Implementation of the United Nations Recommendations, International Maritime Dangerous Goods Code, and International Civil Aviation Organization's Technical Instructions; Final Rule DEPARTMENT OF TRANSPORTATION
Federal RegisterDec 29, 1994
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SUMMARY: This final rule amends the Hazardous Materials Regulations to
maintain alignment with corresponding provisions of international
standards. Because of recent changes to the International Maritime
Dangerous Goods Code (IMDG Code), the International Civil Aviation
Organization's Technical Instructions for the Safe Transport of
Dangerous Goods by Air (ICAO Technical Instructions), and the United
Nations Recommendations on the Transport of Dangerous Goods (UN
Recommendations), these revisions are necessary to facilitate the
transport of hazardous materials in international commerce.
DATES: Effective: October 1, 1995.
Compliance date: Compliance with the regulations, as amended
herein, is authorized as of January 1, 1995.
Incorporation by reference: The incorporation by reference of
certain publications listed in these amendments has been approved by
the Director of the Federal Register as of October 1, 1995.
FOR FURTHER INFORMATION CONTACT: Bob Richard, Assistant International
Standards Coordinator, telephone (202) 366-0586, Beth Romo or John
Gale, Office of Hazardous Materials Standards, telephone (202) 366-
8553, Hazardous Materials Safety, Research and Special Programs
Administration, U.S. Department of Transportation, 400 Seventh Street,
SW., Washington, DC 20590-0001.
SUPPLEMENTARY INFORMATION:
I. Background
On December 21, 1990, the Research and Special Programs
Administration (RSPA) published a final rule [Docket HM-181; 55 FR
52402] which comprehensively revised the Hazardous Materials
Regulations (HMR), 49 CFR Parts 171 to 180, with respect to hazard
communication, classification, and packaging requirements, based on the
UN Recommendations. One intended effect of the rule was to facilitate
the international transportation of hazardous materials by ensuring a
basic consistency between the HMR and international regulations.
The UN Recommendations are not regulations, but are recommendations
issued by the UN Committee of Experts on the Transport of Dangerous
Goods. These recommendations are amended and updated biennially by the
Committee of Experts and are distributed to nations throughout the
world. They serve as the basis for international modal regulations;
specifically the IMDG Code, issued by the International Maritime
Organization (IMO), and the ICAO Technical Instructions. In 49 CFR
171.12, the HMR authorize shipments prepared in accordance with the
IMDG Code if all or part of the transportation is by vessel, subject to
certain conditions and limitations. Offering, accepting and
transporting hazardous materials by aircraft, in conformance with the
ICAO Technical Instructions, and by motor vehicle either before or
after being transported by aircraft, are authorized in Sec. 171.11
(with certain exceptions).
On December 22, 1992, RSPA issued an interim final rule [Docket HM-
215; 57 FR 60738] amending Sec. 171.7 by incorporating the 1993-1994
edition of the ICAO Technical Instructions and Amendment 26 to the IMDG
Code. This rulemaking action authorized the use of the updated
international regulations, effective January 1, 1993. Amendment 26
promulgated numerous miscellaneous changes to the IMDG Code regarding
classification, labeling, packaging, and documentation. The 1993-1994
edition of the ICAO Technical Instructions contained amendments
relating to the seventh revised edition of the UN Recommendations, as
well as changes specific to air transportation.
The HMR, as revised under Docket HM-181, are largely based on the
sixth revised edition of the UN Recommendations. Selected provisions
from the seventh and eighth revised editions of the UN Recommendations
have been incorporated into the HMR under subsequent Docket HM-181
rulemaking actions.
On July 18, 1994, RSPA issued a Notice of Proposed Rulemaking
(NPRM) (Docket HM-215A; 59 FR 36488), which proposed changes to more
fully align the HMR with the seventh and eighth revised editions of the
UN Recommendations. Such changes would provide consistency with the
international air and sea transport requirements which, effective
January 1, 1995, will be aligned with the eighth revised edition of the
UN Recommendations.
II. Summary of Comments
RSPA received nearly 120 comments to the proposed rule from
chemical manufacturers and distributors, carriers, model rocket users,
and industry associations representing hazardous materials offerors,
carriers, and packaging manufacturers and reconditioners. Commenters
supported RSPA's effort to align the HMR with international standards
to provide consistency and facilitate the international transportation
of hazardous materials. Major issues identified by commenters included:
(1) The purported need for a delay in the effective date of the final
rule to allow an orderly transition from old to new requirements; (2)
possible expansion of proposed provisions to allow reuse of certain UN
standard packagings without leakproofness testing; (3) a request from
model rocket users to clarify proposed packaging requirements for model
rockets; (4) proposed removal of an exception for shipments transported
within a port area; (5) reciprocal treatment of foreign-manufactured
packagings; (6) proposed changes in criteria for corrosivity testing;
and (7) proposed subsidiary labeling and terminology changes. A more
detailed discussion of the comments and rulemaking actions in response
to these comments is provided in the following summary.
III. Summary of Regulatory Changes by Section
Part 171
Section 171.7. Various standards, such as those issued by the
International Organization for Standardization (ISO), the American
Society for Testing and Materials (ASTM), and Transport Canada, are
added or updated, and the most current versions of the ICAO Technical
Instructions, the IMDG Code, and the UN Recommendations are
incorporated.
Section 171.8. New definitions for ``Asphyxiant gas,'' ``Gas,''
``Oxidizing gas'' and ``Siftproof packaging'' are added, and
definitions for ``Box,'' ``Liquid,'' ``Overpack,'' ``Solid'' and ``UN
standard packaging'' are revised for consistency with the seventh and
eighth revised editions of the UN Recommendations. Two commenters asked
RSPA to delete the word ``Small'' in the proposed revision of the
definition for ``box''. These commenters claimed that the term was
ambiguous and could lead to differing interpretations by various
enforcement agencies. RSPA agrees and is replacing the wording ``Small
holes'' with the phrase ``Holes appropriate to the size and use of the
packaging''. One of the commenters further asked RSPA to clarify
whether the openings in the box may be designed for uses other than for
ease of handling or opening. RSPA believes the wording ``such as ease
of handling or opening, or to meet classification requirements''
proposed in the NPRM offers sufficient examples of uses for openings
and, therefore, is not amending this text in the final rule. The
definition for ``UN standard packaging'' is revised to clarify that it
applies to both U.S.-manufactured and foreign-manufactured packagings
and to delete reference to Subparts L and M of Part 178.
Section 171.11. Paragraph (d)(5) is adopted as proposed to include
the word ``toxic'' as an appropriate reference to a poison.
Section 171.12. Paragraph (b) is revised as proposed. RSPA is
amending Secs. 171.12(b) and 176.27(c) to reference IMDG Code
requirements for a container packing certification for freight
containers and transport units intended for carriage by vessel. This
requirement applies to persons who load hazardous materials for
transportation (including freight forwarders, freight consolidators and
non-vessel operating common carriers) or transport hazardous materials
by vessel. A freight container packing certification requirement was
adopted several years ago under Amendment 24 to the IMDG Code and
became effective worldwide on January 1, 1994, as mandated under the
International Convention on Safety of Life at Sea (SOLAS Convention).
When hazardous materials are packed into a freight container or
transport vehicle for transportation by vessel, those responsible for
packing the unit must provide a certificate or declaration to the
carrier attesting that the container is suitable for transport, that it
contains compatible materials in packages that have been properly
inspected, packed, and secured, and the container and packages are
properly marked, labeled, and placarded. This certification may appear
either in a separate document or in a signed statement provided on the
dangerous goods shipping document. Because the U.S. is a signatory to
the SOLAS Convention, RSPA is adopting a similar container packing
certification requirement under the HMR.
In the NPRM, RSPA proposed removal of wording in paragraph (c)
which allows hazardous materials being imported into or exported from
the U.S. to comply with IMDG Code regulations in port areas. Commenters
responding to this proposal opposed the removal of this wording; they
claimed that a requirement for hazardous materials being imported into
or exported from the U.S. to comply with the HMR in a port area would
impose an economic burden on the industry and would be a barrier to
trade. Paragraph (c) is not being revised in this final rule. RSPA
plans to address the port area issue in greater detail in a future
rulemaking proceeding.
Section 171.14. This section is revised to provide a delayed
implementation date for amendments adopted in this final rule. RSPA
also is removing obsolete transition dates provided under the Docket
HM-181 final rule and its subsequent revisions. A new paragraph (a)
contains all remaining transition provisions for implementing changes
adopted under the Docket HM-181 final rules.
The effective date of this final rule is October 1, 1995. However,
RSPA is authorizing a voluntary compliance date of January 1, 1995,
which is consistent with the effective date of new requirements for
international air and vessel shipments and will allow shippers to
prepare their international shipments in accordance with the new ICAO,
IMDG, and HMR provisions. RSPA also is authorizing, in new paragraph
(b), a delay in mandatory compliance with the new requirements, until
October 1, 1996. RSPA believes that an effective date of October 1,
1995, with an additional one-year delay until October 1, 1996, offers a
sufficient phase-in period to implement new provisions and deplete
current stocks of shipping papers, labels and placards, and containers
affected by the new requirements. The October 1, 1996 implementation
date also is consistent with certain Docket HM-181 transition
provisions for maintenance and use of packagings. In addition,
paragraph (b)(2) permits intermixing of old and new hazard
communication requirements and reflects certain intermixing provisions
authorized by the Docket HM-181 final rule.
Part 172
Sections 172.101 and 172.102. RSPA is revising the Hazardous
Materials Table (HMT) and the list of special provisions in
Sec. 172.102 for basic conformance with the eighth revised edition of
the UN Recommendations, the ICAO Technical Instructions (1995-1996
edition) and the 27th edition of the IMDG Code.
The IM tank authorizations are revised for consistency with the
changes in Chapter 12 of the seventh and eighth revised editions of the
UN Recommendations. These changes can be found in the ``T-note''
authorizations that are listed in Column 7 of the HMT.
The aircraft quantity limitations in Column 9 and the vessel
stowage requirements in Column 10 are revised for consistency with the
ICAO Technical Instructions and IMDG Code, respectively. In
Sec. 172.101(k)(1)-(k)(5), revised definitions of the vessel stowage
codes, which are prescribed in the Sec. 172.101 Table, are adopted as
proposed for consistency with the IMDG Code. This revision broadens
current stowage provisions for hazardous materials on cargo vessels to
apply to hazardous materials (such as propane) on passenger vessels
carrying a limited number of passengers. RSPA received two comments
supporting this proposed change.
Changes to the HMT are quite extensive--approximately 33% of the
entries in the HMT are changed. Therefore, RSPA is republishing the
entire HMT in this final rule, but does not believe it is necessary to
discuss every change in this section review. However, in order to
facilitate the reader's understanding of the changes to the HMT, RSPA
is providing a list of all entries that are added, deleted, or made
more restrictive. This list includes all changes in (1) the shipping
name, (2) IM tank authorization, (3) subsidiary labeling, (4)
classification, and (5) packaging. In addition, a discussion of the
more substantive changes is provided.
Numerous editorial changes are made to the HMT to correct
misspellings and errors and to provide more consistency. A corrected
typographical error is not shown in the list of significant changes. In
addition, new generic entries are added for self-heating liquids and
solids. Specific entries for self-reactive materials are removed from
the HMT and replaced with new generic entries.
As discussed in the NPRM, the UN Recommendations, ICAO Technical
Instructions, and IMDG Code have replaced the term ``poisonous'' with
the term ``toxic.'' RSPA proposed to amend proper shipping names in the
HMT that contain the word ``poisonous'' by replacing ``poisonous'' with
the word ``toxic'' to conform to international terminology. For
example, the proper shipping name ``Flammable liquid, poisonous,
n.o.s.'' would read ``Flammable liquid, toxic, n.o.s.''. However, RSPA
also proposed to revise Sec. 172.101(c)(3) to allow the use of the word
``poisonous'' interchangeably with the word ``toxic''. Numerous
commenters provided diverse opinions on this proposal. Highway carriers
and the American Trucking Associations (ATA) believed that emergency
responders would be at greater risk because the word ``toxic'' is
overused and minimizes the seriousness of the poison hazard. They
recommended reinstating ``Poison'' or ``Poisonous'' entries for
domestic transportation. Another commenter thought that the option to
use either term would force emergency response personnel and end users
to deal with situations involving the same product bearing different
labels or placards, depending on shipper preference. On the other hand,
chemical manufacturers and their associations, such as the Chemical
Manufacturers Association (CMA), supported the proposal to allow
interchangeable use of either term. Other commenters, such as the
Hazardous Materials Advisory Council (HMAC) agreed with interchangeable
use, but only for as long as required to deplete stocks of preprinted
materials and conduct training. RSPA believes the interchangeable use
of ``poison'' and ``toxic'' for domestic transportation will provide
flexibility and, therefore, is adopting as proposed the provision to
permit use of either term.
The eighth revised edition of the UN Recommendations added entries
and assigned new UN I.D. numbers for elevated temperature materials.
RSPA is changing the I.D. numbers for elevated temperature materials in
the HMT to correspond with those in the UN Recommendations. RSPA
received comments requesting that RSPA not adopt the proposed
identification numbers for elevated temperature materials. The
commenters noted that the old identification numbers have only been
required since October 1, 1993, and that switching them after only one
year will cause confusion and non-compliance. Another commenter
requested an extended transition period for the change in
identification numbers for elevated temperature materials in order to
dispose of large supplies of markings. With the extended transition
period being provided in this final rule, RSPA believes that any
confusion related to the change of identification numbers will be
minimal. Therefore, RSPA is not accepting commenters' requests and has
adopted the shipping descriptions for elevated temperature materials as
proposed. In addition, RSPA is revising the HOT mark illustrated in
Sec. 172.325(c) to reflect the new UN identification number assigned to
``Elevated temperature material, liquid, n.o.s.''
Currently under the HMR, air bags are assigned to the Division 4.1
hazard class and the proper shipping name is limited to ``Air bag
inflators'' or ``Air bag modules.'' Based on changes in the UN
Recommendations, RSPA is revising the proper shipping name for air bags
to include seat belt pre-tensioners and modules. The new proper
shipping name is ``Air bag inflators or Air bag modules or Seat-belt
modules or Seat-belt pre-tensioners.'' This entry also reflects a
change in classification from Division 4.1 to Class 9, adoption of a
new UN number, and removal of the ``D'' in Column 1.
Two new domestic entries are added for ``toy caps'' and ``model
rocket motors''. Model rocket motors containing 30 grams or less
propellant are classed as Division 1.4S while items containing more
than 30 grams but not more than 62.5 grams of propellant are classed as
Division 1.4C. RSPA received numerous comments requesting a different
packing method for these materials. The commenters requested packing
method E-146(b) instead of packing method E-114 for these materials.
RSPA has not adopted this request to allow the use of packing method E-
146 for these materials, but has modified packing method E-114 to allow
plastic bags as inner packagings.
Two new entries for ``Batteries, containing sodium'' and ``Cells,
containing sodium'' are added in the HMT based on the UN
Recommendations entry (UN 3292). Since these materials were previously
authorized only under the terms of an exemption or competent authority
approval, RSPA is adding a new packaging section, Sec. 173.189, that
prescribes general packaging and transport requirements for these
materials consistent with the UN Recommendations.
Currently, in Column 1, a ``+'' is assigned to certain materials
meeting the criteria of Division 6.1, Packing Group I, toxic by
inhalation, but classed in another hazard class. The eighth revised
edition of the UN Recommendations incorporated revisions to the hazard
classification of these materials to Division 6.1, Packing Group I,
toxic by inhalation. Therefore, the ``+'' is removed from Column 1 for
any liquid poison by inhalation (PIH) material newly classed in
Division 6.1, Packing Group I.
