Protection of Stratospheric Ozone: Listing of Substitutes Under the Significant New Alternatives Policy Program in Commercial and Industrial Refrigeration

Federal RegisterMay 24, 2023

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ENVIRONMENTAL PROTECTION AGENCY

40 CFR Part 82

[EPA-HQ-OAR-2023-0043; FRL-10125-1-OAR]

RIN 2060-AV77

Protection of Stratospheric Ozone: Listing of Substitutes Under the Significant New Alternatives Policy Program in Commercial and Industrial Refrigeration

AGENCY:

Environmental Protection Agency (EPA).

ACTION:

Notice of proposed rulemaking.

SUMMARY:

Pursuant to the U.S. Environmental Protection Agency's Significant New Alternatives Policy program, this action proposes to list certain substances in the refrigeration and air conditioning sector. Specifically, EPA proposes to list several substitutes as acceptable, subject to use conditions, for retail food refrigeration, commercial ice machines, industrial process refrigeration, cold storage warehouses, and ice skating rinks. Through this action, EPA is proposing to incorporate by reference standards which establish requirements for commercial refrigerating appliances and commercial ice machines, safe use of flammable refrigerants, and safe design, construction, installation, and operation of refrigeration systems. This action also proposes to exempt propane, in the refrigerated food processing and dispensing end-use, from the prohibition under the Clean Air Act (CAA) on knowingly venting, releasing, or disposing of substitute refrigerants, on the basis of current evidence that the venting, release, or disposal of this substance in this end-use does not pose a threat to the environment.

DATES:

Comments must be received on or before July 10, 2023. Any party requesting a public hearing must notify the contact listed under

FOR FURTHER INFORMATION CONTACT

by 5 p.m. Eastern Daylight Time on May 30, 2023. If a virtual public hearing is held, it will take place on or before June 8, 2023, and further information will be provided on EPA's Stratospheric Ozone website at

https://www.epa.gov/snap.

ADDRESSES:

You may send comments, identified by Docket ID No. EPA-HQ-OAR-2023-0043, by any of the following methods:

•

Federal eRulemaking Portal: https://www.regulations.gov/

(our preferred method). Follow the online instructions for submitting comments.

•

Mail:

U.S. Environmental Protection Agency, EPA Docket Center, Air and Radiation Docket, Mail Code 28221T, 1200 Pennsylvania Avenue NW, Washington, DC 20460.

•

Hand Delivery or Courier:

EPA Docket Center, WJC West Building, Room 3334, 1301 Constitution Avenue NW, Washington, DC 20004. The Docket Center's hours of operations are 8:30 a.m.-4:30 p.m., Monday-Friday (except Federal Holidays).

Instructions:

All submissions received must include the Docket ID No. for this rulemaking. Comments received may be posted without change to

https://www.regulations.gov/,

including any personal information provided. For additional information on the rulemaking process, see the

SUPPLEMENTARY INFORMATION

section of this document.

All documents in the docket are listed on the

https://www.regulations.gov

website. Although listed in the index, some information is not publicly available,

e.g.,

Confidential Business Information (CBI) or other information whose disclosure is restricted by statute. Certain other material, such as copyrighted material, is not placed on the internet and will be publicly available only in hard copy form. Publicly available docket materials are available electronically through

https://www.regulations.gov

or in hard copy at the Air and Radiation Docket at the address above. For further information on EPA Docket Center services and the current status, please visit

https://www.epa.gov/dockets.

FOR FURTHER INFORMATION CONTACT:

Gerald Wozniak, Stratospheric Protection Division, Office of Atmospheric Protection (Mail Code 6205A), Environmental Protection Agency, 1200 Pennsylvania Ave. NW, Washington, DC 20460; telephone number: 202-343-9624; email address:

wozniak.gerald@epa.gov.

Notices and rulemakings under EPA's Significant New Alternatives Policy (SNAP) program are available on EPA's SNAP website at

https://www.epa.gov/snap/snap-regulations

.

