do not require secondary impingers, or to samples

in which the concentrations approach the limit of detection.

(d) Component description, CFV-EFC-CVS. The CVS sample system is

identical to the system described in paragraph (c) of this section,

plus includes a means of electronically measuring the CVS flow rate,

and electronic mass flow controllers for the methanol and formaldehyde

sample lines. The EFC sample system shall conform to all of the

requirements listed in paragraph (c), except that the methanol and

formaldehyde samples must both be drawn from a static probe. It also

must comply with the following additional requirements:

(1) The ratio of the CVS mass flow rate to the sample mass flow

rate shall not deviate from the design ratio by more than 5

percent. (The volumetric sample flow rate shall be varied inversely

with the square root of the bulk stream temperature.)

(2) Flow meters to totalize sample volumes for methanol and/or

formaldehyde samples shall meet the accuracy specifications of

Sec. 86.120. Total sample volumes may be obtained from the flow

controllers, provided that the controllers meet the accuracy

specifications of Sec. 86.120.

15. Section 86.110-94 of Subpart B is amended by revising the text

of paragraph (a)(1) preceding the figures, paragraphs (a)(5)(i) through

(a)(5)(iii), (b) introductory text, (b)(1), (b)(2), (c), and (d), to

read as follows:

Sec. 86.110-94 Exhaust gas sampling system; diesel-cycle vehicles,

and Otto-cycle vehicles requiring particulate emissions measurements.

* * * * *

(a) * * *

(1) This sampling system requires the use of a PDP-CVS, CFV-CVS (or

a CFV-EFC-CVS), sample system with heat exchanger connected to a

dilution tunnel. The heat exchanger is not required for the CFV-CVS or

EFC-CFV-CVS if electronic flow controllers are used to maintain

proportionality for the particulate sample. Figure B94-5 is a schematic

drawing of the PDP system. Figure B94-6 is a schematic drawing of the

CFV-CVS system. (Methanol-fueled Otto-cycle vehicles may be tested

using this test equipment, without measuring particulate emissions.)

* * * * *

(5) * * *

(i) A tailpipe to dilution tunnel duct of unrestricted length

maintained at a temperature above the dew point of the mixture, but

below 250 deg.F (121 deg.C) through heating and cooling as required; or

(ii) Using a short duct (up to 12 feet long) constructed of smooth

wall pipe with a minimum of flexible sections maintained at a

temperature above the dew point of the mixture, but below 250 deg.F

(121 deg.C) prior to the test and during breaks in testing (insulation

may remain in place and or heating may occur during the testing

provided the maximum temperature is not exceeded); or

(iii) Using smooth wall duct less than five feet long with no

required heating. A maximum of two short flexible connectors are

allowed under this option; or

* * * * *

(b) Component description--petroleum-fueled, natural gas-fueled and

liquefied petroleum gas-fueled vehicles. The components necessary for

petroleum-fueled, natural gas-fueled and liquefied petroleum gas-fueled

vehicle exhaust sampling shall meet the following requirements:

(1) The PDP-CVS, Figure B94-5, shall contain a proportional

particulate sampling system, and shall conform to all of the

requirements listed for the exhaust gas PDP-CVS (Sec. 86.109(b)), with

one exception: a flow rate of sufficient volume is required to maintain

the diluted exhaust stream, from which the particulate sample flow is

taken, at a temperature of 125 deg.F (52 deg.C) or less.

(2) The CFV sample system, Figure B94-6, shall contain a

proportional particulate sampling system, and shall conform to all of

the requirements listed for the exhaust gas CFV sample system

(Sec. 86.109(c)), except for the following:

(i) A flow rate of sufficient volume is required to maintain the

diluted exhaust stream, from which the particulate sample flow is

taken, at a temperature of 125 deg.F (52 deg.C) or less.

(ii) If a constant volume particulate sample is collected, a heat

exchanger is required.

[[Page 34341]]

(iii) If a heat exchanger is used, the gas mixture temperature,

measured at a point immediately ahead of the critical flow venturi,

shall be within 20 deg.F (11 deg.C) of the designed

operating temperature at the start of the test. The gas mixture

temperature variation from its value at the start of the test shall be

limited to 20 deg.F (11 deg.C) during the entire test. The

temperature measuring system shall have an accuracy and precision of

2 deg.F (1.1 deg.C).

(iv) The cyclonic separator is optional.

* * * * *

(c) Component description--methanol-fueled vehicles. The components

necessary for methanol-fueled vehicle exhaust sampling shall meet the

following requirements:

(1) The PDP-CVS, Figure B94-5, shall contain a proportional

particulate sampling system, and shall conform to all of the

requirements listed for the exhaust gas PDP-CVS (Sec. 86.109), with one

exception: a flow rate of sufficient volume is required to maintain the

diluted exhaust stream, from which the particulate sample flow is

taken, at a temperature of 125 deg.F (52 deg.C) or less.

(2) The CFV-CVS sample system, Figure B94-6, shall contain a

proportional particulate sampling system, and shall conform to all of

the requirements listed for the exhaust gas CFV sample system

(Sec. 86.109), except for the following:

(i) A flow rate of sufficient volume is required to maintain the

diluted exhaust stream, from which the particulate sample flow is

taken, at a temperature of 125 deg.F (52 deg.C) or less.

(ii) If a constant volume particulate sample is collected, a heat

exchanger is required.

(iii) If a heat exchanger is used, the gas mixture temperature,

measured at a point immediately ahead of the critical flow venturi,

shall be within 20 deg.F (11 deg.C) of the designed

operating temperature at the start of the test. The gas mixture

temperature variation from its value at the start of the test shall be

limited to 20 deg.F (11 deg.C) during the entire test. The

temperature measuring system shall have an accuracy and precision of

2 deg.F (1.1 deg.C).

(iv) The cyclonic separator is optional.

(3) The EFC-CFV-CVS sample system shall conform to all of the

requirements listed for the exhaust gas EFC sample system (Sec. 86.109)

with three exceptions:

(i) A flow rate of sufficient volume is required to maintain the

diluted exhaust stream, from which the particulate sample flow is

taken, at a temperature of 125 deg.F (52 deg.C) or less.

(ii) A proportional particulate sample shall be collected using an

electronic flow controller that meets the performance criteria listed

in Sec. 86.109 for methanol and formaldehyde EFC systems.

(iii) The cyclonic separator is optional.

(4) Losses of methanol due to condensation of water in the duct

connecting the vehicle tail pipe to the dilution tunnel must be

eliminated. This may be accomplished by:

(i) The use of a duct of unrestricted length maintained at a

temperature above the maximum dew point of the exhaust, but below

250 deg.F (121 deg.C), through heating and cooling as required; or

(ii) The use of a short duct (up to 12 feet long) constructed of

smooth wall pipe with a minimum of flexible sections maintained at a

temperature above the maximum dew point of the exhaust, but below

250 deg.F (121 deg.C), prior to the test and during breaks in testing

(insulation may remain in place and/or heating may occur during testing

provided maximum temperature is not exceeded); or

(iii) Using smooth wall duct less than five feet long with no

required heating. A maximum of two short flexible connectors are

allowed under this option; or

(iv) Omitting the duct and performing the exhaust gas dilution

function at the vehicle tailpipe exit.

(5) The vehicle exhaust shall be directed downstream at the point

where it is introduced into the dilution tunnel.

(6) The dilution air shall be between 68 deg.F (20 deg.C) and

86 deg.F (30 deg.C) during the test (unless the requirements of

Sec. 86.109-94(b)(4) are also met).

(7) The dilution tunnel shall be:

(i) Sized to permit development of turbulent flow (Reynold's No.

>>4000) and complete mixing of the exhaust and dilution air between the

mixing orifice and the particulate sample probe. It is recommended that

uniform mixing be demonstrated by the user.

(ii) At least 8.0 inches (20.3 cm) in diameter.

(iii) Constructed of electrically conductive material which does

not react with the exhaust components.

(iv) Grounded.

(8) The temperature of the diluted exhaust stream inside of the

dilution tunnel shall be sufficient to prevent water condensation.

However, the sample zone dilute exhaust temperature shall not exceed

125 deg.F (52 deg.C) at any time during the test.

(9) The particulate sample probe shall be:

(i) Installed facing upstream at a point where the dilution air and

exhaust are well mixed (i.e., near the tunnel centerline, approximately

10 tunnel diameters downstream from the point where the exhaust enters

the dilution tunnel).

(ii) Sufficiently distant (radially) from the THC probe so as to be

free from the influence of any wakes or eddies produced by the THC

probe.

(iii) 0.5 inch (1.27 cm) minimum inside diameter.

(iv) The distance from the sampling tip to the filter holder shall

be at least five probe diameters (for filters located inside the

tunnel), but not more than 40.0 inches (102 cm) for filters located

outside of the dilution tunnel.

(v) Free from sharp bends.

(vi) Configured so that a clean particulate filter (including back

up filter) can be selected simultaneously with the selection of an

empty gaseous emissions bag.

(10) The flow rate through the particulate probe shall be

maintained to a constant value within 5 percent of the set

flow rate.