The shipping name ``acetonitrile'' replaces the name ``methyl
cyanide.'' The hazard class for ``Formaldehyde solutions'' currently
shown as Class 9 is revised to Class 8. Numerous generic pesticide
entries are revised to remove the ``n.o.s.'' from the shipping names.
Revised generic shipping descriptions for Division 4.3 materials
are prefaced by the words ``water-reactive'' in lieu of the words
``substances which in contact with water emit''. The prefix of the
identification number for ``Polyester resin kits'' is changed to ``UN''
from ``NA'' and Special Provision 40 is added in Column 7 that
specifies contents and packaging requirements for polyester resin kits.
In addition, Special Provision 117 is removed from the entry
corresponding to ``UN0150.''
The entry for alcoholic beverages is revised in Column 7 to include
Special Provision 24, to indicate that alcoholic beverages with more
than 70 percent alcohol by volume are assigned Packing Group II and
alcoholic beverages containing more than 24 percent but not more than
70 percent alcohol are assigned Packing Group III. In addition,
Sec. 173.150 is revised to increase (to five liters per inner
packaging) the quantity of alcoholic beverage in a packaging excepted
from the HMR and to provide an exception adopted in the UN
Recommendations to permit Packing Group III alcoholic beverages
transported in receptacles of 250 L (66 gallons) or less to be excepted
from the HMR unless transported by air. One commenter requested that
the shipping name ``ethanol'' also include Special Provision 24 because
distilled spirits can be shipped under either ``alcoholic beverages''
or ``ethanol''. RSPA is not accepting this request. As the commenter
noted, the addition of Special Provision 24 is simply a procedural
modification of the existing classification procedure for alcoholic
beverages. RSPA considers this commenter's request outside the scope of
this rulemaking.
RSPA received a comment requesting that the shipping name
``polystyrene beads expandable evolving flammable vapors'', be retained
for domestic transportation. The commenter noted that the name had only
been required since October 1, 1993, and that it is not cost-efficient
to change in such a short period of time. RSPA is not accepting this
request but believes that the lengthy transition period should offset
any additional cost that may be incurred by the shipper.
Several comments were received that objected to the proposal to
remove from the HMT the entry ``Propellant explosive, solid, NA0274,
1.3C''. These commenters requested that this entry be retained because
it allowed them to ship these 1.3C explosives by cargo only aircraft.
RSPA is not adopting this suggestion and is removing this entry from
the HMT. RSPA believes that there is not sufficient justification to
create a domestic exception for Division 1.3 substances or to allow
these explosive substances to be transported by cargo only aircraft
when no other Division 1.3 substance is allowed to be transported by
aircraft.
Several comments were received regarding the shipping name
``azodicarbonamide'', a self-reactive material. Commenters believed
that listing this material was ``superfluous'' considering the new
classification scheme for self-reactive materials. RSPA concurs and has
removed this entry from the HMR.
One commenter requested several editorial changes to the shipping
name ``Jet perforating guns, charged, without detonator'', which are
adopted in this final rule. However, one suggestion, to remove the
words ``without detonator'' from the shipping description, is not
adopted. The commenter stated that packing method US006 allows
detonators to be transported in jet perforating guns; therefore, the
words ``without detonator'' should be removed from the shipping name.
However, US006 only allows detonators to be transported with, not in,
jet perforating guns.
RSPA received comments disagreeing with the removal of the shipping
name ``Petroleum oil''. Commenters stated that the name was important
for compliance with the Oil Pollution Act requirements in 49 CFR Part
130, and requested that a domestic shipping description be added. RSPA
concurs and is retaining the proper shipping name ``Petroleum oil''
with an identification number ``NA1270''.
One commenter suggested that RSPA provide a non-bulk packaging
exception for ``Resin solution'' comparable to the exception provided
for paint under Sec. 173.173 of the HMR. The commenter claimed that an
exception from the performance packaging requirements is provided for
certain resin solutions under the UN Recommendations and the IMDG Code.
The commenter stated that U.S. companies need the exception for Resin
solutions to compete in the international marketplace. RSPA agrees with
the commenter's suggestion and is adding in the Sec. 172.101 Table for
the entry ``Resin solution'', in Column 8A, ``Sec. 173.173''. RSPA also
is amending the section heading and the introductory text of paragraph
(b) of Sec. 173.173 to include resins.
In the notice, RSPA proposed to add several generic proper shipping
names including the words, ``organic'', ``inorganic'', ``acid'', or
``base''. In addition, RSPA proposed new identification numbers for
generic shipping descriptions for liquefied gases. RSPA received
several comments on these proposals. Many of the commenters were
opposed to these new terms claiming that the information would not
provide any additional information to emergency responders and would be
very costly to implement. If adopted, commenters requested that RSPA
provide guidance on the definition of these terms. One commenter
suggested that ASTM Test Methods D-664 and D-2896 should be used to
determine if a material is an acid or a base. Comments were received
that supported the use of these terms, and RSPA received numerous
comments supporting international harmonization of transportation
regulations.
RSPA understands the concerns expressed by those commenters that
terms such as ``inorganic'' and ``organic'' provide little useful
information to emergency responders. However, RSPA believes that more
harm and confusion would be caused by adopting different shipping names
for domestic and international transportation for these numerous
generic shipping descriptions than would be caused if these shipping
names were adopted. Therefore, RSPA is adopting, as proposed, and
without domestic exceptions, the generic shipping descriptions bearing
the words ``inorganic'', ``organic'', ``acid'', and/or ``base'' and the
new identification number for liquefied gases. In addition, the
extended transition period being provided in this final rule will give
industry adequate time to revise their shipping papers and package
markings. The following provides some general guidance on the
definition of these terms.
For acids and bases, RSPA believes that the ASTM methods referenced
by commenters would be an acceptable method for determining if a
material is an acid or base. However, RSPA is not requiring persons to
use those methods. For an aqueous solution, the use of pH and litmus
paper is an acceptable method for determining if a material is an acid
or base. For a non-aqueous solution, shippers must use their knowledge
of the constituents of the material and make a determination as to
whether a material is an acid or base. For a material that is neither
an acid nor a base, the correct shipping name will be ``Corrosive
liquid, n.o.s.''. The definition of an ``organic'' is a compound with
carbon atoms bonded to other carbon, nitrogen or hydrogen atoms (e.g.,
amines, acid chlorides, acetic acids, phenols). An ``inorganic'' is any
pure element or any compound that does not have carbon atoms bonded to
other carbon, nitrogen or hydrogen atoms (e.g., sodium hydroxide,
sulfuric acid). Shippers must make a determination, based on the
constituents of their material, if their material is inorganic or
organic.
In the NPRM, RSPA proposed to add three new proper shipping names
to the HMT for samples of non-pressurized gases in Divisions 2.1 and
2.3. In response to the NPRM, one commenter urged RSPA to remove the
proposed entries for gas samples in the HMT. The commenter claimed that
non-pressurized flammable gases are not subject to the HMR and that
including gas samples under the HMR would increase shipping costs and
delay shipments. The commenter also recommended that RSPA adopt
criteria in Sec. 173.115 to limit the definition of Division 2.1 to
gases which exert a pressure of 280 kPa (41 psia) or greater at 20
deg.C (68 deg.F). Alternatively, the commenter recommended that RSPA
add a packaging exception for gas samples in quantities less than two
liters in each receptacle and remove proposed Special Provision 35 and
the non-bulk packaging references to Secs. 173.302 and 173.304 for the
gas sample entries in the HMT.
RSPA disagrees with the commenter's recommendation to remove the
entries for gas samples because these materials are currently regulated
under the HMR. The commenter's understanding of Division 2.1 criteria
is incorrect. Non-pressurized gas samples are presently subject to the
HMR if they meet the hazard class criteria in Sec. 173.115. Division
2.1 or 2.3 materials are not limited to gases which exert a pressure of
at least 280 kPa (41 psi) at 20 deg.C (68 deg.F). RSPA simply is
providing more descriptive proper shipping names for non-pressurized
gas samples. Therefore, RSPA is adopting the gas sample entries as
proposed. In addition, RSPA is retaining the non-bulk packaging
references in the Table for persons who want to ship larger quantities
of gas samples. However, RSPA agrees with the commenter concerning the
need to address gas samples in the exceptions and is removing proposed
Special Provision 35 and revising the provisions in Sec. 173.306 to
specifically address gas samples.
One commenter submitted data indicating that ``Diphenylmethane-
4,4'diisocyanate'' does not meet Division 6.1, Packing Group III
criteria under the HMR. Another commenter verified that ``2-Bromo-2-
nitropropane-1,3-diol'' does not meet the criteria for Division 6.1
under the HMR. The commenter requested that RSPA add an ``I'' in the
first column of the Sec. 172.101 Table for the entry ``2-Bromo-2-
nitropropane-1,3-diol'' to distinguish it from a domestically regulated
hazardous material. RSPA agrees that these materials are not hazardous
materials in domestic transportation. However, to facilitate
international transportation, RSPA is retaining the entries for
Diphenylmethane-4,4'diisocyanate and 2-Bromo-2-nitropropane-1,3-diol
and adding an ``I'' in the first column to indicate that these
materials are regulated in international transportation.
One commenter requested that RSPA remove the poison inhalation
hazard (PIH) designation for ``Allyl isothiocyanate, stabilized''
because the material does not meet the PIH criteria in Sec. 173.133.
Based on supporting data submitted by the commenter, RSPA agrees with
the assessment and is removing the PIH designation for Allyl
isothiocyanate, stabilized, in the HMT.
RSPA received one comment regarding the hazard zone designation for
``Allyl chloroformate.'' The commenter provided information which
indicates that the hazard zone for allyl chloroformate should be Zone B
and not Zone A. RSPA agrees that the hazard zone designation for allyl
chloroformate should be ``Zone B'' and is amending the hazard zone
designation for this material rather than issuing an approval under
Sec. 172.101(l)(2). In addition, data provided by a commenter indicates
that the hazard zone for trichloroacetyl chloride is Zone B, not Zone
A, as previously indicated on the HMT. Therefore, RSPA is modifying
this shipping description to indicate that trichloroacetyl chloride is
a Hazard Zone B PIH material.
One commenter objected to RSPA's proposal to add a proper shipping
name for ``Pentachlorophenols'' classed as Division 6.1, Packing Group
II when an existing entry ``Chlorophenols, solid'' carries a Division
6.1, Packing Group III classification. The commenter contended that the
``Keep Away From Food'' label adequately conveys the nature of hazard
posed by these materials. RSPA added ``Pentachlorophenols'' in the HMT
and designated it as Division 6.1, PG II based on the UN
Recommendations. However, according to Sec. 172.101(c)(12), if it has
been determined that a material meets the definition of a hazard class,
packing group, or hazard zone other than the class, packing group, or
hazard zone shown in association with the proper shipping name, another
shipping description shall be selected that appropriately describes the
material. Therefore, RSPA is adding the entry for Pentachlorophenols as
proposed.
RSPA received several comments requesting that Maneb and Maneb
preparations that do not meet the definition of any hazard class, be
excepted from the HMR when transported by motor vehicle, rail car, or
aircraft. Commenters noted that Special Provision 140 of the UN
Recommendations allows the competent authority to deregulate Maneb. In
addition, the commenters noted that exemption DOT E-11037 allows this
material to be shipped unregulated. RSPA concurs and has added Special
Provision 53 to Maneb (UN2968) which states that Maneb not meeting the
definition of Division 4.3 or any other hazard class is not subject to
the HMR when transported by aircraft, motor vehicle, or rail car.
RSPA received a comment requesting that it add the shipping
description ``Dangerous goods in apparatus/ machinery'' to the HMT. The
commenter stated that this shipping name, which is listed in the ICAO
Technical Instructions but not the UN Recommendations, is very sensible
and will be beneficial to both shippers and carriers alike. RSPA agrees
that this name would be beneficial to the industry but believes that
the packaging provision, for both air and ground transport, should be
subject to appropriate public notice and comment. Therefore, RSPA is
not adopting, in this rule, this commenter's suggestion to add the
shipping name ``Dangerous goods in apparatus/machinery'' to the HMT.
However, shipments described and prepared in accordance with the ICAO
Technical Instructions and Sec. 171.11 may be transported domestically
by aircraft and by motor vehicle either before or after being
transported by aircraft.
One commenter suggested that RSPA incorporate an IM tank
authorization into the HMR for 2-Ethyhexyl-
chloroformate equivalent to the tank authorization under the IMDG Code
and under an approval (SA-9407006) issued by OHMS. RSPA is adding
Special Provision T12 in Column 7 of the HMT for 2-
Ethyhexylchloroformate which eliminates the need for an approval.
In the NPRM, RSPA proposed to add subsidiary labeling requirements
for Class 2 materials. As a result, subsidiary labels were added in
Column 6 of the HMT for Class 2 materials, including Chlorine, meeting
more than one hazard class. RSPA proposed to add Corrosive and Oxidizer
subsidiary labels for Chlorine. One commenter contended that the yellow
Oxidizer label is more visible than the black and white Poison gas
label and may cause confusion in determining the primary hazard. RSPA
has determined that the Corrosive subsidiary label is necessary because
of the material's effects on skin tissue; however, RSPA is removing the
Oxidizer subsidiary label for Chlorine because it is unnecessary.
One commenter objected to the proposal to change the order of the
descriptive words in the basic shipping description to coincide with
the precedence of hazards. The commenter cited limited safety benefit
and high costs as reasons not to adopt the proposed changes. Though
RSPA agrees that these changes have limited safety benefit, RSPA
believes that adoption of a domestic-only name for these descriptions
is not justified. In addition, most of the costs the commenter cited
should be ameliorated by the lengthy transition period being provided.
RSPA proposed to add new entries for solid materials containing
flammable, corrosive, or toxic liquids in the NPRM. One commenter
requested clarification on whether these new entries included solid
materials that were previously not regulated. The commenter stated that
RSPA's intent was not adequately clarified in the special provisions
designated for the materials. Another commenter requested clarification
of the phrase ``packaging must correspond to a design type that has
passed a leakproof test at the Packing Group II level'' in Special
Provisions 47, 48, and 49.
RSPA is adding the entries for solid materials containing
flammable, corrosive, or toxic liquids in this rule to provide shippers
with additional generic entries to describe solids that contain liquids
that are either flammable, corrosive, or toxic (e.g., soil contaminated
with toxic material from an underground storage tank) and have not been
tested to verify the hazard class. However, if free liquid is present
at the time the material is loaded, these shipping descriptions may not
be used. The new entries are not intended to regulate non-hazardous
materials (i.e., those materials that do not meet any hazard class
definition). The phrase regarding the leakproof test is intended to
have these materials transported in a packaging whose ``design type''
has been leakproof tested. Therefore, only the design, not every
packaging, need be subjected to the leakproof test.
One commenter objected to RSPA's proposed amendment to require a
CORROSIVE subsidiary label in addition to a POISON GAS primary label on
packages containing dry sulfur dioxide. The commenter stated that the
material is not corrosive to carbon or stainless steel, and the
commenter expressed concern that addition of a CORROSIVE label will
require more frequent cargo tank inspections under Sec. 180.407.
In the context of Sec. 180.407, corrosive lading means that a
material has a corrosive effect on a cargo tank. It is the shipper's
responsibility to determine whether a material is corrosive to the
material of construction of a cargo tank. Because of the corrosive
effects dry sulfur dioxide has on skin tissue, RSPA is adopting the
Class 8 subsidiary label as proposed.
RSPA received several comments requesting new bulk packagings for
chlorosulfonic acid, dimethyl sulfate, and titanium tetrachloride. RSPA
is not accepting these comments because they are beyond the scope of
this rulemaking.