SUPPLEMENTARY INFORMATION:

Table of Contents

I. General Information

A. Executive Summary and Background

B. Does this action apply to me?

C. What acronyms and abbreviations are used in the preamble?

II. What is EPA proposing in this action?

A. Retail Food Refrigeration—Proposed Listing of HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Stand-Alone Units, Remote Condensing Units, Supermarket Systems and Refrigerated Food Processing and Dispensing Equipment and Proposed Listing of R-454A as Acceptable, Subject to Use Conditions, for Use in Remote Condensing Units and Supermarket Systems

1. Background on Retail Food Refrigeration

2. What are the ASHRAE classifications for refrigerant flammability?

3. What are HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

4. Why is EPA proposing these specific use conditions?

5. What additional information is EPA including in these proposed listings?

6. On which topics is EPA specifically requesting comment?

B. Retail Food Refrigeration—Proposed Listing of R-290 as Acceptable, Subject to Use Conditions, for Use in New Refrigerated Food Processing and Dispensing Equipment and Proposed Revision of the Use Conditions in the Previous Listings of R-290 as Acceptable, Subject to Use Conditions, for Use in New Stand-Alone Units

1. Background on Retail Food Refrigeration

2. What are the ASHRAE classifications for refrigerant flammability?

3. What is R-290 and how does it compare to other refrigerants in the refrigerated food processing and dispensing equipment end-use category?

4. Why is EPA proposing these specific use conditions for refrigerated food processing and dispensing equipment?

5. How would the proposed listing for R-290 in refrigerated food processing and dispensing equipment relate to regulations implementing the venting prohibition under CAA section 608?

6. What use conditions currently apply to this refrigerant in the stand-alone units end-use category?

7. What updates to existing use conditions for stand-alone units is EPA proposing?

8. How do the proposed use conditions for stand-alone units differ from the existing ones and why is EPA proposing to change the use conditions?

9. What additional information is EPA including in these proposed listings?

10. On which topics is EPA specifically requesting comment?

C. Commercial Ice Machines—Proposed Listing of HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Commercial Ice Machines

1. Background on Commercial Ice Machines

2. What are the ASHRAE classifications for refrigerant flammability?

3. What are HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

4. Why is EPA proposing these specific use conditions?

5. What additional information is EPA including in these proposed listings?

6. On which topics is EPA specifically requesting comment?

D. Commercial Ice Machines—Proposed Revision of the Use Conditions in the Previous Listing of R-290 as Acceptable, Subject to Use Conditions, for Use in New Self-Contained Commercial Ice Machines

1. Background on Commercial Ice Machines

2. What are the ASHRAE classifications for refrigerant flammability?

3. What is R-290 and where is there information on its use in this end-use?

4. What use conditions currently apply to this refrigerant in this end-use?

5. What updates to existing use conditions for commercial ice machines is EPA proposing?

6. How do the proposed use conditions for commercial ice machines differ from the existing ones and why is EPA proposing to change the use conditions?

7. What additional information is EPA including in this proposed listing?

8. On which topics is EPA specifically requesting comment?

E. Industrial Process Refrigeration—Proposed Listing of HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Industrial Process Refrigeration

1. Background on Idustrial Process Refrigeration

2. What are the ASHRAE classifications for refrigerant flammability?

3. What are HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

4. Why is EPA proposing these specific use conditions?

5. What additional information is EPA including in these proposed listings?

6. On which topics is EPA specifically requesting comment?

F. Cold Storage Warehouses—Proposed Listing of HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Cold Storage Warehouses

1. Background on Cold Storage Warehouses

2. What are the ASHRAE classifications for refrigerant flammability?

3. What are HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

4. Why is EPA proposing these specific use conditions?

5. What additional information is EPA including in these proposed listings?

6. On which topics is EPA specifically requesting comment?

G. Ice Skating Rinks—Proposed Listing of HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Ice Skating Rinks With a Remote Compressor