(11) The particulate sample pump shall be located sufficiently

distant from the dilution tunnel so that the inlet gas temperature is

maintained at a constant temperature ( 5.0 deg.F

(2.8 deg.C)).

(12) The gas meters or flow instrumentation shall be located

sufficiently distant from the tunnel so that the inlet gas temperature

remains constant ( 5.0 deg.F (2.8 deg.C)).

(13) The hydrocarbon probe shall be:

(i) Installed facing upstream at a point where the dilution air and

exhaust are well mixed (i.e., approximately ten tunnel diameters

downstream from the point where the exhaust enters the dilution

tunnel).

(ii) Sufficiently distant (radially) from the particulate probe so

as to be free from the influence of any wakes of eddies produced by the

particulate probe.

(iii) Heated and insulated over the entire length to maintain a

wall temperature more than 5 deg.F (3 deg.C) above the maximum dew

point of the sample, but below 250 deg.F (121 deg.C).

(iv) 0.19 in. (0.48 cm) minimum inside diameter.

(14) It is intended that the THC probe be free from cold spots

(i.e., free from cold spots where the probe wall temperature is less

than 5 deg.F (3 deg.C) above the maximum dew point of the sample.) This

will be determined by a temperature sensor located on a section of the

probe wall outside of the dilution tunnel. The temperature sensor shall

be insulated from any heating elements on the probe. The sensor shall

have an accuracy and precision of 2 deg.F (1.1 deg.C).

[[Page 34342]]

(15) The dilute exhaust gas flowing in the hydrocarbon sample

system shall be:

(i) At 235 deg.F 15 deg.F (113 deg.C

8 deg.C) immediately before the heated filter. This will be determined

by a temperature sensor located immediately upstream of the filter. The

sensor shall have an accuracy and precision of 2 deg.F

(1.1 deg.C).

(ii) At 235 deg. 15 deg.F (113 deg.C

8 deg.C) immediately before the HFID. This will be determined by a

temperature sensor located at the exit of the heated sample line. The

sensor shall have an accuracy and precision of 2 deg.F

(1.1 deg.C).

(16) It is intended that the dilute exhaust gas flowing in the

hydrocarbon sample system between 220 deg.F and 250 deg.F (105 deg.C

and 121 deg.C).

(17) For methanol-fueled vehicles, bag sampling procedures for the

measurement of hydrocarbons as described in Sec. 86.109 may be

employed.

(d) [Reserved]. For guidance see Sec. 86.110-90.

16. Section 86.113-94 of Subpart B is amended by revising paragraph

(d) to read as follows:

Sec. 86.113-94 Fuel specifications.

* * * * *

(d) Mixtures of petroleum and methanol fuels for flexible fuel

vehicles. (1) Mixtures of petroleum and methanol fuels used for exhaust

and evaporative emission testing and service accumulation for flexible

fuel vehicles shall consist of the appropriate petroleum fuels listed

in either paragraph (a) or paragraph (b) of this section and a methanol

fuel representative of the fuel expected to be found in use, as

specified in paragraph (c) of this section, and shall be within the

range of fuel mixtures for which the vehicle was designed, as reported

in Sec. 86.94-21(j). The Administrator may use any fuel or fuel mixture

within this range for testing.

(2) The fuel mixtures used by the manufacturers shall be sufficient

to demonstrate compliance over the full design range, and shall

include:

(i) For emission testing:

(A) The petroleum fuel specified in paragraph (a) or (b) of this

section;

(B) A methanol fuel representative of the methanol fuel expected to

the found in use, as specified in paragraph (c) of this section;

(C) A combination of the fuels specified in paragraphs (d)(2)(i)(A)

and (d)(2)(i)(B) of this section at a composition which represents the

highest Reid Vapor Pressure of in-use mixtures. This mixture shall

contain between 9-13 percent methanol by volume.

(ii) For service accumulation, the fuels specified in paragraphs

(a) and (c) of this section or, for diesel FFVs, paragraphs (b) and (c)

of this section shall be used alternately. The fuels shall be

alternated at mileage intervals not to exceed 5,000 miles. The fuels

shall be alternated such that the cumulative volumes of both the

methanol fuel and the petroleum fuel used shall be at least 25 percent

of the total fuel volume.

(iii) Or, other combinations for testing or service accumulation

which demonstrate compliance with the standards over the entire design

range of the vehicle, provided that written approval is obtained from

the Administrator prior to the start of testing.

(3) The specification range of the fuels to be used under this

paragraph (d) shall be reported in accordance with Sec. 86.094-21.

* * * * *

17. Section 86.114-94 of Subpart B is amended by revising

paragraphs (a)(2), (a)(5), (b), and (c), and adding paragraph (d) to

read as follows:

Sec. 86.114-94 Analytical gases.

(a) * * *

(2) Gases for the THC analyzer shall be:

(i) Single blends of propane using air as the diluent; and

(ii) Optionally, for response factor determination, single blends

of methanol using air as the diluent.

* * * * *

(5) Fuel for FIDs and HFIDs and the methane analyzer shall be a

blend of 40 2 percent hydrogen with the balance being

helium. The mixture shall contain less than one ppm equivalent carbon

response. 98 to 100 percent hydrogen fuel may be used with advance

approval by the Administrator.

* * * * *

(b) Calibration gases (not including methanol) shall be traceable

to within one percent of NIST (formerly NBS) gas standards, or other

gas standards which have been approved by the Administrator.

(c) Span gases (not including methanol) shall be accurate to within

two percent of true concentration, where true concentration refers to

NIST (formerly NBS) gas standards, or other gas standards which have

been approved by the Administrator.

(d) Methanol in air gases used for response factor determination

shall:

(1) Be traceable to within 2 percent of NIST (formerly

NBS) gas standards, or other standards which have been approved by the

Administrator; and

(2) Remain within 2 percent of the labeled

concentration. Demonstration of stability shall be based on a quarterly

measurement procedure with a precision of 2 percent (two

standard deviations), or other method approved by the Administrator.

The measurement procedure may incorporate multiple measurements. If the

true concentration of the gas changes by more than two percent, but

less than ten percent, the gas may be relabeled with the new

concentration.

18. Section 86.116-94 of Subpart B is amended by revising

paragraphs (c)(1) and (c)(3), and adding paragraph (g) to read as

follows:

Sec. 86.116-94 Calibrations, frequency and overview.

* * * * *

(c) * * *

(1) Calibrate the THC analyzers (both evaporative and exhaust

instruments), methane analyzer, carbon dioxide analyzer, carbon

monoxide analyzer, and oxides of nitrogen analyzer (certain analyzers

may require more frequent calibration depending on particular equipment

and uses).

* * * * *

(3) Perform an organic gas retention and calibration on the

evaporative emissions enclosure (see Sec. 86.117-90(c)).

* * * * *

(g) The Administrator, upon request, may waive the requirement to

comply with the specified methanol recovery tolerance (e.g.,

2 percent in Secs. 86.117-90 and 86.119-90), and/or the

specified methanol retention tolerance (e.g., 4 percent in

Sec. 86.117-90), and instead require compliance with higher tolerances

(not to exceed 6 percent for recoveries and 8

for retention), provided that:

(1) The Administrator determines that compliance with these

specified tolerances is not practically feasible; and

(2) The manufacturer makes information available to the

Administrator which indicates that the calibration tests and their

results are consistent with good laboratory practice, and that the

results are consistent with the results of calibration testing

conducted by the Administrator.

19. Section 86.117-90 of Subpart B is amended by revising

paragraphs (c) heading and introductory text, (c)(5), (c)(7), (c)(9),

(d)(1), and (d)(2)(iii) to read as follows:

Sec. 86.117-90 Evaporative emission enclosure calibrations.

* * * * *

(c) Hydrocarbon and methanol (organic gas) retention check and

calibration. The hydrocarbon and methanol (if the enclosure is used for

[[Page 34343]]

methanol-fueled vehicles) retention check provides a check upon the

calculated volume and also measures the leak rate. Prior to its

introduction into service and at least monthly thereafter (the methanol

check can be performed less frequently, provided it is performed at

least twice annually) the enclosure leak rate shall be determined as

follows:

* * * * *

(5) Inject into the enclosure a known quantity of pure propane (4g

is a convenient quantity) and a known quantity of pure methanol (4g is

a convenient quantity) in gaseous form; i.e., at a temperature of at

least 150-155 deg.F (65-68 deg.C). The propane and methanol may be

measured by volume flow or by mass measurement. The method used to

measure the propane and methanol shall have an accuracy of

0.5 percent of the measured value (less accurate methods

may be used with the advanced approval of the Administrator). The

methanol and propane tests do not need to be conducted simultaneously.

* * * * *

(7) To verify the enclosure calibration, calculate the mass of

propane and the mass of methanol using the measurements taken in steps

(4) and (6) (see paragraph (d) of this section). This quantity must be

within 2 percent of that measured in step 5 above. (For

1991-1995 calendar years, the difference may exceed 2

percent for methanol, provided it does not exceed 8 percent

for 1991 testing and 6 percent for 1992-1995 testing.)

* * * * *

(9) Calculate, using the equations in paragraph (d) of this section

and the readings taken in step (8), the hydrocarbon and methanol mass.