RSPA is making several changes to the IBC authorizations in the HMT
based on petitions for reconsideration received to Docket HM-181E. RSPA
will handle all other petitions received to Docket HM-181E in a future
Federal Register publication. The following materials will be allowed,
through a revised Special Provision B110, to be transported in IBCs
authorized in Sec. 173.242(d): UN2030, UN2014, U3149, UN2078, UN1790,
UN2076, UN2022. In addition, Special Provision B100, which does not
allow the use of IBCs, is removed from ``Chloropicrin mixtures, n.o.s,
6.1, UN1583, Packing Group III''. Special Provision B53 also is revised
to indicate that it does not apply to IBCs.
The following tables identify those entries that are: (1) Deleted;
(2) significantly changed; or (3) added. An entry is considered
significantly changed if there is a change in (1) the shipping name,
(2) IM tank authorization, (3) subsidiary labeling, (4) classification,
or (5) packaging. Each entry is identified by its identification number
which, along with the cross-reference table appearing in the HMR prior
to the HMT, can be used to identify the affected entries. Unless
otherwise indicated, the identification numbers are ``UN'' numbers:
List of Entries Deleted From the Sec. 172.101 Table
----------------------------------------------------------------------------------------------------------------
NA1086................. 0416 **1270 1705 2497 3030-3043
NA2255*................ .............. .............. .............. .............. .......................
NA2810*................ 1118 1271 1864 2553 NA9259*
NA2811*................ 1255 1584 2207 2860 NA9276*
0273................... 1256 1592 2229 2951-2955 .......................
0274................... 1257 1703 2449 2970-2973 .......................
----------------------------------------------------------------------------------------------------------------
*See new entry added by the UN recommendations.
**See new NA number (NA1270).
List of Entries Significantly Changed
--------------------------------------------------------------------------------------------------------------------------------------------------------
NA1760.................................. 1322 1474 1731 2006 2379 2534 2818
NA1986.................................. 1325 1475 1740 2022 2382 2557 2821
NA2922.................................. 1328 1477 1747 2029-2030 2383 2564 2823
1030.................................... .............. .............. .............. .............. .............. .............. ..............
1106.................................... 1334 1481 1750 2047 2386 2571 2826
1125.................................... 1336 1482 1751 2051 2389 2583 2834
1135.................................... 1337 1483 1752 2076 2399 2584 2837
1143.................................... 1344 1489 1755 2189 2401 2585 2841
1154.................................... 1348 1502 1757 2194 2407 2586 2845
1158.................................... 1349 1506 1761 2195 2417 2604 2846
1160.................................... 1350 1508 1773 2196 2418 2606 2857
1162.................................... 1353 1511 1783 2198 2420 2610 2869
1167.................................... 1354 1517 1787 2206 2421 2616 2874
1198.................................... 1355 1549 1788 2209 2427 2619 2881
1202.................................... 1356 1564 1789 2211 2428 2626 2904-2905
1210.................................... 1357 1566 1809 2218 2429 2670 2921-2930
1214.................................... 1361 1570 1811 2219 2430 2677 2938
1221.................................... 1364 1588 1814 2232 2438 2679 2945-2946
1228.................................... 1373 1589 1816 2242 2445 2681 2965
1235.................................... 1378 1590 1819 2251 2461 2684 2985-2988
1265.................................... 1395 1599 1824 2257 2478 2693 2991-3021
1268.................................... 1402 1601 1888 2258 2482 2733 3024-3027
1274.................................... 1408 1602 1908 2260 2484 2734 3049-3050
1277.................................... 1409 1605 1922 2264 2485 2735 3065-3066
1282.................................... 1415 1613 1952 2267 2495 2741 3071
1289.................................... 1418 1614 1953 2270 2501 2742 3079
1296.................................... 1420 1648 1954 2276 2502 2757-2787 3084
1297.................................... 1428 1660 1955 2332 2517 2789 3086-3088
1298.................................... 1454 1708 1956 2337 2521 2796 3094
1308.................................... 1455 1715 1975 2343 2526 2801 3096
1310.................................... 1458 1719 1986 2351 2529 2810 3098-3100
1320.................................... 1459 1722 1988 2359 2530 2813 3119-3150
1321.................................... 1462 1724 1992 2361 2533 2817 1717
--------------------------------------------------------------------------------------------------------------------------------------------------------
List of Additions to the Sec. 172.101 Table
------------------------------------------------------------------------
UN # Shipping name
------------------------------------------------------------------------
0491. CHARGES, PROPELLING.
0492. SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0493. SIGNALS, RAILWAY TRACK, EXPLOSIVE.
0494. JET PERFORATING GUNS, CHARGED, oil well, without detonator.
0495. PROPELLANT, LIQUID.
0496. OCTONAL.
0497. PROPELLANT, LIQUID.
0498. PROPELLANT, SOLID.
0499. PROPELLANT, SOLID.
1851. MEDICINE, LIQUID, TOXIC, N.O.S.
1990. BENZALDEHYDE.
3155. PENTACHLOROPHENOL.
3156. COMPRESSED GAS, OXIDIZING, N.O.S.
3157. LIQUEFIED GAS, OXIDIZING, N.O.S.
3158. GAS, REFRIGERATED LIQUID, N.O.S.
3159. 1,1,1,2-TETRAFLUOROETHANE.
3160. LIQUEFIED GAS, TOXIC, FLAMMABLE, N.O.S.
3161. LIQUEFIED GAS, FLAMMABLE, N.O.S.
3162. LIQUEFIED GAS, TOXIC, N.O.S.
3163. LIQUEFIED GAS, N.O.S.
3164. ARTICLES, PRESSURIZED PNEUMATIC or HYDRAULIC (containing non-
flammable gas).
3166. ENGINES, INTERNAL COMBUSTION, including when fitted in machinery
or vehicles.
3167. GAS SAMPLE, NON-PRESSURIZED, FLAMMABLE, N.O.S., not refrigerated
liquid.
3168. GAS SAMPLE, NON-PRESSURIZED, TOXIC, FLAMMABLE, N.O.S., not
refrigerated liquid.
3169. GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S., not refrigerated
liquid.
3170. ALUMINIUM PROCESSING BY-PRODUCTS.
3171. BATTERY-POWERED VEHICLE or BATTERY-POWERED EQUIPMENT (wet
battery).
3174. TITANIUM DISULPHIDE.
3175. SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S.
3176. FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S.
3178. FLAMMABLE SOLID, INORGANIC, N.O.S.
3179. FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S.
3180. FLAMMABLE SOLID, CORROSIVE, INORGANIC, N.O.S.
3181. METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.
3182. METAL HYDRIDES, FLAMMABLE, N.O.S.
3183. SELF-HEATING LIQUID, ORGANIC, N.O.S.
3184. SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S.
3185. SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S.
3186. SELF-HEATING LIQUID, INORGANIC, N.O.S.
3187. SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S.
3188. SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.
3189. METAL POWDER, SELF-HEATING, N.O.S.
3190. SELF-HEATING SOLID, INORGANIC, N.O.S.
3191. SELF-HEATING SOLID, TOXIC, INORGANIC, N.O.S.
3192. SELF-HEATING SOLID, CORROSIVE, INORGANIC, N.O.S.
3194. PYROPHORIC LIQUID, INORGANIC, N.O.S.
3200. PYROPHORIC SOLID, INORGANIC, N.O.S.
3203. PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.
3205. ALKALINE EARTH METAL ALCOHOLATES, N.O.S.
3206. ALKALI METAL ALCOHOLATES, SELF-HEATING, CORROSIVE, N.O.S.
3207. ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND
DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S.
3208. METALLIC SUBSTANCE, WATER-REACTIVE, N.O.S.
3209. METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S.
3210. CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3211. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3212. HYPOCHLORITES, INORGANIC, N.O.S.
3213. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3214. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3215. PERSULPHATES, INORGANIC, N.O.S.
3216. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3217. PERCARBONATES, INORGANIC, N.O.S.
3218. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3219. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S.
3220. PENTAFLUOROETHANE.
3221. SELF-REACTIVE LIQUID TYPE B.
3222. SELF-REACTIVE SOLID TYPE B.
3223. SELF-REACTIVE LIQUID TYPE C.
3224. SELF-REACTIVE SOLID TYPE C.
3225. SELF-REACTIVE LIQUID TYPE D.
3226. SELF-REACTIVE SOLID TYPE D.
3227. SELF-REACTIVE LIQUID TYPE E.
3228. SELF-REACTIVE SOLID TYPE E.
3229. SELF-REACTIVE LIQUID TYPE F.
3230. SELF-REACTIVE SOLID TYPE F.
3231. SELF-REACTIVE LIQUID TYPE B, TEMPERATURE CONTROLLED.
3232. SELF-REACTIVE SOLID TYPE B, TEMPERATURE CONTROLLED.
3233. SELF-REACTIVE LIQUID TYPE C, TEMPERATURE CONTROLLED.
3234. SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED.
3235. SELF-REACTIVE LIQUID TYPE D, TEMPERATURE CONTROLLED.
3236. SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED.
3237. SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED.
3238. SELF-REACTIVE SOLID TYPE E, TEMPERATURE CONTROLLED.
3239. SELF-REACTIVE LIQUID TYPE F, TEMPERATURE CONTROLLED.
3240. SELF-REACTIVE SOLID TYPE F, TEMPERATURE CONTROLLED.
3241. 2-BROMO-2-NITROPROPANE-1,3-DIOL.
3242. AZODICARBONAMIDE.
3243. SOLIDS CONTAINING TOXIC LIQUID, N.O.S.
3244. SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S.
3246. METHANESULPHONYL CHLORIDE.
3247. SODIUM PEROXOBORATE, ANHYDROUS.
3248. MEDICINE, LIQUID, FLAMMABLE, TOXIC, N.O.S.
3249. MEDICINE, SOLID, TOXIC, N.O.S.
3250. CHLOROACETIC ACID, MOLTEN.
3251. ISOSORBIDE-5-MONONITRATE.
3252. DIFLUOROMETHANE.
3253. DISODIUM TRIOXOSILICATE, PENTAHYDRATE.
3254. TRIBUTYLPHOSPHANE.
3255. tert-BUTYL HYPOCHLORITE.
3256. ELEVATED TEMPERATURE LIQUID, N.O.S. with flash point above 37.8
deg.C, at or above its flash point.
3257. ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 deg.C and
below its flash point.
3258. ELEVATED TEMPERATURE SOLID, N.O.S., at or above 240 deg.C.
3259. AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE,
N.O.S.
3260. CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
3261. CORROSIVE, SOLID, ACIDIC, ORGANIC, N.O.S.
3262. CORROSIVE, SOLID, BASIC, INORGANIC, N.O.S.
3263. CORROSIVE, SOLID, BASIC, ORGANIC, N.O.S.
3264. CORROSIVE, LIQUID, ACIDIC, INORGANIC, N.O.S.
3265. CORROSIVE, LIQUID, ACIDIC, ORGANIC, N.O.S.
3266. CORROSIVE, LIQUID, BASIC, INORGANIC, N.O.S.
3267. CORROSIVE, LIQUID, BASIC, ORGANIC, N.O.S.
3268. AIR BAG INFLATORS or AIR BAG MODULES or SEAT-BELT PRE-TENSIONERS
or SEAT-BELT MODULES.
3269. POLYESTER RESIN KIT.
3270. NITROCELLULOSE MEBRANE FILTERS.
3271. ETHERS, N.O.S.
3272. ESTERS, N.O.S.
3273. NITRILES, FLAMMABLE, TOXIC, N.O.S.
3274. ALCOHOLATES SOLUTION, N.O.S., in alcohol.
3275. NITRILES, TOXIC, FLAMMABLE, N.O.S.
3276. NITRILES, TOXIC, N.O.S.
3277. CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S.
3278. ORGANOPHOSPHORUS COMPOUND, TOXIC N.O.S.
3279. ORGANOPHOSPHORUS COMPOUND, TOXIC, FLAMMABLE, N.O.S.
3280. ORGANOARSENIC COMPOUND, N.O.S.
3281. METAL CARBONYLS, N.O.S.
3282. ORGANOMETALLIC COMPOUND, TOXIC N.O.S.
3283. SELENIUM COMPOUND, N.O.S.
3284. TELLURIUM COMPOUND, N.O.S.
3285. VANADIUM COMPOUND, N.O.S.
3286. FLAMMABLE LIQUID, TOXIC, CORROSIVE, N.O.S.
3287. TOXIC LIQUID, INORGANIC, N.O.S.
3288. TOXIC SOLID, INORGANIC, N.O.S.
3289. TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S.
3290. TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S.
3292. BATTERIES, CONTAINING SODIUM, or CELLS, CONTAINING SODIUM.
3293. HYDRAZINE,AQUEOUS SOLUTION with not more than 37% hydrazine, by
mass.
3294. HYDROGEN CYANIDE, SOLUTION IN ALCOHOL with not more than 45%
hydrogen cyanide.
3295. HYDROCARBONS, LIQUID, N.O.S.
3296. HEPTAFLUOROPROPANE.
3297. ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE with not more
than 8.8% ethylene oxide.
3298. ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE with not more than
7.9% ethylene oxide.
3299. ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE with not more than
5.6% ethylene oxide.
3300. ETHYLENE OXIDE AND CARBON DIOXIDE MIXTURE with more than 87%
ethylene oxide.
3301. CORROSIVE LIQUID, SELF-HEATING, N.O.S.
------------------------------------------------------------------------
Appendix B to Sec. 172.101. In the NPRM, RSPA proposed the addition
of two notes which are consistent with recent IMO decisions. The first,
Note 4, allows a material meeting criteria for a marine pollutant in
the IMDG Code but not listed in Appendix B of Sec. 172.101, to be
transported as a marine pollutant. Note 5 allows the Associate
Administrator for Hazardous Materials Safety to except from HMR
requirements a material listed in Appendix B of the HMR that does not
meet the IMDG Code criteria for a marine pollutant. In addition, RSPA
proposed to amend the HMR's List of Marine Pollutants by adding or
removing a number of materials. Commenters to these proposals generally
supported the proposed changes. One commenter questioned the addition
of Notes 4 and 5. However, the majority of commenters addressing these
proposed changes supported the addition of these notes. RSPA is
adopting these notes for consistency with IMDG Code provisions. Note 4
is consistent with the 27th Amendment to the IMDG Code, which allows
the use of criteria for designating marine pollutants. Note 5 provides
flexibility so that if a substance does not meet the IMDG Code criteria
for a marine pollutant the Associate Administrator may except it from
the HMR marine pollutant requirements.
Other commenters thought it more appropriate to address these
proposals under Docket HM-211; Marine Pollutants. RSPA disagrees;
handling marine pollutant issues in Docket HM-215A will facilitate the
harmonization of the HMR with the IMDG Code in conjunction with the
January 1, 1995 implementation date for the 27th Amendment to that
Code.
Section 172.102. Special Provisions 24, 26, 32, 34-37, 39, 40, 43-
52 and 54 are added to Sec. 172.102, Special Provisions 16, 23, B53,
and B110 are revised, and Special Provisions 25, 41, and A33 are
removed. These special provisions relate to certain materials'
classifications and any special packaging requirements that are
necessary to safely transport these materials.
Section 172.203. One commenter addressing proposed changes to the
marine pollutant provisions requested relief from certain shipping
paper requirements for specific hydrocarbon compounds which fall under
the requirements of 49 CFR Part 130, which prescribes prevention and
response requirements for the transportation of oil. This commenter
believed that petroleum products subject to Part 130 should be exempt
from the requirement in Sec. 172.203(l) to indicate on a shipping paper
that the material is also a marine pollutant. RSPA partially agrees
with the commenter that hazardous materials that are subject to 49 CFR
Part 130 should not be subject to the marine pollutant shipping paper
requirements of Sec. 172.203(l)(2). Therefore, RSPA is revising
Sec. 172.203(l)(2) to except petroleum products that are subject to the
provisions of 49 CFR Part 130 when transported in bulk by road or rail.