1. Background on Ice Skating Rinks

2. What are the ASHRAE classifications for refrigerant flammability?

3. What are HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

4. Why is EPA proposing these specific use conditions?

5. What additional information is EPA including in these proposed listings?

6. On which topics is EPA specifically requesting comment?

H. Use Conditions and Further Information for Retail Food Refrigeration, Commercial Ice Machines, Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks With a Remote Compressor

1. What use conditions is EPA proposing and why?

2. What additional information is EPA including in these proposed listings?

3. On which topics is EPA specifically requesting comment?

I. Proposed Exemption for R-290 From the Venting Prohibition Under CAA Section 608 for Refrigerated Food Processing and Dispensing Equipment

1. What is EPA's proposed determination regarding whether venting, releasing, or disposing of R-290 in refrigerated food processing and dispensing equipment would pose a threat to the environment?

2. What is EPA's proposal regarding whether venting of R-290 from refrigerated food processing and dispensing equipment should be exempted from the venting prohibition under CAA section 608(c)(2)?

3. When would the exemption from the venting prohibition apply?

4. What is the relationship between this proposed exemption under CAA section 608(c)(2) and other EPA rules?

5. On which topics is EPA specifically requesting comment?

III. Statutory and Executive Order Reviews

A. Executive Order 12866: Regulatory Planning and Review and Executive Order 13563: Improving Regulation and Regulatory Review

B. Paperwork Reduction Act (PRA)

C. Regulatory Flexibility Act (RFA)

D. Unfunded Mandates Reform Act (UMRA)

E. Executive Order 13132: Federalism

F. Executive Order 13175: Consultation and Coordination With Indian Tribal Governments

G. Executive Order 13045: Protection of Children From Environmental Health and Safety Risks

H. Executive Order 13211: Actions That Significantly Affect Energy Supply, Distribution, or Use

I. National Technology Transfer and Advancement Act and 1 CFR Part 51

J. Executive Order 12898: Federal Actions To Address Environmental Justice in Minority Populations and Low-Income Populations

IV. References

I. General Information

A. Executive Summary and Background

EPA is proposing new and revised listings after its evaluation of human health and environmental information for these substitutes under the Significant New Alternatives Policy (SNAP) program. The Agency is proposing action on these new listings in the refrigeration and air conditioning (AC) sector based on the information that EPA has included in the docket. This proposed action would provide new refrigerant options, thereby increasing flexibility for industry, in specific uses.

This action proposes to list new alternatives for the refrigeration and AC sector. Specifically, EPA is proposing to:

• List hydrofluoroolefin (HFO)-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new retail food refrigeration equipment (

i.e.,

stand-alone units, remote condensing units, supermarket systems, and refrigerated food processing and dispensing equipment);

• List R-454A as acceptable, subject to use conditions, for use in new remote condensing units and supermarket systems;

• List R-290 (propane) as acceptable, subject to use conditions, for use in new refrigerated food processing and dispensing equipment and revise the existing use conditions for R-290 in new stand-alone units.

• List hydrofluorocarbon (HFC)-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new commercial ice machines;

• Revise the existing use conditions for R-290 for use in new self-contained commercial ice machines;

• List HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new chillers for industrial process refrigeration (IPR);

• List HFC-32 and R-454B as acceptable, subject to use conditions, for use in new chillers for IPR;

• List HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new cold storage warehouses; and

• List HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new ice skating rinks using a remote compressor.

In general, the proposed use conditions are consistent across the various substitutes and end-uses contained in this proposal. Because of this similarity, EPA discusses the proposed use conditions that would apply to all five end-uses in section II.H. In summary, the common use conditions proposed are:

(1) These refrigerants may be used only in new equipment, designed specifically and clearly identified for use with the refrigerant. None of these substitutes may be used as a conversion or “retrofit” refrigerant for existing equipment.

(2) These refrigerants may be used only in equipment that meet all requirements listed in the 2nd edition, dated October 27, 2021, of UL

1

Standard 60335-2-89, “Household and Similar Electrical Appliances—Safety—Part 2-89: Requirements for Commercial Refrigerating Appliances and Ice-Makers with an Incorporated or Remote Refrigerant Unit or Motor-Compressor” (hereafter “UL 60335-2-89”). For refrigerants that already have listings that incorporate by reference earlier UL standards, EPA is proposing a transition period when equipment may meet either the earlier UL standard or UL 60335-2-89.