It may not differ by more than 4 percent of the value in

step (6). (For 1991-1995 calendar years, the difference may exceed

4 percent for methanol, provided it does not exceed

8 percent for 1991 testing and 6 percent for

1992-1995 testing.)

(d) Calculations. (1) The calculation of net methanol and

hydrocarbon mass change is used to determine enclosure background and

leak rate. It is also used to check the enclosure volume measurements.

The methanol mass change is calculated from the initial and final

methanol samples, temperature and pressure according to the following

equation:

[GRAPHIC][TIFF OMITTED]TR30JN95.000

Where:

(i) MCH3OH=Methanol mass change, g.

(ii) V=Enclosure volume, ft3, as measured in paragraph (b)(1) of

this section.

(iii) TE=Temperature of sample withdrawn, deg.R.

(iv) TSHED=Temperature of SHED, deg.R.

(v) VE=Volume of sample withdrawn, ft3.

(vi) PB=Barometric pressure at time of sampling, in. Hg.

(vii) CMS=GC concentration of test sample.

(viii) AV=Volume of absorbing reagent in impinger (ml).

(ix) i=Initial sample.

(x) f=Final sample.

(xi) 1=First impinger.

(xii) 2=Second impinger.

(2) * * *

(iii) CCH3OH=Methanol concentration as ppm carbon

[GRAPHIC][TIFF OMITTED]TR30JN95.001

* * * * *

20. Section 86.117-96 of Subpart B is amended by revising

paragraphs (c) heading and introductory text, (c)(1)(vii), (c)(1)(ix),

(c)(1)(xii), (d)(1), and (d)(2)(iii) to read as follows:

Sec. 86.117-96 Evaporative emission enclosure calibrations.

* * * * *

(c) Hydrocarbon and methanol (organic) retention check and

calibration. The hydrocarbon and methanol (if the enclosure is used for

methanol-fueled vehicles) retention check provides a check upon the

calculated volume and also measures the leak rate. The enclosure leak

rate shall be determined prior to its introduction into service,

following any modifications or repairs to the enclosure that may affect

the integrity of the enclosure, and at least monthly thereafter. (The

methanol check can be performed less frequently, provided it is

performed at least twice annually.) If six consecutive monthly

retention checks are successfully completed without corrective action,

the enclosure leak rate may be determined quarterly thereafter as long

as no corrective action is required.

(1) * * *

(vii) Inject into the enclosure 2 to 6 grams of pure propane and 2

to 6 grams of pure methanol in gaseous form; i.e., at a temperature of

at least 150 deg.F (65 deg.C). The propane and methanol may be

measured by volume flow or by mass measurement. The method used to

measure the propane and methanol shall have an accuracy of

0.2 percent of the measured value (less accurate methods

may be used with the advanced approval of the Administrator). The

methanol and propane tests do not need to be conducted simultaneously.

* * * * *

(ix) To verify the enclosure calibration, calculate the mass of

propane and the mass of methanol using the measurements taken in

paragraphs (c)(1)(vi) and (viii) of this section. See paragraph (d) of

this section. This quantity must be within 2 percent of

that measured in paragraph (c)(1)(vii) of this section. (For 1991-1995

calendar years, the difference may exceed 2 percent for

methanol, provided it does not exceed 6 percent.)

* * * * *

(xii) At the completion of the 24-hour cycling period, analyze the

enclosure atmosphere for hydrocarbon and

[[Page 34344]]

methanol content; determine the net withdrawn methanol (in the case of

diurnal emission testing with fixed volume enclosures); record

temperature and barometric pressure. These are the final readings for

the hydrocarbon and methanol retention check. The final hydrocarbon and

methanol mass, calculated in paragraph (d) of this section, shall be

within three percent of that determined in paragraph (c)(1)(viii) of

this section. (For 1991-1995 calendar years, the difference may exceed

3 percent for methanol, provided it does not exceed

6 percent.)

* * * * *

(d) Calculations. (1) The calculation of net methanol and

hydrocarbon mass change is used to determine enclosure background and

leak rate. It is also used to check the enclosure volume measurements.

The methanol mass change is calculated from the initial and final

methanol samples, temperature and pressure according to the following

equation:

[GRAPHIC][TIFF OMITTED]TR30JN95.002

Where:

(i) MCH3OH=Methanol mass change, g.

(ii) V=Enclosure volume, ft3, as measured in paragraph (b)(1) of

this section.

(iii) TE=Temperature of sample withdrawn, deg.R.

(iv) TSHED=Temperature of SHED, deg.R.

(v) VE=Volume of sample withdrawn, ft3.

(vi) PB=Barometric pressure at time of sampling, in. Hg.

(vii) CMS=GC concentration of test sample.

(viii) AV=Volume of absorbing reagent in impinger (ml).

(ix) i=Initial sample.

(x) f=Final sample.

(xii) 1=First impinger.

(xiii) 2=Second impinger.

(xiv) MCH3OH,out=mass of methanol exiting the enclosure, in the

case of fixed volume enclosures for diurnal emission testing,

g.

(xv) MCH3OH,in=mass of methanol exiting the enclosure, in the case

of fixed volume enclosures for diurnal emission testing, g.

(2) * * *

(iii) CCH3OH=Methanol concentration as ppm carbon

[GRAPHIC][TIFF OMITTED]TR30JN95.003

* * * * *

21. Section 86.119-90 of Subpart B is amended by revising

paragraphs (c)(1), (c)(4), and (c)(7) to read as follows:

Sec. 86.119-90 CVS calibration.

* * * * *

(c) * * *

(1) Obtain a small cylinder that has been charged with pure propane

or carbon monoxide gas (CAUTION--carbon monoxide is poisonous).

* * * * *

(4) Following completion of step (3) in this paragraph (c) (if

methanol injection is required), continue to operate the CVS in the

normal manner and release a known quantity of pure methanol (in gaseous

form) into the system during the sampling period (approximately five

minutes). This step does not need to be performed with each

verification, provided that it is performed at least twice annually.

* * * * *

(7) The cause for any discrepancy greater than 2

percent must be found and corrected. (For 1991-1995 calendar years,

discrepancies greater than 2 percent are allowed for the

methanol test, provided that they do not exceed 8 percent

for 1991 testing or 6 percent for 1992-1995 testing.)

22. A new Sec. 86.120-94 is being added to Subpart B to read as

follows:

Sec. 86.120-94 Gas meter or flow instrumentation calibration;

particulate, methanol and formaldehyde measurement.

(a) Sampling for particulate, methanol and formaldehyde emissions

requires the use of gas meters or flow instrumentation to determine

flow through the particulate filters, methanol impingers and

formaldehyde impingers. These instruments shall receive initial and

periodic calibrations as follows:

(1)(i) Install a calibration device in series with the instrument.

A critical flow orifice, a bellmouth nozzle, a laminar flow element or

an NBS traceable flow calibration device is required as the standard

device.

(ii) The flow system should be checked for leaks between the

calibration and sampling meters, including any pumps that may be part

of the system, using good engineering practice.

(2) Flow air through the calibration system at the sample flow rate

used for particulate, methanol, and formaldehyde testing and at the

backpressure which occurs during the test.

(3) When the temperature and pressure in the system have

stabilized, measure the indicated gas volume over a time period of at

least five minutes or until a gas volume of at least 1

percent accuracy can be determined by the standard device. Record the

stabilized air temperature and pressure upstream of the instrument and

as required for the standard device.

(4) Calculate air flow at standard conditions as measured by both

the standard device and the instrument(s). (Standard conditions are

defined as 68 deg.F (20 deg.C) and 29.92 in Hg (101.3 kPa).)

(5) Repeat the procedures of paragraphs (a)(2) through (4) of this

section using at least two flow rates which bracket the typical

operating range.

(6) If the air flow at standard conditions measured by the

instrument differs by 1.0 percent of the maximum operating

range or 2.0 percent of the point (whichever is smaller),

then a correction shall be made by either of the following two methods:

[[Page 34345]]

(i) Mechanically adjust the instrument so that it agrees with the

calibration measurement at the specified flow rates using the criteria

of paragraph (a)(6) of this section; or

(ii) Develop a continuous best fit calibration curve for the

instrument (as a function of the calibration device flow measurement)

from the calibration points to determine corrected flow. The points on

the calibration curve relative to the calibration device measurements

must be within 1.0 percent of the maximum operating range

of 2.0 percent of the point (whichever is smaller).

(b) Other systems. A bell prover may be used to calibrate the

instrument if the procedure outlined in ANSI B109.1-1973 is used. Prior

approval by the Administrator is not required to use the bell prover.

23. Section 86.121-90 of Subpart B is amended by revising

paragraphs (c) introductory text, (c)(1), and (c)(3)(iii) to read as

follows:

Sec. 86.121-90 Hydrocarbon analyzer calibration.

* * * * *

(c) FID response factor to methanol. When the FID analyzer is to be

used for the analysis of hydrocarbon samples containing methanol, the

methanol response factor of the analyzer shall be established. The

methanol response factor shall be determined at several concentrations

in the range of concentrations in the exhaust sample, using either bag

samples or gas bottles meeting the requirements of Sec. 86.114.