A new paragraph (o) is added to require additional information to
be included in the shipping paper description for organic peroxides and
self-reactive materials. In addition, paragraphs (k) and (m) are
revised based on changes to the HMT. In paragraph (k), the list of
shipping names requiring technical names is revised based on changes to
the HMT. In paragraph (m), the reference to ``Poison'' is modified to
include an alternative reference to ``Toxic.''
Section 172.204. RSPA proposed to amend the certification statement
in paragraph (a)(2) by adding ``placarded'' as a condition for
declaring a shipment to be properly prepared for transportation. The
intent of this proposed change is to provide consistency with
international declarations and enable one shipper certification
statement to be used for both domestic and export shipments so that
different preprinted forms are not needed. Commenters supported this
proposed change for certifying an international shipment, but were
divided as to whether it is appropriate for domestic transportation.
Several commenters suggested that paragraph (a)(1) be deleted because
it is no longer required. Other commenters believed that paragraph
(a)(1) should be retained for domestic purposes without the addition of
``placarded'' to the certification. According to these commenters,
certifying that a shipment has been properly placarded is inconsistent
with the provisions in Sec. 172.506 that a shipper must offer and a
carrier must affix the required placards for transportation by highway.
RSPA believes that the addition of ``placarded'' in the certification
would not apply to shipments for which the offeror has no control over
affixing placards. However, in this rule, RSPA is retaining paragraph
(a)(1) for domestic purposes and is adopting paragraph (a)(2) as
proposed for use in either domestic or international transportation. In
addition, paragraph (a)(2) is amended by removing the provision to
indicate the mode of transportation in the shipper's certification.
This revision is consistent with the multimodal approach adopted in the
UN Recommendations, ICAO and IMDG Code.
Section 172.320. Section 172.320 is adopted as proposed to
authorize all product codes that are traceable to an ``EX-number'' to
be marked on boxes of explosives in lieu of the EX number.
Section 172.325. The identification number ``9259'' shown in the
HOT marking illustration in paragraph (c) is revised to read ``3257''
to reflect the new UN number assigned to ``Elevated temperature
material, liquid, n.o.s.''
Section 172.400a. A new paragraph (c) is adopted as proposed to
state that a subsidiary POISON label is not required on a package
bearing a primary CORROSIVE label if the poison hazard of the material
inside is based solely on corrosive destruction of tissue and is not
due to systemic poisoning. In addition, based on the merit of comments,
RSPA is adding a new paragraph (d) to allow the use of a POISON label
in place of a KEEP AWAY FROM FOOD label for domestic transportation of
Division 6.1 PG III materials.
Section 172.402. Paragraph (a)(2) is adopted as proposed to
incorporate certain subsidiary labeling provisions in the subsidiary
labeling table in paragraph (a)(2). These provisions require subsidiary
hazard labeling for Class 8 Packing Group III materials and Class 3
Packing Group III materials except for Class 3 Packing Group III
materials having a flash point at or above 38 deg.C (100 deg.F) when
transported by highway or rail. In addition, paragraph (a)(1) is
revised to clarify that if Column 6 of the Sec. 172.101 Table indicates
a subsidiary label for which there is an exception in paragraph (a)(2)
of Sec. 172.402, the exception applies. This revision is based on the
merit of comments urging consistency in subsidiary labeling provisions.
In the NPRM, RSPA discussed a change adopted in the eighth revised
edition of the UN Recommendations which removed the STOW AWAY FROM
FOODSTUFFS label and placard and replaced them with the POISON label
and placard for materials having either a primary or secondary hazard
in Division 6.1 Packing Group III. As noted previously, RSPA is
addressing this issue in a rulemaking action under Docket HM-217;
however, RSPA believes that a package containing a material meeting
Division 6.1 Packing Group III criteria as either a primary or
subsidiary hazard should bear a label which communicates a warning that
the material must be kept separate from foodstuffs when transported
domestically by any mode. This was discussed in the preamble of the
notice, and the proposed changes to the Sec. 172.101 Table included the
addition of a KEEP AWAY FROM FOOD label in Column 6 for each affected
entry. However, RSPA inadvertently neglected, in the Sec. 172.402(a)(2)
proposed regulatory text changes, to remove the ``N'' at the
intersection of row ``III'' and column ``6.1'' and replace it with an
``X''. Commenters on this issue opposed any required domestic labeling
of materials having a subsidiary hazard of Division 6.1 Packing Group
III. Both HMAC and the Conference on Safe Transportation of Hazardous
Articles (COSTHA) stated that any proposed changes should be deferred
for consideration under Docket HM-217. In addition, COSTHA noted
potential changes to UN toxicity classification criteria and claimed
that adopting harmonized toxicity criteria will decrease the number of
liquids in Division 6.1 Packing Group III. COSTHA encouraged RSPA not
to revise provisions for the labeling and placarding of Division 6.1
Packing Group III materials until the UN and DOT have completed
harmonization efforts.
The preamble section review in the NPRM clearly expressed RSPA's
intent to revise Sec. 172.402(a)(2) to replace the ``N'' with an ``X''
(which would have the effect of requiring subsidiary labeling for
materials having a Division 6.1 Packing Group III subsidiary hazard).
RSPA believes that materials having a primary or secondary hazard of
Division 6.1 PG III pose a risk not only of food contamination, but
also dermal and inhalation hazards sufficient to warrant hazard
communication. Therefore, RSPA is adopting the requirement for
subsidiary hazard labeling for Division 6.1 Packing Group III materials
when transported in any mode.
Also, new subsidiary labeling requirements for Class 2 materials
are added as paragraphs (f) and (g). Several commenters requested
clarification of proposed paragraph (f) regarding a Division 2.2
material that meets the definition of an oxidizer. RSPA is clarifying
in this final rule that a Division 2.2 material may meet the definition
of an oxidizing gas, as defined in Sec. 171.8.
Section 172.411. A requirement specifying a minimum height for the
compatibility group letter on certain EXPLOSIVE labels is removed.
Section 172.416. Section 172.416 is revised to allow the use of the
words ``TOXIC GAS'' on the POISON GAS label.
Section 172.430. Section 172.430 is revised to allow the use of the
word ``TOXIC'' on the POISON label.
Section 172.540. Section 172.540 is revised to allow the use of the
words ``TOXIC GAS'' on the POISON GAS placard.
Section 172.547. Section 172.547 is revised to reduce the size
requirement for the word ``spontaneously'' in the ``SPONTANEOUSLY
COMBUSTIBLE'' placard from 25 mm to 12 mm.
Section 172.554. Section 172.554 is revised to allow the use of the
word ``TOXIC'' on the POISON placard.
Part 173
Section 173.2a. Consistent with the UN Recommendations, the
Precedence of Hazards Table is adopted as proposed to account for
combinations of Division 4.2 and Class 8 materials which currently are
denoted as impossible combinations. In addition, two new notes are
added at the end of the paragraph (b) table. Note 1 specifies that, for
materials having multiple risks which are not listed by technical name
in the Sec. 172.101 Table, the most stringent packaging group must be
used. Note 2 is added to specify the class assignment for a material
which meets the definition of Class 8 and has an inhalation toxicity by
dusts and mists at the Packing Group I level.
Section 173.21. A revised reference to the Sec. 173.224 self-
reactive materials table is adopted as proposed to reflect changes to
the table.
Section 173.22. Revised paragraph (a)(3)(i) is adopted as proposed
to indicate that the marking appearing on the bottom of a metal or
plastic drum in accordance with Sec. 178.503 is not an acceptable means
of determining if the drum is an authorized packaging. Paragraph (a)(2)
is revised to recognize packagings manufactured outside the U.S. as
provided in Sec. 173.24(d)(2), and paragraph (a)(4) is revised to limit
notification provisions to packagings manufactured in the U.S.
Section 173.24. Paragraph (d) is adopted as proposed to specify the
conditions under which foreign-manufactured packagings may be used. The
revision stipulates the conditions under which foreign-manufactured UN
packagings may be filled and used in the U.S. Only packagings from
countries affording the same degree of acceptance to U.S.-manufactured
packagings may be used. Several commenters did not realize that this
proposed revision applies to empty packagings being imported into the
U.S. for filling. They thought that the proposal applied to packagings
already filled with a hazardous material before being imported into the
U.S. Provisions concerning the import of filled packagings are
contained in Secs. 171.11, 171.12, and 171.12a and are not amended in
this final rule. Other commenters expressed concern as to the ability
of U.S. shippers to determine which countries recognize U.S.
packagings. Two commenters suggested that RSPA periodically publish a
notice in the Federal Register, listing those countries that do not
recognize U.S. manufactured UN standard packagings. Several commenters
objected to the issue of reciprocity being addressed in a rulemaking
action, claiming this is a political issue. One alternative suggested
by commenters is to consider and resolve such issues at the UN or by
the competent authorities of the countries involved. RSPA agrees that
every effort should be made by the competent authority of each country
involved to resolve reciprocity issues. RSPA would only resort to
declaring a country as not providing reciprocal treatment for UN
standard packaging manufactured in the U.S. in a Federal Register
notice after exhausting attempts to resolve differences through
negotiation.
In addition, revised paragraph (e)(4)(ii) is adopted as proposed to
prohibit hazardous materials from being packed or mixed with other
hazardous or nonhazardous materials in the same outer packaging if such
materials are capable of reacting with each other and causing the
evolution of ``asphyxiant gases.''
Section 173.25. Paragraph (a) is adopted as proposed to refer to
the definition of ``Overpack'' in Sec. 171.8, which also is amended to
provide examples of suitable overpacks. Commenters generally supported
the proposed revision; however, based on several comments, there
appears to be confusion regarding the current provisions for overpacks,
specifically concerning the marking, labeling and use of shrink- or
stretch-wrapped pallets. Currently, shrinkwrap is considered an
overpack when consolidating packages on a pallet. The overpack must be
marked and labeled for each hazardous material contained therein unless
markings and labels representative of each hazardous material are
visible. If packages are stacked and banded on a pallet, the packages
should be positioned, when possible, so that the markings and labels
are visible on the outside of the stack.
Paragraph (b) is added as proposed to authorize shrink-wrapped or
stretch-wrapped trays as outer packagings for inner packagings prepared
under limited quantity or consumer commodity provisions if the
completed package is capable of meeting the Packing Group III
performance level and the gross weight of the package does not exceed
20 kg. This proposal generated opposition from carriers, who claimed
that shrink wrap as an outer packaging does not provide adequate
protection from the rigors of transportation and should not be
authorized. However, at least one of these commenters was referring to
a shrink-wrapped pallet rather than a package limited to 20 kg (44
pounds) gross weight. On the other hand, commenters such as COSTHA
strongly supported this proposal, but requested that RSPA maintain
consistency with the UN Recommendations by authorizing the use of
shrink-wrapped or stretch-wrapped trays as outer packagings without
imposing a requirement that these completed packagings be capable of
passing Packing Group III performance tests.
Section 173.28. RSPA is not adopting a proposed revision to
paragraph (b)(1), based on the merit of a comment suggesting the
sentence duplicates the provisions of Sec. 173.24(d) and should only
apply to the reuse of packagings required to meet performance
standards, not to the reuse of all packagings. The Association of
Container Reconditioners (ACR) urged RSPA to revise the footnote to the
table in paragraph (b)(4), to restore the minimum thicknesses to what
was required when the final rule was published on December 21, 1990.
ACR pointed out that in corrections and amendments made in 1991, the
footnote to the table in paragraph (b)(4) had been revised to allow
reuse of metal drums with a minimum wall thickness of 0.8 mm and
minimum head thickness of 1.1 mm. ACR asked that the note be revised to
reference minimum thicknesses of 0.82 mm and 1.09 mm. Since these
changes were not proposed in the NPRM, RSPA is not revising the minimum
thicknesses at this time; however, the number ``0'' has been added
after the last digit in each instance for clarity.
A commenter expressed confusion over the requirement for the
nominal or minimum thickness to be permanently marked on a packaging
that is to be reused. The commenter stated that it appeared that the
marking could be either the nominal or minimum thickness. Paragraph
(b)(4) has been revised to clarify that the nominal thickness is marked
on metal packagings, and the minimum thickness must be marked on
plastic packagings which are to be reused.
New paragraph (b)(7) is added to waive requirements for leaktesting
prior to each reuse to certain packagings used in limited operations.
The NPRM proposed to waive retesting requirements for stainless steel,
monel, or nickel drums, which are constructed with a thickness at least
one and one half times the minimum required by Sec. 173.28(b)(4), and
which are refilled with the same or similar compatible contents and
transported by a private carrier, contract carrier, or common carrier
in a transport vehicle or freight container used exclusively for such
service, within a distribution chain controlled by the offeror.
Commenters overwhelmingly supported RSPA's proposed paragraph
(b)(7). Numerous commenters suggested that RSPA extended the provisions
of paragraph (b)(7) to plastic drums in addition to stainless steel,
monel, and nickel drums. The commenters cited the high costs that would
be incurred by plastic drum users if leak testing were required prior
to each use. Many commenters stated that the leak test itself could
cause damage to plastic drums over time, due to the bulging of the
packaging caused by internal pressure. Commenters asked that RSPA
revise paragraph (b)(7) to be more consistent with the UN
Recommendations, which require leak testing for plastic drums only
after reconditioning.
RSPA recognizes that the UN Recommendations do not require a
packaging to be leakproofness tested before it is reused for transport,
but only after it is reconditioned. However, RSPA notes that the UN
Recommendations, at section 9.6.7.2., limit the period of use for
plastic drums and jerricans to five years from the date of manufacture.
The HMR do not currently place a limit on the period of use for plastic
drums. RSPA believes that under certain controlled conditions, plastic
drums can be used safely without leak testing prior to each reuse.
Upon further consideration of the leakproofness testing
requirements for plastic drums, RSPA has determined that the types of
damage to plastic drums caused by normal transportation stresses
include puncture, abrasion of plastic material, and loose or damaged
closures. RSPA believes that these types of damage can be detected by a
thorough visual examination by a person who is qualified to identify
such damage. RSPA also believes that damage to plastic drums from
abrasion, puncture, and damaged fittings can be minimized with careful
handling. For that reason, RSPA believes that plastic drums used in
distribution chains controlled by the offeror can be used safely
without leak testing prior to each reuse. However, damage caused by
incompatibility of the product being shipped with the plastic of the
drum would not be detected through an external visual examination.
Because such damage can happen and worsen over time, RSPA believes that
after five years of use, a plastic drum should be subjected to a leak
test prior to each reuse for the shipment of liquid hazardous
materials.
New paragraph Sec. 173.28(b)(7) authorizes the reuse, without leak
testing, of certain drums including those constructed of stainless
steel, monel, nickel, and plastic. In order to ensure an appropriate
level of safety, when stainless steel, monel, or nickel drums are
reused without undergoing leakproofness testing, they are required to
meet more stringent thickness standards than prescribed in paragraph
(b)(4). Plastic drums may be reused without undergoing leakproofness
testing only for five years from the date of manufacture, consistent
with the UN Recommendations. After five years from the date of
manufacture, such drums could continue to be used only if leakproofness
tested prior to each reuse. Metal and plastic drums can only be reused
without leak testing when refilled with the same or similar contents,
and transported by a private carrier, contract carrier, or common
carrier in a transport vehicle or freight container used exclusively
for such service, within a distribution chain controlled by the
offeror. As proposed in the NPRM, other packagings could qualify only
if approved by the Associate Administrator for Hazardous Materials
Safety. In any case, a packaging which, upon visual examination, shows
evidence of a reduction in integrity must be reconditioned and, if
applicable, leak tested, before being reused.