1

UL, formerly known as Underwriters Laboratories.

(3) These refrigerants must be used with warning labels on the equipment and packaging that are similar to or match verbatim those required by UL 60335-2-89.

(4) Equipment must be marked with distinguishing red color-coded hoses and piping to indicate use of a flammable refrigerant and marked service ports, pipes, hoses, and other devices through which the refrigerant is serviced.

(5) These refrigerants must be used with equipment and packaging marked with the Global Harmonized System of Classification and Labelling of Chemicals (GHS) symbol for hazard category 1 flammable gases.

Additional use conditions specific to particular end-uses may also apply and are discussed with each proposed listing. The regulatory text of the proposed listings, including the proposed use conditions and further information, appears in tables at the end of this document. The proposed new listings would appear in appendix Y to 40 Code of Federal Regulations (CFR) part 82, subpart G. The proposed revised listings for R-290 in new retail food refrigeration equipment (stand-alone units only) and in new self-contained commercial ice machines would appear, respectively, in appendices R and V to 40 CFR part 82, subpart G.

There may be other legal obligations pertaining to the manufacture, use, handling, and disposal of the listed substitutes that are not included in the information in the tables (

e.g.,

the CAA section 608(c)(2) venting prohibition or Department of Transportation (DOT) requirements for transport of flammable gases). Flammable refrigerants being recovered or otherwise disposed of from commercial or industrial refrigeration equipment are likely to be hazardous waste under the Resource Conservation and Recovery Act (RCRA) (see 40 CFR parts 260 through 270).

In addition, EPA is proposing to exempt R-290 used in the refrigerated food processing and dispensing end-use from the CAA section 608(c)(2) prohibition on knowingly venting, releasing, or disposing of substitute refrigerants on the basis of current evidence that the venting, release, or disposal of this substance in this end-use does not pose a threat to the environment.

SNAP Program Background

The SNAP program implements CAA section 612. Several major provisions of section 612 are:

1. Rulemaking

Section 612(c) requires EPA to promulgate rules making it unlawful to replace any class I (chlorofluorocarbon (CFC), halon, carbon tetrachloride, methyl chloroform, methyl bromide, hydrobromofluorocarbon, and chlorobromomethane) or class II (hydrochlorofluorocarbon (HCFC)) ozone-depleting substance (ODS) with any substitute that the Administrator determines may present adverse effects to human health or the environment where the Administrator has identified an alternative that (1) reduces the overall risk to human health and the environment and (2) is currently or potentially available.

2. Listing of Unacceptable/Acceptable Substitutes

Section 612(c) requires EPA to publish a list of the substitutes that it finds to be unacceptable for specific uses and to publish a corresponding list of acceptable substitutes for specific uses.

3. Petition Process

Section 612(d) grants the right to any person to petition EPA to add a substance to, or delete a substance from, the lists published in accordance with section 612(c).

4. 90-Day Notification

Section 612(e) directs EPA to require any person who produces a chemical substitute for a class I substance to notify the Agency not less than 90 days before a new or existing chemical is introduced into interstate commerce for significant new use as a substitute for a class I substance. The producer must also provide the Agency with the producer's unpublished health and safety studies on such substitutes.

The regulations for the SNAP program are promulgated at 40 CFR part 82, subpart G, and the Agency's process for reviewing SNAP submissions is described in regulations at 40 CFR 82.180. Under these rules, the Agency has identified five types of listing decisions: acceptable; acceptable subject to use conditions; acceptable subject to narrowed use limits; unacceptable; and pending (40 CFR 82.180(b)). Use conditions and narrowed use limits are both considered “use restrictions.” Substitutes that are deemed acceptable with no use restrictions (no use conditions or narrowed use limits) can be used for all applications within the relevant end-uses in the sector. After reviewing a substitute, the Agency may determine that a substitute is acceptable only if certain conditions in the way that the substitute is used are met to minimize risks to human health and the environment. EPA describes such substitutes as “acceptable subject to use conditions” (40 CFR 82.180(b)(2)). For some substitutes, the Agency may permit a narrowed range of use within an end-use or sector. For example, the Agency may limit the use of a substitute to certain end-uses or specific applications within an industry sector. EPA describes these substitutes as “acceptable subject to narrowed use limits.” Under the narrowed use limit, users intending to adopt these substitutes “must ascertain that other alternatives are not technically feasible.” (40 CFR 82.180(b)(3)).