(1) The bag sample of methanol for analysis in the FID, if used,

shall be prepared using the apparatus shown in Figure B90-11. A known

volume of methanol is injected, using a microliter syringe, into the

heated mixing zone (250 deg.F (121 deg.C)) of the apparatus. The

methanol is vaporized and swept into the sample bag with a known volume

of zero grade air measured by a gas flow meter meeting the performance

requirements of Sec. 86.120.

BILLING CODE 6560-50-P

[[Page 34346]]

[GRAPHIC][TIFF OMITTED]TR30JN95.044

BILLING CODE 6560-50-C

[[Page 34347]]

* * * * *

(3) * * *

(iii) SAMppm=methanol concentration in the sample bag, or gas

bottle, in ppmC. SAMppm for sample bags

[GRAPHIC][TIFF OMITTED]TR30JN95.004

Where:

* * * * *

24. Section 86.123-78 of Subpart B is amended by adding paragraph

(c) to read as follows:

Sec. 86.123-78 Oxides of nitrogen analyzer calibration.

* * * * *

(c) When testing methanol-fueled vehicles, it may be necessary to

clean the analyzer frequently to prevent interference with NOX

measurements (see EPA/600/S3-88/040).

25. Section 86.127-94 of Subpart B is amended by adding paragraph

(f) to read as follows:

Sec. 86.127-94 Test procedures; overview.

* * * * *

(f) Background concentrations are measured for all species for

which emissions measurements are made. For exhaust testing, this

requires sampling and analysis of the dilution air. For evaporative

testing, this requires measuring initial concentrations. (When testing

methanol-fueled vehicles, manufacturers may choose not to measure

background concentrations of methanol and/or formaldehyde, and then

assume that the concentrations are zero during calculations.)

26. Section 86.127-96 of Subpart B is amended by adding paragraph

(g) to read as follows:

Sec. 86.127-96 Test procedures; overview.

* * * * *

(g) Background concentrations are measured for all species for

which emissions measurements are made. For exhaust testing, this

requires sampling and analysis of the dilution air. For evaporative

testing, this requires measuring initial concentrations. (When testing

methanol-fueled vehicles, manufacturers may choose not to measure

background concentrations of methanol and/or formaldehyde, and then

assume that the concentrations are zero during calculations.)

27. Section 86.137-90 of Subpart B is amended by revising paragraph

(b)(20) to read as follows:

Sec. 86.137-90 Dynamometer test run, gaseous and particulate

emissions.

* * * * *

(b) * * *

(20) As soon as possible, transfer the hot start ``transient''

exhaust and dilution air samples to the analytical system and process

the samples according to Sec. 86.140, obtaining a stabilized reading of

the exhaust bag sample on all analyzers within 20 minutes of the end of

the sample collection phase of the test. Obtain methanol and

formaldehyde sample analyses, if applicable, within 24 hours of the end

of the sample period. (If it is not possible to perform analysis on the

methanol and formaldehyde samples, within 24 hours, the samples should

be stored in a dark cold (4-10 deg.C) environment until analysis. The

samples should be analyzed within fourteen days.)

* * * * *

28. Section 86.137-94 of Subpart B is amended by revising

paragraphs (b)(4), (b)(6)(iii), (b)(6)(iv), and (b)(15), and removing

the note following paragraph (b)(6)(iv) to read as follows:

Sec. 86.137-94 Dynamometer test run, gaseous and particulate

emissions.

* * * * *

(b) * * *

(4) For methanol-fueled vehicles, with the sample selector valves

in the ``standby'' position, insert fresh sample collection impingers

into the methanol sample collection system, fresh impingers or a fresh

cartridge into the formaldehyde sample collection system and fresh

impingers (or a single cartridge for formaldehyde) into the dilution

air sample collection systems for methanol and formaldehyde (background

measurements of methanol and formaldehyde may be omitted and

concentrations assumed to be zero for calculations in Sec. 86.144).

* * * * *

(6) * * *

(iii) For methanol samples, the flow rates shall be set such that

the system meets the design criteria of Sec. 86.109 and Sec. 86.110.

For samples in which the concentration in the primary impinger exceeds

0.5 mg/l, it is recommended that the mass of methanol collected in the

secondary impinger not exceed ten percent of the total mass collected.

For samples in which the concentration in the primary impinger does not

exceed 0.5 mg/l, analysis of the secondary impingers is not necessary.

(iv) For formaldehyde samples, the flow rates shall be set such

that the system meets the design criteria of Sec. 86.109 and

Sec. 86.110. For impinger samples in which the concentration of

formaldehyde in the primary impinger exceeds 0.1 mg/l, it is

recommended that the mass of formaldehyde collected in the secondary

impinger not exceed ten percent of the total mass collected. For

samples in which the concentration in the primary impinger does not

exceed 0.1 mg/l, analysis of the secondary impingers is not necessary.

* * * * *

(15) Five seconds after the engine stops running, simultaneously

turn off gas flow measuring device No. 2 and if applicable, turn off

the hydrocarbon integrator No. 2, mark the hydrocarbon recorder chart,

turn off the No. 2 particulate sample pump and close the valves

isolating particulate filter No. 2, and position the sample selector

valves to the ``standby'' position (and open the valves isolating

particulate filter No. 1, if applicable). Record the measured roll or

shaft revolutions (both gas meter or flow measurement instrumentation

readings), and reset the counter. As soon as possible, transfer the

``stabilized'' exhaust and dilution air samples to the analytical

system and process the samples according to Sec. 86.140, obtaining a

stabilized reading of the exhaust bag sample on all analyzers within 20

minutes of the end of the sample collection phase of the test. Obtain

methanol and formaldehyde sample analyses, if applicable, within 24

hours of the end of the sample period. (If it is not possible to

perform analysis on the methanol and formaldehyde samples within 24

hours, the samples should be stored in a dark cold (4-10 deg.C)

environment until analysis. The samples should be analyzed within

fourteen days.) If applicable, carefully remove both pairs of

particulate sample filters from their respective holders, and place

each in a separate petri dish, and cover.

* * * * *

29. Section 86.140-94 of Subpart B is amended by revising

paragraphs (c) and (d) to read as follows:

Sec. 86.140-94 Exhaust sample analysis.

* * * * *

(c) For CH3OH (methanol-fueled vehicles), introduce test

samples into the gas chromatograph and measure the concentration. This

concentration is CMS in the calculations.

(d) For HCHO (methanol-fueled vehicles), introduce formaldehyde

test samples into the high pressure liquid chromatograph and measure

the concentration of formaldehyde as a dinitrophenylhydrazine

derivative in acetonitrile. This concentration is CFS in the

calculations.

* * * * *

30. Section 86.142-90 of Subpart B is amended by revising

paragraphs (p)(1)

[[Page 34348]]

through (p)(7), and removing paragraph (p)(8), to read as follows:

Sec. 86.142-90 Records required.

* * * * *

(p) * * *

(1) Specification of the methanol-fuel or methanol-fuel mixtures

used during the test.

(2) Volume of sample passed through the methanol sampling system

and the volume of deionized water in each impinger.

(3) The concentration of the GC analyses of the test samples

(methanol).

(4) Volume of sample passed through the formaldehyde sampling

system and the volume of DNPH solution used.

(5) The concentration of the HPLC analysis of the test sample

(formaldehyde).

(6) The temperatures of the sample lines before the HFID and the

impinger, the temperature of the exhaust transfer duct (as applicable),

and the temperature of the control system of the heated hydrocarbon

detector.

(7) A continuous measurement of the dew point of the raw and

diluted exhaust. This requirement may be omitted if the temperatures of

all heated lines are kept above 220 deg.F, or if the manufacturer

performs an engineering analysis demonstrating that the temperature of

the heated systems remains above the maximum dew point of the gas

stream throughout the course of the test.

* * * * *

31. Section 86.143-90 of Subpart B is amended by revising

paragraphs (a)(1) and (a)(2)(iii) to read as follows:

Sec. 86.143-90 Calculations; evaporative emissions.

(a) * * *

(1) For methanol:

[GRAPHIC][TIFF OMITTED]TR30JN95.005

Where:

(i) MCH3OH = Methanol mass change, g.

(ii) Vn = Net enclosure volume, ft3, as determined by

subtracting 50 ft3 (1.42 m\3\) (volume of vehicle with trunk and

windows open) from the enclosure volume. A manufacturer may use the

measured volume of the vehicle (instead of the nominal 50 ft3)

with advance approval by the Administrator: Provided, the measured

volume is determined and used for all vehicles tested by that

manufacturer.

(iii) TE = Temperature of sample withdrawn, deg.R.

(iv) VE = Volume of sample withdrawn, ft3.

(v) TSHED = Temperature of SHED, deg.R

(vi) CMS = GC concentration of sample, g/ml.

(vii) AV = Volume of absorbing reagent in impinger.

(viii) PB = Barometric pressure at time of sampling, in. Hg.

(ix) i = Initial sample.

(x) f = Final sample.

(xi) 1 = First impinger.

(xii) 2 = Second impinger.

(2) * * *

(iii) CCH3OH = Methanol concentration as ppm carbon.