RSPA does not agree with commenters who suggested that the waiver
of leak testing requirements be extended to metal drums other than
those made from stainless steel, monel, and nickel. Transportation
stresses typically can cause leakage, from the chime seams of these
drums, that is most appropriately detected through the performance of a
leakproofness test.
In addition, paragraph (c)(1)(i) is revised to clarify that only
external coatings must be removed when reconditioning metal drums.
Section 173.33. Paragraph (c)(5) is amended as proposed to limit
the provisions of the paragraph to materials in Packing Groups I and II
of Division 6.1.
Section 173.52. The descriptions of Compatibility Group B is
revised to clarify that detonators and similar articles are included
within this description even if they do not contain primary explosives.
In addition, in the descriptions for Compatibility Groups E and F, the
word ``gel'' is added to clarify that articles with a propelling charge
containing gel may not be classified in Compatibility Group E or F.
Section 173.59. The definitions ``powder, smokeless,''
``propellants,'' and ``charges, propelling'' are revised and
definitions for ``charges, propelling, for cannon,'' ``propellent,
liquid,'' and ``propellant, solid'' are added.
Section 173.60. Paragraph (b)(15) is added to require all plastic
packagings to be static-resistant.
Section 173.62. The Explosives Table is amended to add new
descriptions for Class 1 materials. In addition, the packing method for
UN0075 and UN0143 is revised to E-159. The Table of Packing Methods is
editorially revised to change the reference to steel and aluminum boxes
from 4A1 or 4A2 to 4A and 4B1 or 4B2 to 4B. Several packing methods are
revised by authorizing aluminum boxes (4B) as an alternate packaging.
For clarity, the entire Explosive Packing Methods Table has been
reprinted along with the Table of Particular Packaging Requirements and
Exceptions. Paragraph (e) is revised to update the military packaging
exception to allow explosives packaged prior to January 1, 1990, to be
transported in accordance with the packaging provisions in effect on
that date.
Section 173.115. The definition of a Division 2.2 gas is expanded
to include asphyxiant and oxidizing gases. However, based on comments
received, the definition is revised to be more consistent with the
definition in the UN Recommendations. In addition, the definitions of
asphyxiant gas and oxidizing gas proposed in the NPRM have been moved
to Sec. 171.8.
Section 173.120. RSPA received several comments supporting the new
exceptions for Class 3 materials. Some of these commenters requested
that these exceptions be extended to the definition of combustible
liquids. Through RSPA agrees that similar exceptions should be adopted
for the definition of combustible liquid, the exceptions have been
established for materials with a flash point of 141 deg.F or below.
The tests may not be appropriate for a material with a flash point of
below 200 deg.F. Therefore, RSPA is unable to adopt this suggestion.
However, if data is provided to support adoption of these test methods,
or a modified form thereof, RSPA will initiate a new rulemaking action
to adopt these exceptions for combustible liquids.
Section 173.121. Criteria for including viscous Class 3 materials
in Packing Group III is revised. Several modifications to the method
are provided when the temperature of the flash point is too low for the
standard procedures. The table in Sec. 173.121(b)(1)(iv) is amended for
consistency with the eighth revision of the UN Recommendations.
Section 173.124. The definition of self-reactive materials is
revised to conform to the changes in the UN Recommendations, which now
contains ``generic'' shipping descriptions. Seven types of self-
reactive material (Types A-G) are defined in paragraph (a)(2). The
procedure for assigning a specific self-reactive material to a generic
type is set forth in paragraph (a)(2)(vi). If a self-reactive material
is identified by technical name in the Self-Reactive Materials Table in
Sec. 173.224, the generic type is assigned in that Table. The lengthy
process by which importing and exporting countries agree on the
packaging requirements or assignment of a shipping description for a
new self-reactive material is avoided by using this procedure.
Section 173.128. Editorial revisions are made in paragraphs (a),
(c)(2) and (c)(3), paragraph (b)(7) is clarified and procedures for
obtaining approvals are clarified in revised paragraph (d).
Section 173.136. RSPA received several comments on the adoption of
the OECD Guidelines in the definition of Class 8 (corrosive materials).
Some commenters supported the proposed change, while others opposed it
and requested that RSPA not adopt it. Those that opposed the change to
the Class 8 definition cited problems with retesting of chemicals
tested under the old definition, moistening of solid materials before
testing, and ``full thickness testing.'' The changes adopted in this
final rule to the definition of Class 8 are a refinement of the
existing definition. RSPA will not require the retesting of materials
that have been classified under the test method previously found in
Appendix A of Part 173. In addition, the new definition will not expand
significantly the number of materials subject to the HMR. Although the
OECD Guidelines require appropriate moistening of a solid material
before application to the skin, this minuscule amount of liquid should
have no effect on the outcome of the test. In addition, review of some
past testing of corrosive solids indicates that moistening is already
being used as a vehicle to assure good contact with the skin. As stated
by one commenter, the new definition will provide standardization in
classifying these materials; make more definitive information available
to emergency responders, drivers, cargo handlers, and others; and will
facilitate the safe handling and emergency response procedures for
corrosive materials. Therefore, RSPA is adopting the changes to the
definition of Class 8 and assignment of Class 8 Packing Groups, as
proposed.
Section 173.150. RSPA proposed to add language in the introductory
text of Sec. 173.150(b) to specifically address combustible liquids in
the limited quantity provisions. RSPA received a comment in opposition
to this proposal stating that there is no difference in the way
combustible liquids that are hazardous substances or hazardous wastes
(versus non-hazardous substances or non-hazardous wastes) are treated
under the current wording of these provisions. However, combustible
liquids in non-bulk packagings that meet the definition of a hazardous
substance, hazardous waste, or marine pollutant currently are subject
to shipping paper, marking, placarding and other requirements set forth
in Sec. 173.150(f)(3). RSPA is adopting the proposed language to
clarify that combustible liquids are eligible for the limited quantity
exceptions if they are packaged accordingly.
Section 173.152. The limited quantity provisions for organic
peroxides are amended by increasing the authorized net capacity per
inner packaging for Type D, E, or F liquid and solid organic peroxides
and Type B or C solid organic peroxides. However, the authorized net
capacity for liquid Type B or C organic peroxides is decreased from 30
ml to 25 ml per inner packaging.
Section 173.158. Based on the merits of a comment and a petition
for rulemaking (P-1170), a new paragraph (f)(3) is added for nitric
acid of 70 percent or less to authorize combination packagings
consisting of inner plastic packagings individually overpacked in
tightly closed metal packagings, and further packed in an outer
packaging, such as a drum or box. This packaging currently is
authorized for transportation in cargo aircraft only, but there is no
comparable authorization for transport in other modes. Offerors of
nitric acid in plastic packagings are reminded of the compatibility
requirements specified in Sec. 173.24(e).
Section 173.164. Certain exceptions for mercury (metallic and
articles containing mercury), are revised, and a 4H2 solid plastic box
is authorized as an outer packaging, consistent with the ICAO Technical
Instructions.
Section 173.166. This section is amended to limit its applicability
to air bag inflators and modules showing certain specified results when
subjected to a bonfire test. Airbag modules and inflators not meeting
the test criteria must be transported as explosives. RSPA received
several comments on the transportation of airbags, many of which were
outside the scope of this rulemaking. One commenter requested that RSPA
revise proposed proper shipping names for airbags, but did not provide
sufficient justification for adding a domestic-only proper shipping
name for these commodities. The comments requesting new packaging
authorization and removal of the Ex-number marking requirements have
been denied because they are considered beyond the scope of this
rulemaking.
Section 173.168. RSPA proposed the addition of a separate section
to define a ``nonspillable battery,'' establish separate requirements
for nonspillable batteries (as opposed to the requirements for wet
batteries contained in Sec. 173.159), and provide vibration and
pressure differential testing criteria. Except when transporting a
wheelchair or other battery-powered mobility aid equipped with a
nonspillable battery by air as checked baggage, a nonspillable battery
which is protected against short circuits, securely packaged and
durably marked is not subject to any other HMR requirements. After
further deliberation, RSPA has decided not to create a separate section
for nonspillable batteries and, therefore, provisions for these
batteries will remain in Sec. 173.159.
Section 173.171. Paragraph (a) is revised as proposed to clarify
that smokeless powder must be examined and approved as both Division
1.3 and Division 4.1.
Section 173.185. RSPA is amending the requirements for lithium
batteries consistent with changes in the UN Recommendations. While the
new requirements apply more severe test requirements to lithium
batteries, they also allow batteries with higher quantities of lithium
to be transported without being subject to the regulations, provided
specified criteria are met. Existing batteries previously allowed to be
transported as Class 9 batteries may continue to be transported under
the present requirements indefinitely if the present requirements are
met. One commenter to this section asked why rechargeable batteries are
no longer specifically mentioned in the section. Rechargeable batteries
are no longer mentioned in the section because such batteries are being
treated in the same manner as other lithium batteries.
Section 173.189. RSPA received two comments on the proposed
transport of sodium batteries. One commenter requested that sodium
batteries installed in motor vehicles be excepted from the HMR, and the
other requested that sodium batteries be allowed to contain
polysulfides. RSPA concurs with these commenters and has revised this
proposed section accordingly.
Section 173.196. RSPA is adopting the proposed revision to
paragraph (f) to clarify that either the inner receptacle or the outer
packaging for infectious substances must be capable of withstanding the
prescribed pressure differential.
Section 173.211-213. These sections are adopted as proposed to
change packaging identification codes (for steel boxes from 4A1 to 4A2
to 4A and for aluminum boxes from 4B1 and 4B2 to 4B) for consistency
with international requirements.
Section 173.224. This section is revised based on the UN
Recommendations. Paragraph (b) sets forth the Self-Reactive Materials
Table which identifies the technical name for specific self-reactive
materials, the identification number which is used to select the
appropriate generic shipping description, specifications for
concentrations of the self-reactive material, packing methods that may
be used, temperature control requirements, and additional special
provisions. The existing packing methods for self-reactive materials
are replaced with the packing methods for organic peroxides which are
prescribed in Sec. 173.225.
Paragraph (c) sets forth procedures for new self-reactive
materials, formulations and samples. New self-reactive materials and
formulations of currently identified self-reactive materials must be
approved in accordance with the provisions in Sec. 173.124(a)(2)(vi).
Paragraph (c)(4) contains provisions for the shipping of samples of new
formulations. Paragraph (d) specifies that self-reactive materials of
Type F may be transported in bulk only under the approval of the
Associate Administrator for Hazardous Materials Safety.
Section 173.225. In Sec. 173.225, paragraph (a) is revised to
prohibit the use of metallic non-bulk packagings meeting a Packing
Group I packaging standard. Paragraph (c)(5) is added to authorize the
transportation of mixtures of organic peroxides that are specifically
identified in the Organic Peroxides Table without approval by the
Associate Administrator for Hazardous Materials Safety. In addition,
the Organic Peroxide Table is revised to add new organic peroxides
adopted in the UN Recommendations. Several miscellaneous changes, based
on comments, have been made to the Table. In addition, for use
domestically, RSPA is adding 12 new organic peroxides that are not
listed in the UN Recommendations but have been approved by RSPA for
domestic transportation.
Section 173.304. In the paragraph (a)(2) table, for the entry
``carbon dioxide,'' an erroneous reference to a DOT-311800 cylinder is
corrected to authorize a DOT-3T1800 cylinder for carbon dioxide.
Section 173.306. In paragraph (a)(3)(v), the hot water immersion
test for aerosols and small gas receptacles includes a reference
temperature of 50 deg.C (122 deg.F) in addition to the reference
temperature of 55 deg.C (131 deg.F). A reference temperature of
50 deg.C is permitted if the liquid phase of the materials contained in
the receptacle does not exceed 95 percent of the capacity of the
receptacle at 50 deg.C. In addition, provisions are added for plastic
receptacles or contents which are sensitive to heat.
Appendix A to Part 173. Appendix A, which provides a method of
testing corrosion to skin, is removed and reserved for consistency with
changes to the definition and packing group assignment for Class 8
materials.
Appendix E to Part 173. New criteria are added for self-reactive
materials possessing explosive properties, and an editorial change is
made to clarify that powders of metals or metal alloys that can be
ignited are classified in Division 4.1.
Appendix F to Part 173. In paragraph 1., an editorial revision is
made to correctly reference Division 5.1.
Appendix H to Part 173. A new Appendix H is added to Part 173 to
provide a method of testing for combustibility. This method outlines a
procedure for determining if a material can sustain combustion if
heated under test conditions and exposed to an external source of
flame.
Part 175
Section 175.10. The phrase ``environmental restoration or
protection'' is added as an exception in paragraph (a)(12) to clarify
that certain aircraft operations pertaining to environmental
restoration may be conducted under the provisions of this paragraph.
Exceptions for carbon dioxide (dry ice) are consolidated into paragraph
(a)(13) to except this material from regulation from Part 175 when it
is used as a refrigerant for a package, intended for use in food or
beverage service aboard an aircraft, or used to pack perishables in
carry-on baggage. Based on the merit of two comments, proposed
paragraph (a)(4) more closely adopts the language of the ICAO Technical
Instructions to permit non-radioactive medicinal or toilet articles
(including aerosols) in either carry-on baggage or checked baggage. It
also permits aerosols in Division 2.2 having no subsidiary risk, if
intended for sporting or home use, in checked baggage. In addition, a
new paragraph (a)(26) is added to except from regulation small medical
or clinical mercury thermometers carried by passengers or crew members
for personal use.
Section 175.33. Paragraph (a)(1) is revised to require that a
compatibility group letter for a Class 1 material be included in the
written notification to the pilot-in-command. RSPA also proposed to add
a new paragraph (a)(9) to require an aircraft operator to include an
air waybill number where one has been issued. However, based on the
merit of a comment from the Air Transport Association, RSPA agrees that
the placement of an airway bill number on the notification does nothing
to enhance safety. Therefore, this proposed requirement is not adopted.
Part 176
Section 176.27. RSPA proposed the addition of a new paragraph (c)
to reference a container packing certificate required under the
provisions of the SOLAS Convention and the IMDG Code. Commenters to
this proposal did not object to its addition, but suggested that the
certification contain a reference to the section outlining the
requirements rather than a certification that each of the requirements
have been met. RSPA agrees, and is revising proposed paragraph (c)(2).
In addition, the Hazardous Materials Advisory Council (HMAC) and the
Chemical Manufacturers Association (CMA) asked RSPA to clarify that the
container packing certificate is to be presented to the vessel carrier
at the time the hazardous materials are offered for transportation by
vessel. A clarification is added in paragraph (c)(1) in response to
this request.
Section 176.76. A new paragraph (i) is adopted as proposed to
address the transport of fumigated transport units on vessels. These
fumigation requirements are in addition to the fumigation requirements
contained in Sec. 173.9. The new vessel requirements are generally
consistent with the IMDG Code requirements for transporting fumigated
transport units and are consistent with Special Permits currently being
issued by the Coast Guard for U.S. maritime transport of fumigated
transport units.
Part 177
Section 177.841. Revised paragraph (e)(3) is adopted as proposed to
specify requirements for separating Division 6.1 Packing Group III
materials from foodstuffs, consistent with provisions in Sec. 177.848.
Part 178
Section 178.2. Changes to paragraphs (a) and (e) are adopted as
proposed. Paragraph (a) is revised to clarify that Part 178
requirements for UN standard packagings apply only to packagings
manufactured in the U.S. See Sec. 173.24(d)(2) for foreign-manufactured
packagings. A new paragraph (e) is added to include definitions for
``manufacturer'' and ``specification markings.'' These new definitions
specify who is to be identified through a specification marking as the
``manufacturer'' and clarify the manufacturer's responsibility under
Part 178.
Section 178.3. One commenter thought that the location of
manufacture should be immaterial to the use of the ``USA'' mark. This
commenter stated that the ``USA'' mark should be described as simply
indicating compliance with Part 178, regardless of where the packaging
is physically manufactured and asked RSPA to clarify the use of the
marking ``USA'' for a DOT specification or UN specification packaging
that is manufactured in the U.S. or in another country. RSPA believes
that a ``USA'' marked packaging should be manufactured and marked only
in the U.S., and that packagings manufactured in the U.S. must be
marked ``USA'' and comply with Part 178.
Section 178.502. In paragraph (a) introductory text and paragraph
(a)(1), the terms ``type'' or ``types'' of packagings are revised for
consistency with international regulations to read ``kind'' or
``kinds'' of packagings.
Section 178.503. As proposed in the NPRM, this section is revised
to incorporate changes in the UN Recommendations with regard to the
marking of non-bulk packagings. Consistent with the UN Recommendations,
each packaging certified to a UN standard must have a series of
markings which describe the packaging and its characteristics. The
Steel Shipping Container Institute (SSCI) objected to the lower weight
limit for packagings which would be required to be marked on the top or
side, suggesting that a capacity limit, such as 30 liters, would be
more appropriate. SSCI pointed out that, if all packagings over 30 kg
are required to be marked on the side or top, packagings as small as 5
gallons, if they are used to ship very dense products, must be marked
this way. In the UN Recommendations, and as proposed in the NPRM, the
threshold of 30 kg above which packagings must be marked on the top or
a side is intended to represent the maximum weight that a person can
reasonably be expected to lift in order to see the markings on the
bottom of a package. The important consideration is weight, rather than
capacity, and therefore the 30 kg size limit, after which markings must
be applied on the top or side, is adopted in this final rule. This
requirement has been moved to Sec. 178.3(a)(5) to appear with related
marking requirements.
Currently, Sec. 178.503 requires that metal or plastic drums or
jerricans intended for reuse be marked with the minimum thickness of
the packaging material. Consistent with the UN Recommendations, in this
final rule metal drums and jerricans intended for reuse must be marked
with the nominal thickness. The nominal thickness marked must be in
accordance with ISO 3574; that is, the nominal thickness marked may
only exceed the actual minimum thickness of the packaging material by
the tolerance specified in ISO 3574. A commenter suggested that RSPA
clarify, for a metal packaging marked with a nominal thickness, what
the minimum thickness must be. In this final rule, a table indicating
what minimum thickness corresponds to the nominal thickness specified
in ISO Standard 3574, for various packaging capacities, has been added
to a new Appendix C to Part 178. Packagings to be used are still
subject to the minimum thickness requirements of Sec. 173.28. Because
the eighth revised edition of the UN Recommendations did not address
thickness requirements for plastic packagings, plastic drums and
jerricans intended for reuse must continue to be marked with the
minimum thickness of the packaging material.
In additional to the full marking on the top or side of a metal
drum having a capacity greater than 100 liters, paragraph (a)(10)
requires a permanent marking of the drum characteristics on the bottom
of the drum. The country authorizing the mark and the name and address
of the manufacturer are not required as part of this permanent mark.
This marking identifies the packaging as it was originally
manufactured, and may not necessarily be used to determine compliance
with packaging requirements. For example, if a non-removable head drum
has been converted to a removable head drum, this conversion is not
reflected in the marking on the bottom of the drum, but is evident in
the top or side marking. For drums marked permanently on the bottom,
the top or side mark is not required to be permanent (i.e., able to
withstand the reconditioning process). RSPA is not adopting a
commenter's suggestion that the permanent marking on the bottom of a
drum not be required if the markings appearing on the top or side of
the packaging are permanent. RSPA believes this type of change should
be considered first by the UN Committee of Experts.
As proposed in the NPRM, the additional permanent marking on the
bottom of a drum would have applied to plastic drums as well as metal
drums. Several commenters objected to this proposal as it applied to
plastic drums. RSPA notes that the UN Recommendations do not require
plastic drums to bear the additional permanent marking on the bottom of
the drum, and most plastic drums are permanently marked on the side.
Based on the merit of comments, and consistent with the UN
Recommendations, RSPA is limiting the additional marking requirement of
paragraph (a)(10) to metal drums with a capacity greater than 100
liters.
Based on comments from ACR, the marking requirements for metal
drums with a capacity greater than 100 liters have been revised in this
final rule for greater consistency with the UN Recommendations, and for
clarity. As proposed in the NPRM, the permanent marking requirements of
paragraph (a)(10) would have applied only to those metal drums
``intended for reuse or reconditioning as a single packaging or the
outer packaging of a composite packaging.'' ACR stated that the
determination of suitability for reuse or reconditioning is not made by
the manufacturer. RSPA agrees, and the qualifier ``intended for reuse
or reconditioning'' is not adopted in this final rule.
A commenter was concerned that a semi-permanent label would not be
considered ``durable'' for purposes of the UN marking. RSPA would
consider the use of a printed label to satisfy the requirement for
``durable'' markings, provided the label can withstand the rigors of
normal transportation.
Paragraph (c) specifies additional requirements for markings on
reconditioned metal drums. The paragraph requires that reconditioners
reapply markings which no longer appear on drums after the
reconditioning process. A reconditioner can duplicate the original
markings or apply markings which reflect a lower performance level, but
cannot apply markings which identify a performance level greater than
that for which the original design type had been tested and marked.
A new paragraph (d) clarifies marking requirements for
remanufactured packagings. Based on a comment from ACR, paragraph (d)
specifies that required markings need not be permanent on
remanufactured metal drums for which there is no change to the
packaging type, and no replacement of integral structural components.
All other remanufactured metal drums must be permanently marked on the
top or side. This paragraph was not proposed in the NPRM, but is
considered necessary to ensure that packagings can be properly marked
after remanufacture, when it may not be possible to permanently mark on
the bottom.
Section 178.512. Standards for steel boxes and aluminum boxes are
consolidated by removing the distinction between unlined/uncoated steel
or aluminum boxes and steel or aluminum boxes having an inner liner or
coating. Therefore, both unlined and lined steel boxes are identified
as 4A and unlined and lined aluminum boxes are identified as 4B.
Corresponding revisions are reflected in the packaging authorizations
of Part 173.
Section 178.513. A new paragraph is added to the standards for
natural wood boxes to specify fastening requirements.
Section 178.516. Paragraph (b)(1) contains an updated reference to
ISO Standard 535-1976(E). Paragraph (b)(2) is revised to authorize the
ends of fiberboard boxes to be constructed of suitable materials other
than wood, which is already authorized. As proposed in the NPRM,
paragraph (b)(3)(iii) is redesignated as (b)(4) to clarify that the
requirement for water-resistant adhesive applies to all box closures,
and not only the manufacturer's joint. In its comments, 3M suggested
that RSPA include ASTM D5570, Standard Test Method for Water Resistance
of Tape and Adhesives Used as a Box Closure, as a standard for
determining the water resistance of adhesives used in 4G boxes. Since
RSPA did not propose such a standard in the NPRM, the suggestion is not
adopted in this final rule.
Section 178.521. In paragraph (b)(2), the term ``water-resistant''
is revised to ``waterproof'', and examples of a waterproof ply or
barrier are provided.
Section 178.522. A composite packaging consisting of a plastic
receptacle in a protective plastic drum is designated as 6HH in the
current HMR standards. The UN Recommendations recently adopted a new
composite packaging standard to authorize a plastic receptacle in a
protective plastic box. Therefore, in paragraph (b)(3), the previous
6HH composite packaging is redesignated at 6HH1 and the new composite
packaging (the plastic receptacle in a protective plastic box) is
designated as 6HH2.
Section 178.601. Paragraph (b) is adopted as proposed to limit the
responsibility of shippers to those packaging assembly functions they
actually perform or are responsible for performing. A revision to
paragraph (b)(2) removes the shipper responsibility provision regarding
packaging fabrication and testing functions not performed by the
shipper. Only one commenter did not favor this proposal. The Society of
the Plastics Industry believed that a shipper should share some
responsibility for compliance, such as obtaining a certification from
the packaging manufacturer for each type of packaging used in hazardous
materials service. Paragraph (g)(2)(i) is revised to clarify that
selective testing under Variation 2 requires the fragile inner
packagings to contain liquids. A new sentence is added to the end of
paragraph (g)(2)(vi) to clarify that where outer packagings are not
leakproof or siftproof and consequently require some type of leakproof
liner, plastic bag or other means of containment, sufficient absorbent
material must be placed inside the liner or bag. A new paragraph (k) is
added to permit several tests to be performed on one sample if the
validity of test results is not affected and if approved by the
Associate Administrator for Hazardous Materials Safety. Newly
designated paragraph (l) is revised as proposed to clarify
recordkeeping requirements and provide consistency with test report
requirements in the UN Recommendations. One commenter requested
clarification of the methods by which a test method is ``maintained''
at each location where a packaging is manufactured. This commenter
asked if a manufacturer's central office could maintain records when
multiple locations are involved and provide access through a computer
data base or fax. ``Maintained'' as provided in Sec. 178.601(l) is
limited to hard copies of test reports or electronic storage of reports
at each manufacturing location. Inspectors cannot conduct inspections
without test records to compare to the packages. Therefore, the company
may maintain records at a central office so long as the company is
capable of providing hard copy reports in a timely manner to an
inspector at the time of inspection. SSCI pointed out that paragraph
(l)(10) is redundant with paragraph (l)(1) in that both require an
identification of the address of the test facility. RSPA agrees, and
paragraph (l)(10), as adopted, requires the title, rather than the
address, of the signatory to be included.
Section 178.602. In paragraph (c) a reference to
``Sec. 178.603(d)(2)'' is corrected to read ``Sec. 178.603(e)''.
Section 178.603. In paragraph (a), a new provision is added to
require that the drop test be performed using the package orientation
most likely to result in failure if more than one orientation is
possible. Paragraph (c) is revised to clarify that the cold drop test
outlined in this paragraph applies only to plastic packagings, and
applies to combination packagings with inner plastic bags only when the
inner packagings are intended to contain liquids. A revision to
paragraph (f)(1) clarifies that inner packagings of combination
packagings are not required to be vented to reach equilibrium after the
drop test.
Section 178.604. For consistency with a change in the UN
Recommendations, the length of time to conduct a leakproofness test,
other than for production testing, is specified as five minutes in
revised paragraph (d).
Section 178.606. For consistency with the UN Recommendations, a
phrase is added in paragraph (c)(1) to clarify that the force to be
applied, when a test sample contains a non-hazardous liquid with a
specific gravity different from the hazardous liquid intended for
transport, must be calculated based on the specific gravity that will
be marked on the packaging.
Appendix C to Part 178. A new Appendix C is added to Part 178 to
incorporate a table indicating the corresponding nominal and minimum
thicknesses for packagings of varying capacities, in accordance with
ISO Standard 3574.
Rulemaking Analyses and Notices
A. Executive Order 12866 and DOT Regulatory Policies and Procedures
This final rule is not considered to be a significant regulatory
action under section 3(f) of Executive Order 12866 and was not reviewed
by the Office of Management and Budget. The rule is not considered
significant under the Regulatory Policies and Procedures of the
Department of Transportation [44 FR 11034]. A regulatory evaluation is
available for review in the Docket.
B. Executive Order 12612
This final rule has been analyzed in accordance with the principles
and criteria contained in Executive Order 12612 (``Federalism'').
Federal law expressly preempts State, local, and Indian tribe
requirements applicable to the transportation of hazardous material
that cover certain covered subjects and are not substantively the same
as Federal requirements. 49 U.S.C. 5125(b)(1). These subjects are:
(A) The designation, description, and classification of hazardous
materials;
(B) The packing, repacking, handling, labeling, marking, and
placarding of hazardous material;
(C) The preparation, execution, and use of shipping documents
pertaining to hazardous material and requirements respecting the
number, content, and placement of such documents;
(D) The written notification, recording, and reporting of the
unintentional release in transportation of hazardous material; and
(E) The design, manufacturing, fabrication, marking, maintenance,
reconditioning, repairing, or testing of a package or container which
is represented, marked, certified, or sold as qualified for use in the
transportation of hazardous material.
This final rule concerns classification, packaging, labeling,
marking, shipping documentation, and manufacture of packaging for
hazardous material. Therefore, this final rule preempts State, local,
or Indian tribe requirements that are not substantively the same as
Federal requirements on these subjects.
Section 5125(b)(2) of title 49 U.S.C. provides that when DOT issues
a regulation concerning any of the covered subjects, DOT must determine
and publish in the Federal Register the effective date of Federal
preemption. That effective date may not be earlier than the 90th day
following the date of issuance of the final rule and not later than two
years after the date of issuance. RSPA has determined that the
effective date of Federal preemption for these requirements will be
October 1, 1995. Thus, RSPA lacks discretion in this area, and
preparation of a federalism assessment is not warranted.
C. Regulatory Flexibility Act
This rule incorporates changes introduced in the seventh and eighth
revised editions of the UN Recommendations, the 1993-1994 and 1995-1996
ICAO Technical Instructions, and Amendments 26 and 27 to the IMDG Code.
It applies to offerors and carriers of hazardous materials and
facilitates the transportation of hazardous materials in international
commerce by providing consistency with international requirements. If
this rule is not adopted, U.S. companies, including numerous small
entities competing in foreign markets, will be forced to comply with a
dual system of regulation, to their economic disadvantage. Therefore, I
certify that this rule will not have a significant economic impact on a
substantial number of small entities.
D. Paperwork Reduction Act
The requirements for information collection have been approved by
the Office of Management and Budget (OMB) under the provisions of the
Paperwork Reduction Act of 1980 (Pub. L. 95-511) under OMB control
number 2137-0034 for shipping papers and 2137-0557 for approvals.
E. Regulation Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory
action listed in the Unified Agenda of Federal Regulations. The
Regulatory Information Service Center publishes the Unified Agenda in
April and October of each year. The RIN number contained in the heading
of this document can be used to cross-reference this action with the
Unified Agenda.
List of Subjects
49 CFR Part 171
Exports, Hazardous materials transportation, Hazardous waste,
Imports, Incorporation by reference, Reporting and recordkeeping
requirements.
49 CFR Part 172
Hazardous materials transportation, Hazardous waste, Labels,
Markings, Packaging and containers, Reporting and recordkeeping
requirements.
49 CFR Part 173
Hazardous materials transportation, Packaging and containers,
Radioactive materials, Reporting and recordkeeping requirements,
Uranium.
49 CFR Part 175
Air carriers, Hazardous materials transportation, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 176
Hazardous materials transportation, Maritime carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 177
Hazardous materials transportation, Motor carriers, Radioactive
materials, Reporting and recordkeeping requirements.
49 CFR Part 178
Hazardous materials transportation, Motor vehicles safety,
Packaging and containers, Reporting and recordkeeping requirements.
In consideration of the foregoing, 49 CFR Chapter I is amended as
follows:
PART 171--GENERAL INFORMATION, REGULATIONS, AND DEFINITIONS
1. The authority citation for Part 171 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
2. In the Sec. 171.7(a)(3) Table, under the entry American Society
for Testing and Materials, a new entry is added in numerical order;
under the entry International Organization for Standardized, three new
entries are added at the end of existing entries; and a new entry is
added in alphabetical order, to read as follows:
Sec. 171.7 Reference material.