[GRAPHIC][TIFF OMITTED]TR30JN95.006

* * * * *

32. Section 86.143-96 of Subpart B is amended by revising

paragraphs (b)(1)(i) and (b)(1)(ii)(C) to read as follows:

Sec. 86.143-96 Calculations; evaporative emissions.

* * * * *

(b) * * *

(1) * * *

(i) For methanol:

[GRAPHIC][TIFF OMITTED]TR30JN95.007

Where:

(A) MCH3OH = Methanol mass change, g.

(B) Vn = Net enclosure volume, ft3, as determined by

subtracting 50 ft\3\ (1.42 m3) (volume of vehicle with trunk and

windows open) from the enclosure volume. A manufacturer may use the

measured volume of the vehicle (instead of the nominal 50 ft3)

with advance approval by the Administrator: Provided, the measured

volume is determined and used for all vehicles tested by that

manufacturer.

(C) TE = Temperature of sample withdrawn, deg.R.

(D) VE = Volume of sample withdrawn, ft3.

(E) TSHED = Temperature of SHED, deg.R

(F) CMS = GC concentration of sample, g/ml.

(G) AV = Volume of absorbing reagent in impinger.

(H) PB = Barometric pressure at time of sampling, in. Hg.

[[Page 34349]]

(I) i = Initial sample.

(J) f = Final sample.

(K) 1 = First impinger.

(L) 2 = Second impinger.

(M) MCH3OH, out=mass of methanol exiting the enclosure, in the

case of fixed-volume enclosures for diurnal emission testing,

g.

(N) MCH3OH, in=mass of methanol entering the enclosure, in the

case of fixed-volume enclosures for diurnal emission testing,

g.

(ii) * * *

(C) CCH3OH = Methanol concentration as ppm carbon.

[GRAPHIC][TIFF OMITTED]TR30JN95.008

* * * * *

33. Section 86.144-94 of Subpart B is amended by revising

paragraphs (c)(5)(iv) through (c)(5)(xvi), (c)(7)(ii), and (e), and by

removing paragraphs (c)(5)(xvii) and (c)(5)(xviii), to read as follows:

Sec. 86.144-94 Calculations; exhaust emissions.

* * * * *

(c) * * *

(5) * * *

(iv)(A) CCH3OHe=Methanol concentration in the dilute exhaust, ppm.

(B) CCH3OHe=

[GRAPHIC][TIFF OMITTED]TR30JN95.009

(v)(A) CCH3OHd=Methanol concentration in the dilution air, ppm.

(B) CCH3OHd=

[GRAPHIC][TIFF OMITTED]TR30JN95.010

(vi) TEM=Temperature of methanol sample withdrawn from dilute

exhaust, deg.R.

(vii) TDM=Temperature of methanol sample withdrawn from dilution

air, deg.R.

(viii) PB=Barometric pressure during test, mm Hg.

(ix) VEM=Volume of methanol sample withdrawn from dilute exhaust,

ft3.

(x) VDM=Volume of methanol sample withdrawn from dilution air,

ft3.

(xi) CS=GC concentration of sample drawn from dilute exhaust,

g/ml.

(xii) CD=GC concentration of sample drawn from dilution air,

g/ml.

(xiii) AVS=Volume of absorbing reagent (deionized water) in impinger

through which methanol sample from dilute exhaust is drawn, ml.

(xiv) AVD=Volume of absorbing reagent (deionized water) in impinger

through which methanol sample from dilution air is drawn, ml.

(xv) 1=first impinger.

(xvi) 2=second impinger.

* * * * *

(7) * * *

(ii) For methanol-fueled vehicles, where fuel composition is

CxHyOz as measured, or calculated, for the fuel used:

[GRAPHIC][TIFF OMITTED]TR30JN95.011

* * * * *

(e) For methanol-fueled vehicles with measured fuel composition of

CH3.487O0.763, example calculation of exhaust emissions using

positive displacement pump:

(1) For the ``transient'' phase of the cold start test assume the

following: V0=0.29344 ft3 rev; N=25,801; R=37.5 pct; Ra=37.5

percent; PB=725.42 mm Hg; Pd=22.02 mm Hg; P4=70 mm Hg;

Tp 570 deg.R; FID HCe=14.65 ppm, carbon equivalent; r=0.788;

TEM=527.67 deg.R; VEM=0.2818 ft3; CS1=7.101;

AVS1=15.0 ml; CS2=0.256; AVS2=15.0 ml; TDM=527.67

deg.R; VDM=1.1389 ft3; CD1=0.439; AVD1=15.0 ml;

CD2=0.0; AVD2=15.0 ml; CFDE=8.970 g/ml;

VAE=5.0 ml; Q=0.1429; TEF=527.67 deg.R; VSE=0.2857

ft3; CFDA=0.39 g/ml; VAA=5.0 ml;

TDF=527.67 deg.R; VSA=1.1043 ft3; NOXe=5.273 ppm;

COem=98.8 ppm; CO2e=0.469 pct; CH4e=2.825 ppm; FID

HCd=2.771 ppm; NOXd=0.146 ppm; COdm=1.195 ppm;

CO2d=0.039 percent; CH4d=2.019 ppm; Dct=3.583 miles.

Then:

(i) Vmix=(0.29344)(25,801)(725.42-70)(528)/(760)(570)=6048.1.0

ft3 per test phase.

(ii) H=(43.478)(37.5)(22.02)/[725.42-(22.02x37.5/100)]=50 grains of

water per pound of dry air.

(iii) KH=1/[1-0.0047(50-75)]=0.8951.

(iv) COe=[1-(0.01+0.005 x 3.487) x 0.469)

[[Page 34350]]

-0.000323(37.5)) x 98.8=96.332 ppm.

(v) COd=(1-0.000323(37.5)) x 1.195=1.181 ppm.

(vi)

[GRAPHIC][TIFF OMITTED]TR30JN95.012

(vii) HCe=14.65

-(0.788)(10.86)=6.092.

(viii)

[GRAPHIC][TIFF OMITTED]TR30JN95.013

(x) CH3OHconc=10.86-0.16(1-1/24.939)=10.71 ppm.

(xi) CH3OHmass=6048.1 x 37.71 x (10.71/1,000,000)=2.44 grams

per test phase.

(xii) HCconc=[14.65 - (0.788)(10.86)] - [2.771 - (0.788)(0.16)]

(1-1/24.94)=3.553 ppm.

(xiii) HCmass=(6048.1)(16.33)(3.553/1,000,000)=0.35 grams per test

phase.

(xiv)

[GRAPHIC][TIFF OMITTED]TR30JN95.014

(xv)

[GRAPHIC][TIFF OMITTED]TR30JN95.015

(xvi) HCHOconc=0.664-0.0075(1-1/24.939)=0.6568 ppm.

(xvii) HCHOmass=(6048.1)(35.36)(0.6568/1,000,000)=0.1405 grams per

test phase.

(xviii) THCE=0.35+(13.8756/32.042)(2.44)+(13.8756/

30.0262)(0.1405)=1.47 grams per test phase.

(xix) NOXconc=5.273-(0.146)(1-1/24.939)=5.13 ppm.

(xx) NOXmass=(6048.1)(54.16)(5.13/1,000,000)(0.8951)=1.505 grams

per test phase.

(xxi) COconc=96.332-1.181(1-1/24.939)=95.2 ppm.

(xxii) COmass=(6048.1)(32.97)(95.2/1,000,000)=18.98 grams per test

phase.

(xxiii) CO2conc=0.469-0.039(1-1/24.939)=0.432 percent.

(xxiv) CO2mass=(6048.1)(51.85)(0.432/100)=1353 grams.

(xxv) CH4conc=2.825-2.019(1-1/24.939)=0.89 ppm.

(xxvi) NMHCconc=3.553 ppm-0.89 ppm=2.67 ppm.

(xxvii) NMHCmass=(6048.1)(16.33)(2.67/1,000,000)=0.263 grams per

test phase.

(xxviii) NMHCEmass=0.263+(13.8756/32.042)(2.44)+(13.8756/

30.0262)(0.1405)=1.39 grams per test phase.

(2) For the stabilized portion of the cold start test assume that

similar calculations resulted in the following:

(i) THCE=0.143 grams per test phase.

(ii) NOXmass=0.979 grams per test phase.

(iii) COmass=0.365 grams per test phase.

(iv) CO2mass=1467 grams per test phase.

(v) Ds=3.854 miles.

(vi) NMHCE=0.113 grams per test phase.

(3) For the ``transient'' portion of the hot start test assume that

similar calculations resulted in the following:

(i) THCE=0.488 grams as carbon equivalent per test phase.

(ii) NOXmass=1.505 grams per test phase.

(iii) COmass=3.696 grams per test phase.

(iv) CO2mass=1179 grams per test phase.

(v) Dht=3.577 miles.

(vi) NMHCE=0.426 grams per test phase.