(a) * * *
(3) Table of material incorporated by reference. * * *
------------------------------------------------------------------------
49 CFR
Source and name of material reference
------------------------------------------------------------------------
* * * * * * *
American Society for Testing and Materials
* * * * * * *
ASTM G 31-72 (Reapproved 1990) Standard Practice for
Laboratory Immersion Corrosion Testing of Metals.......... 173.137
* * * * * * *
International Organization for Standardization
* * * * * * *
ISO 3574-1986(E) Cold-reduced carbon steel sheet of
commercial and drawing qualities.......................... 178.503
ISO 2592-1973(E) Petroleum products--Determination of flash
and fire points--Cleveland open cup method................ 173.120
ISO 9328-1--1991(E) Steel plates and strips for pressure
purposes--Technical delivery conditions--Part 1: General
requirements.............................................. 173.137
* * * * * * *
Organization for Economic Cooperation and Development
(OECD)
OECD Publications and Information Center, 2001 L
Street, Suite 700, Washington, DC 20036
OECD Guideline for Testing of Chemicals, No.404
``Acute Dermal Irritation/Corrosion'', 1992....... 173.137
* * * * * * *
------------------------------------------------------------------------
* * * * *
Sec. 171.7 [Amended]
3. In addition, in Sec. 171.7, in the table in paragraph (a)(3),
the following changes are made:
a. In the entry ASTM D 56-79, the wording ``D 56-79 Standard Method
of Test for Flash Point by Tag Closed Tester'' is revised to read ``D
56-93 Standard Test Method for Flash Point by Tag Closed Tester''.
b. In the entry ASTM D 93-80, the wording ``D 93-80 Standard Method
of Test for Flash Point by Pensky Martens Closed Tester'' is revised to
read ``D 93-90 Standard Test Methods for Flash Point by Pensky-Martens
Closed Tester''.
c. In the entry ASTM D 3278-78, the wording ``D 3278-78 Flash Point
of Liquids by Setaflash Closed Tester'' is revised to read ``ASTM D
3278-89 Standard Test Methods for Flash Point of Liquids by Setaflash
Closed-Cup Apparatus''.
d. In the entry ASTM D 4359-84, the wording ``D 4359-84'' is
revised to read ``ASTM D 4359-90''.
e. Under International Civil Aviation Organization (ICAO), for the
entry ``Technical Instructions for the Safe Transport of Dangerous
Goods by Air'', the date ``1993-1994'' is revised to read ``1995-
1996''.
f. Under International Maritime Organization (IMO), the entry
``International Maritime Dangerous Goods (IMDG) Code, 1990 Consolidated
Edition, as amended by Amendment 26 thereto'' is amended by removing
the wording ``Amendment 26 thereto'' and adding in its place the
wording ``Amendment 27 (1994)''.
g. Under International Organization for Standardization, the
wording ``ISO-535-1976(E) Paper and Board--Determination of Water
Absorption--Cobb Method'' is revised to read ``ISO-535-1991(E) Paper
and board--Determination of water absorptiveness--Cobb method''.
h. Under Transport Canada, the entry ``Transportation of Dangerous
Goods Regulations, as of July 1, 1985, incorporating Registration
Numbers SOR/85-77, SOR/85-585 and SOR/85-609'' is revised to read
``Transportation of Dangerous Goods Regulations, 1 July 1985, SOR/85/
77, incorporating the following Registration Numbers: SOR/85-314, SOR/
85-585, SOR/85-609, SOR/86-526, SOR/88-635, SOR/87-335, SOR/87-186,
SOR/89-39, SOR/89-294, SOR/90-847, SOR/91-711, SOR/91-712, SOR/92-447,
SOR/92-600, SOR/93-203, SOR/93-274, SOR/93-525, SOR/94-146 and SOR/94-
264 (English edition)''.
i. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Sixth Revised Edition (1989)'' the
wording ``Sixth Revised Edition (1989)'' is revised to read ``Eighth
Revised Edition (1993)''.
j. Under United Nations, for the entry ``UN Recommendations on the
Transport of Dangerous Goods, Tests and Criteria, Second Edition,
1990'', in column 2, the references ``173.124;'' ``173.128;''
``173.166;'' and ``173.185'' are added in appropriate numerical order.
4. In Sec. 171.8, the following definitions are added or revised,
as indicated, in appropriate alphabetical order to read as follows:
Sec. 171.8 Definitions and abbreviations.
[Add:]
* * * * *
Asphyxiant gas means a gas which dilutes or replaces oxygen
normally in the atmosphere.
* * * * *
Gas means a material which has a vapor pressure greater than 300
kPa (43.5 psi) at 50 deg.C (122 deg.F) or is completely gaseous at
20 deg.C (68 deg.F) at a standard pressure of 101.3 kPa (14.7 psi).
* * * * *
Oxidizing gas means a gas which may, generally by providing oxygen,
cause or contribute to the combustion of other material more than air
does.
* * * * *
Siftproof packaging means a packaging impermeable to dry contents,
including fine solid material produced during transportation.
* * * * *
[Revise:]
* * * * *
Box means a packaging with complete rectangular or polygonal faces,
made of metal, wood, plywood, reconstituted wood, fiberboard, plastic,
or other suitable material. Holes appropriate to the size and use of
the packaging, for purposes such as ease of handling or opening, or to
meet classification requirements, are permitted as long as they do not
compromise the integrity of the packaging during transportation, and
are not otherwise prohibited in this subchapter.
* * * * *
Liquid means a material, other than an elevated temperature
material, with a melting point or initial melting point of 20 deg.C
(68 deg.F) or lower at a standard pressure of 101.3 kPa (14.7 psi). A
viscous material for which a specific melting point cannot be
determined must be subjected to the procedures specified in ASTM D 4359
``Standard Test Method for Determining Whether a Material is Liquid or
Solid''.
* * * * *
Overpack, except as provided in subpart K of part 178 of this
subchapter, means an enclosure that is used by a single consignor to
provide protection or convenience in handling of a package or to
consolidate two or more packages. Overpack does not include a transport
vehicle, freight container, or aircraft unit load device. Examples of
overpacks are one or more packages:
(1) Placed or stacked onto a load board such as a pallet and
secured by strapping, shrink wrapping, stretch wrapping, or other
suitable means; or
(2) Placed in a protective outer packaging such as a box or crate.
* * * * *
Solid means a material which is not a gas or a liquid.
* * * * *
UN standard packaging means a packaging conforming to standards in
the UN Recommendations on the Transport of Dangerous Goods.
* * * * *
Sec. 171.11 [Amended]
5. In Sec. 171.11, in the last sentence of paragraph (d)(5), the
wording ``Poison'' is revised to read ``Poison or Toxic''.
Sec. 171.12 [Amended]
6. In Sec. 171.12, in paragraph (b) introductory text, in the
second sentence, the wording ``stowed and segregated, and certified in
accordance with the IMDG Code'' is revised to read ``stowed and
segregated, and certified (including a container packing certification,
if applicable) in accordance with the IMDG Code''.
7. Section 171.14 is revised to read as follows:
Sec. 171.14 Transitional provisions for implementing requirements
based on the UN Recommendations.
General. The purpose of the provisions of this section is to
provide an orderly transition to new requirements based on the UN
Recommendations, so as to minimize any burdens associated with them.
Subsequent final rules may implement different time requirements than
the transitional provisions in this section. When the effective date
section or regulatory text of a final rule imposes a compliance date
earlier or later than that which would be required under this section,
the transition date in this section does not apply.
(a) A rule published in the Federal Register on December 21, 1990,
effective October 1, 1991, resulted in a comprehensive revision of this
subchapter based on the UN Recommendations. Final rules published in
the Federal Register on December 20, 1991 effective October 1, 1991,
October 1, 1992 effective October 1, 1992, September 24, 1993 effective
October 1, 1993, and September 22, 1994 effective September 22, 1994,
further revised the December 21, 1990 final rule. Prior to an
applicable transition date in paragraph (a)(1) of this section, a
person may elect to comply with either the applicable requirements of
this subchapter in effect on September 30, 1991, or the requirements of
this subchapter appearing in the December 20, 1990 rule, as revised in
final rules published in the Federal Register on December 20, 1991,
October 1, 1992, September 24, 1993, and September 22, 1994.
(1) Transition dates. The following transition dates apply only to
requirements in the December 21, 1990 rule, as revised in the December
20, 1991, October 1, 1992, September 24, 1993, and September 22, 1994
final rules:
(i) January 1, 1995. On January 1, 1995, all applicable regulatory
requirements, including those pertaining to classification (see
Sec. 173.134 of this subchapter), hazard communication, and packaging,
are effective for Division 6.2 materials (infectious substances) other
than regulated medical waste and infectious substances affecting
animals only.
(ii) October 1, 1995. On October 1, 1995, all applicable regulatory
requirements, including those pertaining to classification (see
Sec. 173.134 of this subchapter), hazard communication, and packaging
are effective for regulated medical waste (Division 6.2) and infectious
substances affecting animals only (Division 6.2).
(iii) October 1, 1996. On October 1, 1996, requirements in Parts
172 and 173 of this subchapter for maintenance and use of packagings
that were not previously in effect are effective. (DOT specification
packagings removed from Part 178 of this subchapter by the December 21,
1990 final rule and packaging authorizations removed from Part 173 of
this subchapter by the December 21, 1990 final rule may no longer be
used in place of new packaging requirements.)
(2) Other transitional provisions--(i) Packages filled prior to
October 1, 1991. Notwithstanding the marking and labeling provisions of
Subparts D and E, respectively, of Part 172, and the packaging
provisions of Part 173 and Subpart B of Part 172 of this subchapter, a
package may be offered for transportation and transported prior to
October 1, 2001, if it--
(A) Conforms to the old requirements of this subchapter in effect
on September 30, 1991;
(B) Is filled with hazardous materials prior to October 1, 1991;
(C) Is marked ``Inhalation Hazard'', if appropriate, in accordance
with Sec. 172.313 of this subchapter or Special Provision 13, as
assigned in the Sec. 172.101 Table; and
(D) Is not emptied and refilled on or after October 1, 1991.
(ii) Transitional placarding provisions. Until October 1, 2001,
placards which conform to specifications for placards in effect on
September 30, 1991, may be used in place of the placards specified in
Subpart F of Part 172 of this subchapter, in accordance with the
following table:
Placard Substitution Table
------------------------------------------------------------------------
Hazard class or Old (Sept. 30, 1991)
division number Current placard name placard name
------------------------------------------------------------------------
Division 1.1........... Explosives 1.1......... Explosives A.
Division 1.2........... Explosives 1.2......... Explosives A.
Division 1.3........... Explosives 1.3......... Explosives B.
Division 1.4........... Explosives 1.4......... Dangerous.
Division 1.5........... Explosives 1.5......... Blasting agents.
Division 1.6........... Explosives 1.6......... Dangerous.
Division 2.1........... Flammable gas.......... Flammable gas.
Division 2.2........... Nonflammable gas....... Nonflammable gas.
Division 2.3........... Poison gas............. Poison gas.
Class 3................ Flammable.............. Flammable.
Combustible liquid..... Combustible............ Combustible.
Division 4.1........... Flammable solid........ Flammable solid.
Division 4.2........... Spontaneously Flammable solid.
combustible.
Division 4.3........... Dangerous when wet..... Flammable solid W.
Division 5.1........... Oxidizer............... Oxidizer.
Division 5.2........... Organic peroxide....... Organic peroxide.
Division 6.1, PG I and Poison................. Poison.
II.
Division 6.1, PG III... Keep away from food.... (none required).
Class 7................ Radioactive............ Radioactive.
Class 8................ Corrosive.............. Corrosive.
Class 9................ Class 9................ (none required).
------------------------------------------------------------------------
(b) A rule published in the Federal Register on December 29, 1994,
effective October 1, 1995, resulted in further revisions to this
subchapter based on the UN Recommendations. During the transition
period provided in paragraph (b)(1) of this section, a person may elect
to comply with either the applicable requirements of this subchapter in
effect on September 30, 1995, the applicable requirements based on the
transition dates provided in paragraph (a)(1) of this section, or the
requirements of this subchapter appearing in the December 29, 1994,
final rule.
(1) Transition date. On October 1, 1996, all applicable regulatory
requirements adopted in the December 29, 1994, final rule must be met.
(2) Intermixing old and new requirements. Prior to the transition
date in paragraph (b)(1) of this section, it is recommended that hazard
communication requirements be consistent where practicable, i.e.,
marking, labeling, placarding, and shipping paper descriptions should
conform to either the old requirements of this subchapter in effect on
September 30, 1995, or new requirements of this subchapter added or
revised by the December 29, 1994, rule, without intermixing of
communication elements. However, intermixing is permitted, during the
applicable transition period, for packaging, hazard communication, and
handling provisions, as follows:
(i) If either shipping names or identification numbers are
identical, a shipping paper may display the old shipping description
even if the package is marked and labeled under the new shipping
description;
(ii) If either shipping names or identification numbers are
identical, a shipping paper may display the new shipping description
even if the package is marked and labeled under the old shipping
description; and
(iii) Either old or new placards may be used regardless of whether
old or new shipping descriptions and package markings are used.
PART 172--HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS
MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND
TRAINING REQUIREMENTS
8. The authority citation for part 172 continues to read as
follows:
Authority: 49 U.S.C. 5101-5127; 49 CFR 1.53.
9. In Sec. 172.101, paragraphs (c)(3), (c)(13) and (k)(1) through
(k)(5) are revised and, in paragraph (g), a new sentence is added as
the last sentence to read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
(c) * * *
(3) The word ``poison'' or ``poisonous'' may be used
interchangeably with the word ``toxic'' when only domestic
transportation is involved. The abbreviation ``n.o.i.'' or
``n.o.i.b.n.'' may be used interchangeably with ``n.o.s.''.
* * * * *
(13) Self-reactive materials and organic peroxides. A generic
proper shipping name for a self-reactive material or an organic
peroxide, as listed in Column 2 of the Table, must be selected based on
the material's technical name and concentration, in accordance with the
provisions of Secs. 173.224 or 173.225 of this subchapter,
respectively.
* * * * *
(g) * * * No label is required for a material classed as a
combustible liquid or for a Class 3 material that is reclassed as a
combustible liquid.
* * * * *
(k) * * *
(1) Stowage category ``A'' means the material may be stowed ``on
deck'' or ``under deck'' on a cargo vessel and on a passenger vessel.
(2) Stowage category ``B'' means--
(i) The material may be stowed ``on deck'' or ``under deck'' on a
cargo vessel and on a passenger vessel carrying a number of passengers
limited to not more than the larger of 25 passengers, or one passenger
per each three meters of overall vessel length; and
(ii) ``On deck only'' on passenger vessels in which the number of
passengers specified in paragraph (k)(2)(i) of this section is
exceeded.
(3) Stowage category ``C'' means the material must be stowed ``on
deck only'' on a cargo vessel and on a passenger vessel.
(4) Stowage category ``D'' means the material must be stowed ``on
deck only'' on a cargo vessel and on a passenger vessel carrying a
number of passengers limited to not more than the larger of 25
passengers or one passenger per each three meters of overall vessel
length, but the material is prohibited on passenger vessels in which
the limiting number of passengers is exceeded.
(5) Stowage category ``E'' means the material may be stowed ``on
deck'' or ``under deck'' on a cargo vessel and on a passenger vessel
carrying a number of passengers limited to not more than the larger of
25 passengers, or one passenger per each three meters of overall vessel
length, but is prohibited from carriage on passenger vessels in which
the limiting number of passengers is exceeded.
* * * * *
Sec. 172.101 [Amended]
10. In addition, in Sec. 172.101, the following changes are made:
a. In paragraph (c)(11) introductory text, the wording
``Secs. 173.21, 173.51, 173.56(d), or 173.56(e)(1)'' is revised to read
``Secs. 173.21, 173.51, 173.56(d), 173.56(e)(1), 173.124(a)(2)(iii) or
173.128(c)''; and the wording ``hazard class and identification
number,'' is revised to read ``hazard class, identification number, and
packing group,''.
b. In paragraph (c)(12)(iii), the last sentence is removed.
11. In Sec. 172.101, the Hazardous Materials Table is revised to
read as follows:
Sec. 172.101 Purpose and use of hazardous materials table.