(4) Weighted emission results:

(i)

[GRAPHIC][TIFF OMITTED]TR30JN95.016

(ii)

[[Page 34351]]

[GRAPHIC][TIFF OMITTED]TR30JN95.017

(iii)

[GRAPHIC][TIFF OMITTED]TR30JN95.018

(iv)

[GRAPHIC][TIFF OMITTED]TR30JN95.019

(v)

[GRAPHIC][TIFF OMITTED]TR30JN95.020

34. Section 86.509-90 of Subpart F is amended by revising

paragraphs (a)(2)(i) through (a)(2)(iv), (a)(3), text of paragraph

(a)(4) preceding the figure, paragraphs (b) introductory text, (b)(4),

(b)(5), (b)(6), (c) introductory text, (c)(4) and (c)(5), (c)(6), and

adding paragraphs (a)(5) and (d) to read as follows:

Sec. 86.509-90 Exhaust gas sampling system.

(a) * * *

(2) * * *

(i) Using a duct of unrestricted length maintained at a temperature

above the maximum dew point of the exhaust, but below 121 deg.C

(250 deg.F); heating and possibly cooling capabilities are required; or

(ii) Using a short duct (up to 12 feet long) constructed of smooth

wall pipe with a minimum of flexible sections, maintained at a

temperature above the maximum dew point of the exhaust, but below

121 deg.C (250 deg.F), prior to the test and during any breaks in the

test and uninsulated during the test (insulation may remain in place

and/or heating may occur during testing provided maximum temperature is

not exceeded); or

(iii) Using smooth wall duct less than five feet long with no

required heating. A maximum of two short flexible connectors are

allowed under this option; or

(iv) Omitting the duct and performing the exhaust gas dilution

function at the motorcycle tailpipe exit.

(3) Positive displacement pump. The Positive Displacement Pump-

Constant Volume Sampler (PDP-CVS), Figure F90-1 satisfies the first

condition by metering at a constant temperature and pressure through

the pump. The total volume is measured by counting the revolutions made

by the calibrated positive displacement pump. The proportional samples

are achieved by sampling at a constant flow rate. For methanol-fueled

motorcycle sample lines for the methanol and formaldehyde samples are

heated to prevent condensation. The temperature of the sample lines

shall be more than 3 deg.C (5 deg.F) above the maximum dew point of

the sample, but below 121 deg.C (250 deg.F). (Note: For 1990 through

1994 model year methanol-fueled motorcycles, methanol and formaldehyde

sampling may be omitted provided the bag sample (hydrocarbons and

methanol) is analyzed using a HFID calibrated with methanol.)

BILLING CODE 6560-50-P

[[Page 34352]]

[GRAPHIC][TIFF OMITTED]TR30JN95.045

BILLING CODE 6560-50-C

[[Page 34353]]

(4) Critical flow venturi. The operation of the Critical Flow

Venturi--Constant Volume Sampler (CFV-CVS) sample system, Figure F90-2,

is based upon the principles of fluid dynamics associated with critical

flow. Proportional sampling throughout temperature excursions is

maintained by use of small CFVs in the sample lines, which respond to

the varying temperatures in the same manner as the main CFV. For

methanol-fueled motorcycles, the methanol and formaldehyde sample lines

are heated to prevent condensation. The temperature of the sample lines

shall be more than 3 deg.C (5 deg.F) above the maximum dew point of the

sample, but below 121 deg.C (250 deg.F). Care must be taken to ensure

that the CFVs of the sample probes are not heated since heating of the

CFVs would cause loss of proportionality. (Note: For 1990 through 1994

model year methanol-fueled motorcycles, methanol and formaldehyde

sampling may be omitted provided the bag sample (hydrocarbons and

methanol) is analyzed using a HFID calibrated with methanol.) Total

flow per test is determined by continuously computing and integrating

instantaneous flow. A low response time temperature sensor is necessary

for accurate flow calculation.

* * * * *

(5) Electronic Flow Control. The Critical Flow Venturi--Electronic

Flow Control--Constant Volume Sampler (CFV-EFC-CVS) system is identical

to the CFV-CVS system described in paragraphs (a)(4) and (c) of this

section, except that it maintains proportional sampling for methanol

and formaldehyde by measuring the CVS flow rate, and electronically

controlling sample flow rates. It is recommended that sample volumes be

measured by separate flow meters. For methanol-fueled motorcycles, the

samples lines for the methanol and formaldehyde samples are heated to

prevent condensation. The temperature of the sample lines shall be more

than 20 deg.F (11 deg.C) above the maximum dew point of the sample,

but below 121 deg.C (250 deg.F).

* * * * *

(b) Component description, PDP-CVS. The PDP-CVS, Figure F90-1,

consists of a dilution air filter and mixing assembly, heat exchanger,

positive displacement pump, sampling systems including, probes and

sampling lines which, in the case of the methanol-fueled motorcycles,

are heated to prevent condensation (heating of the sample lines may be

omitted, provided the methanol and formaldehyde sample collection

systems are close coupled to the probes thereby preventing loss of

sample due to cooling and resulting condensation in the sample lines),

and associated valves, pressure and temperature sensors. The PDP-CVS

shall conform to the following requirements:

* * * * *

(4) The location of the dilution air inlet shall be placed so as to

use test-cell air for dilution and the flow capacity of the CVS shall

be large enough to completely eliminate water condensation in the

dilution and sampling systems. Control of water condensation with

methanol-fueled vehicles is critical. Additional care may also be

required to eliminate water condensation when testing natural gas and

liquefied petroleum gas-fueled vehicles. (Procedures for determining

CVS flow rates are detailed in ``Calculation of Emissions and Fuel

Economy When Using Alternative Fuels,'' EPA 460/3-83-009.)

Dehumidifying the dilution air before entering the CVS is allowed.

Heating the dilution air is also allowed, provided:

(i) The air (or air plus exhaust gas) temperature does not exceed

121 deg.C (250 deg.F).

(ii) Calculation of the CVS flow rate necessary to prevent water

condensation is based on the lowest temperature encountered in the CVS

prior to sampling. (It is recommended that the CVS system be insulated

when heated dilution air is used.)

(iii) The dilution ratio is sufficiently high to prevent

condensation in bag samples as they cool to room temperature.

(5) Sample collection bags for dilution air and exhaust samples

(hydrocarbons and carbon monoide) shall be of sufficient size so as not

to impede sample flow. A single dilution air sample, covering the total

test period, may be collected for the determination of methanol and

formaldehyde background (methanol-fueled motorcycles).

(6) The methanol sample collection system and the formaldehyde

sample collection system shall each be of sufficient capacity so as to

collect samples of adequate size for analysis without significant

impact on the volume of dilute exhaust passing through the PDP. The

systems shall also comply with the following requirements that apply to

the design of the systems, not to individual tests:

(i) The methanol system shall be designed such that if a test

motorcycle continuously emitted the maximum allowable level of methanol

(based on all applicable standards) the measured concentration in the

primary impinger would exceed either 25 mg/l or a concentration equal

to 25 times the limit of detection for the GC analyzer.

(ii) The formaldehyde system shall be designed such that if a test

motorcycle continuously emitted formaldehyde at a rate equal to twenty

percent of the maximum allowable level of THCE (i.e., 1.0 g/km for a

5.0 g/km standard), or the maximum formaldehyde level allowed by a

specific formaldehyde standard, whichever is less, the concentration of

formaldehyde in the DNPH solution of the primary impinger, or solution

resulting from the extraction of the DNPH cartridge, shall exceed

either 2.5 mg/l or a concentration equal to 25 times the limit of

detection for the HPLC analyzer.

(iii) The methanol and formaldehyde systems shall be designed such

that the primary impinger collects at least 90 percent of the analyte

in the samples. The remaining analyte shall be collected by the

secondary impinger. This requirement does not apply to dilution air

samples, since they do not require secondary impingers, or to samples

in which the concentrations approach the limit of detection.

(c) Component description, CFV-CVS. The CFV-CVS sample system,

Figure F90-2, consists of a dilution air filter and mixing assembly, a

cyclone particulate separator, unheated sampling venturies for the bag

samples, and for the methanol and formaldehyde samples from methanol-

fueled vehicles, samples lines heated to prevent condensation for the

methanol and formaldehyde samples from methanol fueled vehicles

(heating of the sample lines may be omitted provided, the methanol and

formaldehyde sample collection systems are close coupled to the probes

thereby preventing loss of sample due to cooling and resulting

condensation in the sample lines), a critical flow venturi, and

assorted valves, and pressure and temperature sensors. The CFV sample

system shall conform to the following requirements:

* * * * *

(4) The location of the dilution air inlet shall be placed so as to

use test-cell air for dilution and the flow capacity of the CVS shall

be large enough to completely eliminate water condensation in the

dilution and sampling systems. Control of water condensation with

methanol-fueled vehicles is critical. Additional care may also be

required to eliminate water condensation when testing natural gas and

liquefied petroleum gas-fueled vehicles. (Procedures for determining

CVS flow rates are detailed in

[[Page 34354]]

``Calculation of Emissions and Fuel Economy When Using Alternative

Fuels,'' EPA 460/3-83-009.) Dehumidifying the dilution air before

entering the CVS is allowed. Heating the dilution air is also allowed,

provided:

(i) The air (or air plus exhaust gas) temperature does not exceed

250 deg.F.

(ii) Calculation of the CVS flow rate necessary to prevent water

condensation is based on the lowest temperature encountered in the CVS

prior to sampling. (It is recommended that the CVS system be insulated

when heated dilution air is used.)

(iii) The dilution ratio is sufficiently high to prevent

condensation in bag samples as they cool to room temperature.