* * * * *
BILLING CODE 4910-60-P
Sec. 172.101 Hazardous Materials Table
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
(8) Packaging authorizations (9) Quantity limitations (10) Vessel stowage
(Sec. 173.***) -------------------------- requirements
Hazard Identification Packing Label(s) required (if Special ---------------------------------- ---------------------
Symbols Hazardous materials descriptions and proper shipping names class or Numbers group not excepted) provisions Passenger Cargo Other
Division Exceptions Non-bulk Bulk aircraft or aircraft Vessel stowage
packaging packaging railcar only stowage provisions
(1) (2).......................................................... (3) (4) (5) (6)................... (7)............. (8A) (8B) (8C) (9A)....... (9B)....... (10A).. (10B)
----------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
....... Accellerene, see p-Nitrosodimethylaniline.................... ........... .............. ...................... ................ ........... ........... .......
....... Accumulators, electric, see Batteries, wet etc............... ........... .............. ...................... ................ ........... ........... .......
D...... Accumulators, pressurized, pneumatic or hydraulic (containing 2.2 NA1956 NONFLAMMABLE GAS...... ................ 306 306 None No limit... No limit... A......
non-flammable gas).
....... Acetal....................................................... 3 UN1088 II FLAMMABLE LIQUID...... T7.............. 150 202 242 5 L........ 60 L....... E......
....... Acetaldehyde................................................. 3 UN1089 I FLAMMABLE LIQUID...... A3, B16, T20, None 201 243 Forbidden.. 30 L....... E......
T26, T29.
A...... Acetaldehyde ammonia......................................... 9 UN1841 III CLASS 9............... ................ 155 204 240 200 kg..... 200 kg..... A...... 34
....... Acetaldehyde oxime........................................... 3 UN2332 III FLAMMABLE LIQUID...... B1, T8.......... 150 203 242 60 L....... 220 L...... A......
....... Acetic acid, glacial or Acetic acid solution, with more than 8 UN2789 II CORROSIVE, FLAMMABLE A3, A6, A7, A10 154 202 243 1 L........ 30 L....... A......
80 percent acid, by mass. LIQUID. B2, T8.
....... Acetic acid solution, with more than 10 percent but not more 8 UN2790 II CORROSIVE............. A3, A6, A7, A10 154 202 242 1 L........ 30 L....... A......
than 80 percent acid, by mass. B2, T8.
....... Acetic anhydride............................................. 8 UN1715 II CORROSIVE, FLAMMABLE A3, A6, A7, A10, 154 202 243 1 L........ 30 L....... A...... 40
LIQUID. B2, T8.
....... Acetone...................................................... 3 UN1090 II FLAMMABLE LIQUID...... T8.............. 150 202 242 5 L........ 60 L....... B......
....... Acetone cyanohydrin, stabilized.............................. 6.1 UN1541 I POISON................ 2, A3, B9, B14, None 227 244 Forbidden.. 30 L....... D...... 25, 40, 49
B32, B76, B77,
N34, T38, T43,
T45.
....... Acetone oils................................................. 3 UN1091 II FLAMMABLE LIQUID...... T7, T30......... 150 202 242 5 L........ 60 L....... B......
....... Acetonitrile................................................. 3 UN1648 II FLAMMABLE LIQUID...... T14............. 150 202 242 1 L........ 60 L....... B...... 40
....... Acetyl acetone peroxide with more than 9 percent by mass Forbidden .............. ...................... ................ ........... ........... .......
active oxygen.
....... Acetyl benzoyl peroxide, solid, or with more than 40 percent Forbidden .............. ...................... ................ ........... ........... .......
in solution.
....... Acetyl bromide............................................... 8 UN1716 II CORROSIVE............. B2, T12, T26.... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl chloride.............................................. 3 UN1717 II FLAMMABLE LIQUID, A3, A6, A7, None 202 243 1 L........ 5 L........ B...... 40
CORROSIVE. B100, N34, T18,
T26.
....... Acetyl cyclohexanesulfonyl peroxide, with more than 82 Forbidden .............. ...................... ................ ........... ........... .......
percent wetted with less than 12 percent water.
....... Acetyl iodide................................................ 8 UN1898 II CORROSIVE............. B2, B101, T9.... 154 202 242 1 L........ 30 L....... C...... 40
....... Acetyl methyl carbinol....................................... 3 UN2621 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A......
....... Acetyl peroxide, solid, or with more than 25 percent in Forbidden .............. ...................... ................ ........... ........... .......
solution.
....... Acetylene, dissolved......................................... 2.1 UN1001 FLAMMABLE GAS......... ................ None 303 None Forbidden.. 15 kg...... D...... 25, 40, 57
....... Acetylene (liquefied)........................................ Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene silver nitrate..................................... Forbidden .............. ...................... ................ ........... ........... .......
....... Acetylene tetrabromide, see Tetrabromoethane................. ........... .............. ...................... ................ ........... ........... .......
....... Acid butyl phosphate, see Butyl acid phosphate............... ........... .............. ...................... ................ ........... ........... .......
....... Acid, sludge, see Sludge acid................................ ........... .............. ...................... ................ ........... ........... .......
....... Acridine..................................................... 6.1 UN2713 III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Acrolein dimer, stabilized................................... 3 UN2607 III FLAMMABLE LIQUID...... B1, T1.......... 150 203 242 60 L....... 220 L...... A...... 40
....... Acrolein, inhibited.......................................... 6.1 UN1092 I POISON, FLAMMABLE 1, B9, B12, B14, None 226 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B30, B42, B72,
B77, T38, T43,
T44.
....... Acrylamide................................................... 6.1 UN2074 III KEEP AWAY FROM FOOD... T8.............. 153 213 240 100 kg..... 200 kg..... A...... 12
....... Acrylic acid, inhibited...................................... 8 UN2218 II CORROSIVE, FLAMMABLE B2, T8.......... 154 202 243 1 L........ 30 L....... C...... 25, 40
LIQUID.
....... Acrylonitrile, inhibited..................................... 3 UN1093 I FLAMMABLE LIQUID, B9, T18, T26.... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
....... Actuating cartridge, explosive, see Cartridges, power device. ........... .............. ...................... ................ ........... ........... .......
....... Adhesives, containing a flammable liquid..................... 3 UN1133 II FLAMMABLE LIQUID...... B52, T7, T30.... 150 173 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, B52, T7, T30 150 173 242 60 L....... 220 L...... A......
....... Adiponitrile................................................. 6.1 UN2205 III KEEP AWAY FROM FOOD... T1.............. 153 203 241 60 L....... 220 L...... A......
....... Aerosols, corrosive, Packing Group II or III, (each not 2.2 UN1950 NONFLAMMABLE GAS, A34............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
exceeding 1 L capacity). CORROSIVE.
....... Aerosols, flammable, (each not exceeding 1 L capacity)....... 2.1 UN1950 FLAMMABLE GAS......... N82............. 306 None None 75 kg...... 150 kg..... A...... 40, 48, 85
....... Aerosols, non-flammable, (each not exceeding 1 L capacity)... 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306, 307 None None 75 kg...... 150 kg..... A...... 48, 85
....... Aerosols, poison, each not exceeding 1 L capacity............ 2.2 UN1950 NONFLAMMABLE GAS...... ................ 306 None None Forbidden.. Forbidden.. A...... 40, 48, 85
....... Air bag inflators or Air bag modules or Seat-belt pre- 9 UN3268 III CLASS 9............... ................ 166 166 166 25 kg...... 100 kg..... A......
tensioners or Seat-belt modules.
....... Air, compressed.............................................. 2.2 UN1002 NONFLAMMABLE GAS...... ................ 306 302 302 75 kg...... 150 kg..... A......
....... Air, refrigerated liquid, (cryogenic liquid)................. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. 150 kg..... D...... 51
OXIDIZER.
....... Air, refrigerated liquid, (cryogenic liquid) non-pressurized. 2.2 UN1003 NONFLAMMABLE GAS, ................ 320 316 318, 319 Forbidden.. Forbidden.. D...... 51
OXIDIZER.
....... Aircraft evacuation slides, see Life saving appliances etc... ........... .............. ...................... ................ ........... ........... .......
....... Aircraft hydraulic power unit fuel tank (containing a mixture 3 UN3165 I FLAMMABLE LIQUID, ................ None 172 None Forbidden.. 42 L....... E......
of anhydrous hydrazine and monomethyl hydrazine) (M86 fuel). POISON, CORROSIVE.
....... Aircraft survival kits, see Life saving appliances etc....... ........... .............. ...................... ................ ........... ........... .......
....... Alcoholates solution, n.o.s., in alcohol..................... 3 UN3274 II FLAMMABLE LIQUID, ................ None 202 243 1 L........ 5 L........ B......
CORROSIVE.
....... Alcoholic beverages.......................................... 3 UN3065 II FLAMMABLE LIQUID...... 24, B1, T1...... 150 202 242 5 L........ 60 L....... A......
............................................................. ........... .............. III FLAMMABLE LIQUID...... 24, B1, N11, T1. 150 203 242 60 L....... 220 L...... A......
....... Alcohols, n.o.s.............................................. 3 UN1987 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Alcohols, toxic, n.o.s....................................... 3 UN1986 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... None 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldehydes, n.o.s............................................. 3 UN1989 I FLAMMABLE LIQUID...... T8, T31......... None 201 243 1 L........ 30 L....... E......
............................................................. ........... .............. II FLAMMABLE LIQUID...... T8, T31......... 150 202 242 5 L........ 60 L....... B......
............................................................. ........... .............. III FLAMMABLE LIQUID...... B1, T7, T30..... 150 203 242 60 L....... 220 L...... A......
....... Aldehydes, toxic, n.o.s...................................... 3 UN1988 I FLAMMABLE LIQUID, T8, T31......... None 201 243 Forbidden.. 30 L....... E...... 40
POISON.
............................................................. ........... .............. II FLAMMABLE LIQUID, T8, T31......... None 202 243 1 L........ 60 L....... B...... 40
POISON.
............................................................. ........... .............. III FLAMMABLE LIQUID, KEEP B1, T8, T31..... 150 203 242 60 L....... 220 L...... A......
AWAY FROM FOOD.
....... Aldol........................................................ 6.1 UN2839 II POISON................ T8.............. None 202 243 5 L........ 60 L....... A...... 12
D...... Aldrin, liquid............................................... 6.1 NA2762 II POISON................ ................ None 202 243 5 L........ 60 L....... B......
D...... Aldrin, solid................................................ 6.1 NA2761 II POISON................ ................ None 212 242 25 kg...... 100 kg..... A...... 40
....... Alkali metal alcoholates, self-heating, corrosive, n.o.s..... 4.2 UN3206 II SPONTANEOUSLY ................ None 212 242 15 kg...... 50 kg...... B......
COMBUSTIBLE,
CORROSIVE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 242 25 kg...... 100 kg..... B......
COMBUSTIBLE,
CORROSIVE.
....... Alkali metal alloys, liquid, n.o.s........................... 4.3 UN1421 I DANGEROUS WHEN WET.... A2, A3, B48, N34 None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amalgams........................................ 4.3 UN1389 I DANGEROUS WHEN WET.... A2, A3, N34..... None 201 244 Forbidden.. 1 L........ D......
....... Alkali metal amides.......................................... 4.3 UN1390 II DANGEROUS WHEN WET.... A6, A7, A8, A19, None 212 241 15 kg...... 50 kg...... E...... 40
A20, B101.
....... Alkali metal dispersions, or Alkaline earth metal dispersions 4.3 UN1391 I DANGEROUS WHEN WET.... A2, A3.......... None 201 244 Forbidden.. 1 L........ D......
....... Alkaline corrosive liquids, n.o.s., see Caustic alkali ........... .............. ...................... ................ ........... ........... .......
liquids, n.o.s..
....... Alkaline earth metal alcoholates, n.o.s...................... 4.2 UN3205 II SPONTANEOUSLY ................ None 212 241 15 kg...... 50 kg...... B......
COMBUSTIBLE.
............................................................. ........... .............. III SPONTANEOUSLY ................ None 213 241 15 kg...... 100 kg..... B......
COMBUSTIBLE.
....... Alkaline earth metal alloys, n.o.s........................... 4.3 UN1393 II DANGEROUS WHEN WET.... A19, B100....... None 212 241 15 kg...... 50 kg...... E......
....... Alkaline earth metal amalgams................................ 4.3 UN1392 I DANGEROUS WHEN WET.... A19, N34, N40... None 211 242 Forbidden.. 15 kg...... D......
....... Alkaloids, liquid, n.o.s., or Alkaloid salts, liquid, n.o.s.. 6.1 UN3140 I POISON................ A4, T42......... None 201 243 1 L........ 30 L....... A......
............................................................. ........... .............. II POISON................ T14............. None 202 243 5 L........ 60 L....... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... T7.............. 153 203 241 60 L....... 220 L...... A......
....... Alkaloids, solid, n.o.s. or Alkaloid salts, solid, n.o.s. 6.1 UN1544 I POISON................ ................ None 211 242 5 kg....... 50 kg...... A......
poisonous.
............................................................. ........... .............. II POISON................ ................ None 212 242 25 kg...... 100 kg..... A......
............................................................. ........... .............. III KEEP AWAY FROM FOOD... ................ 153 213 240 100 kg..... 200 kg..... A......
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2584 II CORROSIVE............. B2, T8, T27..... 154 202 242 1 L........ 30 L....... B......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, liquid or Aryl sulfonic acids, liquid 8 UN2586 III CORROSIVE............. T8.............. 154 203 241 5 L........ 60 L....... B......
with not more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid, 8 UN2583 II CORROSIVE............. ................ 154 212 240 15 kg...... 50 kg...... A......
with more than 5 percent free sulfuric acid.
....... Alkyl sulfonic acids, solid or Aryl sulfonic acids, solid 8 UN2585 III CORROSIVE............. ................ 154 213 240 25 kg...... 100 kg..... A......
with not more than 5 percent free sulfuric acid.
....... Alkylphenols, liquid, n.o.s. (including C2-C12 homologues)... 8 UN3145 I CORROSIVE............. T8.............. None 201 243 0.5 L...... 2.5 L...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 202 242 1 L........ 30 L....... B......
............................................................. ........... .............. III CORROSIVE............. T7.............. 154 203 241 5 L........ 60 L....... A......
....... Alkylphenols, solid, n.o.s. (including C2-C12 homologues).... 8 UN2430 I CORROSIVE............. T8.............. None 211 242 1 kg....... 25 kg...... B......
............................................................. ........... .............. II CORROSIVE............. T8.............. 154 212 240 15 kg...... 50 kg...... B......
............................................................. ........... .............. III CORROSIVE............. T8.............. 154 213 240 25 kg...... 100 kg..... A......
....... Alkylsulfuric acids.......................................... 8 UN2571 II CORROSIVE............. B2, T9, T27..... 154 202 242 1 L........ 30 L....... C...... 14
....... Allethrin, see Pesticides, liquid, toxic, n.o.s.............. ........... .............. ...................... ................ ........... ........... .......
....... Allyl acetate................................................ 3 UN2333 II FLAMMABLE LIQUID, T8.............. None 202 243 1 L........ 60 L....... E...... 40
POISON.
....... Allyl alcohol................................................ 6.1 UN1098 I POISON, FLAMMABLE 2, B9, B14, B32, None 227 244 Forbidden.. Forbidden.. D...... 40
LIQUID. B74, B77, T38,
T43, T45.
....... Allyl bromide................................................ 3 UN1099 I FLAMMABLE LIQUID, T18............. None 201 243 Forbidden.. 30 L....... B...... 40
POISON.
....... Allyl chloride............................................... 3 UN1100 I FLAMMABLE LIQUID, T18, T26........ None 201 243 Forbidden.. 30 L.......
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