(5) Sample collection bags for dilution air and exhaust samples

(hydrocarbons and carbon monoxide) shall be of sufficient size so as

not to impede sample flow. A single dilution air sample, covering the

total test period, may be collected for the determination of methanol

and formaldehyde background (methanol-fueled motorcycles).

(6) The methanol sample collection system and the formaldehyde

sample collection system shall each be of sufficient capacity so as to

collect samples of adequate size for analysis without significant

impact on the volume of dilute exhaust passing through the CVS. The

systems shall also comply with the following requirements that apply to

the design of the systems, not to individual tests:

(i) The methanol system shall be designed such that if a test

motorcycle continuously emitted the maximum allowable level of methanol

(based on all applicable standards) the measured concentration in the

primary impinger would exceed either 25 mg/l or a concentration equal

to 25 times the limit of detection for the GC analyzer.

(ii) The formaldehyde system shall be designed such that if a test

motorcycle continuously emitted formaldehyde at a rate equal to twenty

percent of the maximum allowable level of THCE (i.e., 1.0 g/km for a

5.0 g/km standard), or the maximum formaldehyde level allowed by a

specific formaldehyde standard, whichever is less, the concentration of

formaldehyde in the DNPH solution of the primary impinger, or solution

resulting from the extraction of the DNPH cartridge, shall exceed

either 2.5 mg/l or a concentration equal to 25 times the limit of

detection for the HPLC analyzer.

(iii) The methanol and formaldehyde systems shall be designed such

that the primary impinger collects at least 90 percent of the analyte

in the samples. The remaining analyte shall be collected by the

secondary impinger. This requirement does not apply to dilution air

samples, since they do not require secondary impingers, or to samples

in which the concentrations approach the limit of detection.

(d) Component description, CFV-EFC-CVS. The CVS sample system is

identical to the system described in paragraph (c) of this section,

plus includes a means of electronically measuring the CVS flow rate,

and electronic mass flow controllers for the methanol and formaldehyde

sample lines, and separate flow meters to totalize sample flow volumes

(optional). The EFC sample system shall conform to all of the

requirements listed in paragraph (c) of this section, except that the

methanol and formaldehyde samples mat both be drawn from a single

static probe. It also must comply with the following additional

requirements:

(1) The ratio of the CVS flow rate to the sample flow rate shall

not deviate from the ratio at the start of the test by more than

5 percent. (The volumetric sample flow rate shall be varied

inversely with the square root of the bulk stream temperature.)

(2) Flow totalizers for methanol and/or formaldehyde samples shall

have an accuracy of 2 percent. Total sample volumes may be

obtained from the flow controllers, with the advance approval of the

administrator, provided that the controllers can be shown to have an

accuracy of 2 percent.

35. Section 86.513-94 of Subpart F is amended by revising

paragraphs (c)(1) and (c)(2), and adding paragraph (c)(3) to read as

follows:

Sec. 86.513-94 Fuel and engine lubricant specifications.

* * * * *

(c) * * * (1) mixtures of petroleum and methanol fuels used for

exhaust and evaporative emission testing and service accumulation for

flexible fuel motorcycles shall consist of the petroleum fuel listed in

paragraph (a) of this section and the methanol fuel listed in paragraph

(b), and shall be within the range of fuel mixtures for which the

vehicle was designed, as reported in accordance with Sec. 86.90-21. The

Administrator may use any fuel or fuel mixture within this range for

testing.

(2) The fuel mixtures used by the manufacturers shall be sufficient

to demonstrate compliance over the full design range, and shall

include:

(i) For emission testing,

(A) The petroleum fuel specified in paragraph (a) or (b),

(B) A methanol fuel representative of the methanol fuel expected to

the found in use, as specified in paragraph (b),

(ii) For service accumulation, an alternating combination of the

fuels specified in paragraphs (a) and (b) will be used to demonstrate

the durability of the emission control systems based on good

engineering judgement. The combination shall be selected such that the

cumulative volumes of both the methanol fuel and the petroleum fuel

used shall be at least twenty-five percent of the total fuel volume.

The fuels shall be alternated at mileage intervals not to exceed 1,000

kilometers.

(3) The specification range of the fuels to be used under paragraph

(c) of this section shall be reported in accordance with Sec. 86.094-

21.

* * * * *

36. Section 86.514-78 of Subpart F is amended by revising

paragraphs (a)(2) and (b), and adding paragraph (c) to read as follows:

Sec. 86.514-78 Analytical gases.

(a) * * *

(2) Gases for the THC analyzer shall be:

(i) Single blends of propane using air as the diluent; and

(ii) Optionally, for response factor determination, single blends

of methanol using air as the diluent.

* * * * *

(b) Calibration gases (not including methanol) shall be known to

within 2 percent of true values.

(c) Methanol in air gases used for response factor determination

shall:

(1) Be traceable to within 2 percent of NIST (formerly

NBS) gas standards, or other gas standards which have been approved by

the Administrator; and

(2) Remain within 2 percent of the labeled

concentration. Demonstration of stability shall be based on a quarterly

measurement procedure with a precision of 2 percent (two

standard deviations), or other method approved by the Administrator.

The measurement procedure may incorporate multiple measurements. If the

true concentration of the gas changes by more than two percent, but

less than ten percent, the gas may be relabeled with the new

concentration.

37. Section 86.516-90 of Subpart F is amended by revising paragraph

(c)(1) to read as follows:

Sec. 86.516-90 Calibrations, frequency and overview.

* * * * *

(c) * * *

(1) Calibrate the hydrocarbon analyzer, methane analyzer, carbon

dioxide analyzer, carbon monoxide

[[Page 34355]]

analyzer, and oxides of nitrogen analyzer (certain analyzers may

require more frequent calibration depending on particular equipment and

uses).

* * * * *

38. Section 86.519-90 of Subpart F is amended by revising

paragraphs (d)(1), (d)(4), and (d)(7) to read as follows:

Sec. 86.519-90 Constant volume sampler calibration.

* * * * *

(d) * * *

(1) Obtain a small cylinder that has been charged with pure propane

or carbon monoxide gas (CAUTION--carbon monoxide is poisonous).

* * * * *

(4) Following completion of step (3) above (if methanol injection

is required), continue to operate the CVS in the normal manner and

release a known quantity of pure methanol (in gaseous form) into the

system during the sampling period (approximately 5 minutes). This step

does not need to be performed with each verification, provided that it

is performed at least twice annually.

* * * * *

(7) The cause for any discrepancy greater than 2

percent must be found and corrected. The Administrator, upon request,

may waive the requirement to comply with 2 percent methanol

recovery tolerance, and instead require compliance with a higher

tolerance (not to exceed 6 percent), provided that:

(i) The Administrator determines that compliance with the specified

tolerance is not practically feasible; and

(ii) The manufacturer makes information available to the

Administrator which indicates that the calibration tests and their

results are consistent with good laboratory practice, and that the

results are consistent with the results of calibration testing

conducted by the Administrator.

39. Section 86.521-90 of Subpart F is amended by revising

paragraphs (d) introductory text, (d)(1), and (d)(3)(iii) to read as

follows:

Sec. 86.521-90 Hydrocarbon analyzer calibration.

* * * * *

(d) FID response factor to methanol. When the FID analyzer is to be

used for the analysis of hydrocarbon samples containing methanol, the

methanol response factor of the analyzer shall be established. The

methanol response factor shall be determined at several concentrations

in the range of concentrations in the exhaust sample, using either bag

samples or gas bottles meeting the requirements of Sec. 86.514.

(1) The bag sample, if used, of methanol for analysis in the FID

shall be prepared using the apparatus shown in Figure F90-4. A known

volume of methanol is injected, using a microliter syringe, into the

heated mixing zone (250 deg.F (121 deg.C)) of the apparatus. The

methanol is vaporized and swept into the sample bag with a known volume

of zero grade air measured by a gas flow meter meeting the performance

requirements of Sec. 86.120.

BILLING CODE 6560-50-P

[[Page 34356]]

[GRAPHIC][TIFF OMITTED]TR30JN95.046

BILLING CODE 6560-50-C

[[Page 34357]]

* * * * *

(3) * * *

(iii) SAMppm=methanol concentration in the sample bag, or gas bottle,

in ppmC. SAMppm for sample bags:

[GRAPHIC][TIFF OMITTED]TR30JN95.021

Where:

* * * * *

40. Section 86.523-78 of Subpart F is amended by adding paragraph

(c) to read as follows:

Sec. 86.523-78 Oxides of nitrogen analyzer calibration.

* * * * *

(c) When testing methanol-fueled motorcycles, it may be necessary

to clean the analyzer frequently to prevent interference with NOX

measurements (see EPA/600/S3-88/040).

41. Section 86.527-90 of Subpart F is amended by adding paragraph

(e) to read as follows:

Sec. 86.527-90 Test procedures, overview.

* * * * *

(e) Background concentrations are measured for all species for

which emissions measurements are made. For exhaust testing, this

requires sampling and analysis of the dilution air. (When testing

methanol-fueled motorcycles, manufacturers may choose not to measure

background concentrations of methanol and/or formaldehyde, and then

assume that the concentrations are zero during calculations.)

42. Section 86.537-90 of Subpart F is amended by revising

paragraphs (b)(4), (b)(6)(iii), (b)(6)(iv), (b)(12), and (b)(14), and

by removing the note following paragraph (b)(6)(iv) to read as follows:

Sec. 86.537-90 Dynamometer test runs.

* * * * *

(b) * * *

(4) For methanol-fueled vehicles, with the sample selector valves

in the ``standby'' position, insert fresh sample collection impingers

into the methanol sample collection system, fresh impingers or a fresh

cartridge into the formaldehyde sample collection system and fresh

impingers (or a single cartridge for formaldehyde) into the dilution

air sample collection systems for methanol and formaldehyde (background

measurements of methanol and formaldehyde may be omitted and

concentrations assumed to be zero for calculations in Sec. 86.544).

* * * * *

(6) * * *

(iii) For methanol samples, the flow rates shall be set such that

the system meets the design criteria of Sec. 86.509. For samples in

which the concentration in the primary impinger exceeds 0.5 mg/l, it is

recommended that the mass of methanol collected in the secondary

impinger not exceed ten percent of the total mass collected. For

samples in which the concentration in the primary impinger does not

exceed 0.5 mg/l, secondary impingers do not need to be analyzed.

(iv) For formaldehyde samples, the flow rates shall be set such

that the system meets the design criteria of Sec. 86.509. For impinger

samples in which the concentration of formaldehyde in the primary

impinger exceeds 0.1 mg/l, it is recommended that the mass of

formaldehyde collected in the secondary impinger not exceed ten percent

of the total mass collected. For samples in which the concentration in

the primary impinger does not exceed 0.1 mg/l, secondary impingers do

not need to be analyzed.

* * * * *

(12) At the end of the deceleration which is scheduled to occur at

505 seconds, simultaneously switch the sample flows from the

``transient'' bags and samples to ``stabilized'' bags and samples,

switch off gas flow measuring device No. 1 and, start gas flow

measuring device No. 2. Before the acceleration which is scheduled to

occur at 510 seconds, record the measured roll or shaft revolutions and

reset the counter or switch to a second counter. As soon as possible,

transfer the ``stabilized'' exhaust and dilution air samples to the

analytical system and process the samples according to Sec. 86.540,

obtaining a stabilized reading of the exhaust bag sample on all

analyzers within 20 minutes of the end of the sample collection phase

of the test. Obtain methanol and formaldehyde sample analyses, if

applicable, within 24 hours of the end of the sample period. (If it is

not possible to perform analysis on the methanol and formaldehyde

samples within 24 hours, the samples should be stored in a dark cold

(4-10 deg.C) environment until analysis. The samples should be analyzed

within fourteen days.)

* * * * *

(14) Five seconds after the engine stops running, simultaneously

turn off gas flow measuring device No. 2 and position the sample

selector valves to the ``standby'' position (and open the valves

isolating particulate filter No. 1, if applicable). Record the measured

roll or shaft revolutions (both gas meter or flow measurement

instrumentation readings) and re-set the counter. As soon as possible,

transfer the ``stabilized'' exhaust and dilution air samples to the

analytical system and process the samples according to Sec. 86.540,

obtaining a stabilized reading of the exhaust bag sample on all

analyzers within 20 minutes of the end of the sample collection phase

of the test. Obtain methanol and formaldehyde sample analyses, if

applicable, within 24 hours of the end of the sample period. (If it is

not possible to perform analysis on the methanol and formaldehyde

samples within 24 hours, the samples should be stored in a dark cold

(4-10 deg.C) environment until analysis. The samples should be analyzed

within fourteen days.)

* * * * *

43. Section 86.540-90 of Subpart F is amended by revising

paragraphs (b) and (c) to read as follows:

Sec. 86.540-90 Exhaust sample analysis.

* * * * *

(b) For CH3OH (methanol-fueled vehicles), introduce test

samples into the gas chromatograph and measure the concentration. This

concentration is CMS in the calculations.

(c) For HCHO (methanol-fueled vehicles), introduce test samples

into the high pressure liquid chromatograph and measure the

concentration of formaldehyde as a dinitropheylhydrazine derivative in

acetonitrile. This concentration is CFS in the calculations.

44. Section 86.542-90 of Subpart F is amended by revising paragraph

(p) to read as follows:

Sec. 86.542-90 Records required.

* * * * *

(p) Additional required records for methanol-fueled vehicles:

(1) Specification of the methanol fuel, or fuel mixtures, used

during testing.

(2) Volume of sample passed through the methanol sampling system

and the volume of deionized water in each impinger.

[[Page 34358]]

(3) The methanol calibration information from the GC standards.

(4) The concentration of the GC analyses of the test samples

(methanol).

(5) Volume of sample passed through the formaldehyde sampling

system.

(6) The formaldehyde calibration information from the HPLC

standards.

(7) The concentration of the HPLC analysis of the test sample

(formaldehyde).

* * * * *

45. Section 86.544-90 of Subpart F is amended by revising

paragraphs (c)(5)(iv) through (c)(5)(xvi), and (c)(7)(ii), and removing

paragraphs (c)(5)(xvii), (c)(5)(xviii), and (e) to read as follows:

Sec. 86.544-90 Calculations; exhaust emissions.

* * * * *

(c) * * *

(5) * * *

(iv)(A) CCH3OHe=Methanol concentration in the dilute exhaust, ppm.

(B)

[GRAPHIC][TIFF OMITTED]TR30JN95.022

(v)(A) CCH3OHd=Methanol concentration in the dilution air, ppm.

[GRAPHIC][TIFF OMITTED]TR30JN95.023

(B)

(vi) TEM=Temperature of methanol sample withdrawn from dilute

exhaust, deg.R.

(vii) TDM=Temperature of methanol sample withdrawn from dilution

air, deg.R.

(viii) PB=Barometric pressure during test, mm Hg.

(ix) VEM=Volume of methanol sample withdrawn from dilute exhaust,

ft\3\.

(x) VDM=Volume of methanol sample withdrawn from dilution air,

ft\3\.

(xi) Cs=GC concentration of sample drawn from dilute exhaust,

g/ml.

(xii) CD=GC concentration of sample drawn from dilution air,

g/ml.

(xiii) AVs=Volume of absorbing reagent (deionized water) in

impinger through which methanol sample from dilute exhaust is drawn,

ml.

(xiv) AVD=Volume of absorbing reagent (deionized water) in

impinger through which methanol sample from dilution air is drawn, ml.

(xv) 1=first impinger.

(xvi) 2=second impinger.

* * * * *

(7) * * *

(ii) For methanol-fueled, natural gas-fueled or liquefied petroleum

gas-fueled motorcycles, where fuel composition is CxHyOz

as measured, or calculated, for the fuel used (for natural gas and

liquefied petroleum gas-fuel, Z=0):

[GRAPHIC][TIFF OMITTED]TR30JN95.024

* * * * *

46. Section 86.1207-90 of Subpart M is amended by revising

paragraphs (b)(1) introductory text and (c)(2), and adding paragraph

(b)(3) to read as follows:

Sec. 86.1207-90 Sampling and analytical system; evaporative emissions.

* * * * *

(b) * * *

(1) For gasoline and methanol-fueled vehicles a hydrocarbon

analyzer utilizing the hydrogen flame ionization principle (FID) shall

be used to monitor the atmosphere within the enclosure (a heated FID

(HFID)(235 deg.15 deg.F (1138 deg.C)) is

recommended for methanol-fueled vehicles). Instrument bypass flow may

be returned to the enclosure. The FID shall have a response time to 90

percent of final reading of less than 1.5 seconds, and be capable of

meeting performance requirements expressed as a function of Cstd: where

Cstd is the specific enclosure hydrocarbon level, in ppm, corresponding

to the evaporative emission standard:

* * * * *

(3) The methanol sampling system described in paragraph (b)(2) of

this section shall be designed such that, if a test vehicle emitted the

maximum allowable level of methanol (based on all applicable standards)

during any phase of the test, the measured concentration in the primary

impinger would exceed either 25 mg/l or a concentration equal to 25

times the limit of detection for the GC analyzer, and such that the

primary impinger collects at least 90 percent of the analyte in the

samples. The remaining analyte shall be collected by the secondary

impinger. The provisions of this paragraph apply to the design of

sampling systems, not to individual tests.

(c) * * *

(2) For the methanol sample, permanent records shall be made of the

following: the volumes of deionized water introduced into each

impinger, the rate and time of sample collection and the chromatogram

of the analyzed sample.

* * * * *

47. Section 86.1207-96 of Subpart M is amended by revising

paragraphs (b)(1) and (c)(2), and adding paragraph (b)(3) to read as

follows:

Sec. 86.1207-96 Sampling and analytical systems; evaporative

emissions.

* * * * *

[[Page 34359]]

(b) * * *

(1) For gasoline-, liquefied petroleum gas-, natural gas- and

methanol-fueled vehicles a hydrocarbon analyzer utilizing the hydrogen

flame ionization principle (FID) shall be used to monitor the

atmosphere within the enclosure (a heated FID

(HFID)(235 deg.15 deg.F (1138 deg.C)) i

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