In making decisions regarding whether a substitute is acceptable or unacceptable, and whether substitutes present risks that are lower than or comparable to risks from other substitutes that are currently or potentially available in the end-uses under consideration, EPA examines the following criteria in 40 CFR 82.180(a)(7): (i) atmospheric effects and related health and environmental impacts; (ii) general population risks from ambient exposure to compounds with direct toxicity and to increased ground-level ozone; (iii) ecosystem risks; (iv) occupational risks; (v) consumer risks; (vi) flammability; and (vii) cost and availability of the substitute.

Many SNAP listings include “comments” or “further information” to provide additional information on substitutes. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute

under the SNAP program. However, regulatory requirements so listed are binding under other regulatory programs (

e.g.,

worker protection regulations promulgated by the U.S. Occupational Safety and Health Administration (OSHA)). The “further information” classification does not necessarily include all other legal obligations pertaining to the use of the substitute. While the items listed are not legally binding under the SNAP program, EPA encourages users of substitutes to apply all statements in the “Further Information” column in their use of these substitutes. In many instances, the information simply refers to sound operating practices that have already been identified in existing industry and/or building codes or standards. Thus, many of the statements, if adopted, would not require the affected user to make significant changes in existing operating practices.

For additional information on the SNAP program, visit the SNAP website at

https://www.epa.gov/snap.

The full lists of acceptable substitutes for ODS in all industrial sectors are available at

https://www.epa.gov/snap/snap-substitutes-sector.

For more information on the Agency's process for administering the SNAP program or criteria for evaluation of substitutes, refer to the initial SNAP rulemaking published March 18, 1994 (59 FR13044), codified at 40 CFR part 82, subpart G. SNAP decisions and the appropriate

Federal Register

citations can be found at

https://www.epa.gov/snap/snap-regulations.

Substitutes listed as unacceptable; acceptable, subject to narrowed use limits; or acceptable, subject to use conditions, are also listed in the appendices to 40 CFR part 82, subpart G.

Background on requirements concerning venting, release, or disposal of refrigerants and refrigerant substitutes under CAA section 608

The statutory requirements concerning venting, release, or disposal of ODS refrigerants and substitutes for ODS used as refrigerants are under CAA section 608, and EPA's authority to promulgate the regulatory revisions in this action is based in part on CAA section 608. Section 608 of the Act, as amended, titled

National Recycling and Emission Reduction Program,

requires, among other things, that EPA establish regulations governing the use and disposal of ODS used as refrigerants, such as certain CFCs and HCFCs, during the service, repair, or disposal of appliances and IPR.

2

Section 608(c)(1) provides that it is unlawful for any person in the course of maintaining, servicing, repairing, or disposing of an appliance (or IPR) to knowingly vent, or otherwise knowingly release or dispose of, any class I or class II substance used as a refrigerant in that appliance (or IPR) in a manner which permits the ODS to enter the environment.

2

Additional information about the 608 Refrigerant Management Program is available in EPA's rules implementing that program, such as rules published on May 14, 1993 (58 FR 28660), November 18, 2016 (81 FR 82272), and March 11, 2020 (85 FR 14150).

Section 608(c)(2) extends the prohibition in section 608(c)(1) to knowingly venting or otherwise knowingly releasing or disposing of any refrigerant substitute for class I or class II substances by any person maintaining, servicing, repairing, or disposing of appliances or IPR. This prohibition applies to any substitute refrigerant unless the Administrator determines that such venting, releasing, or disposing does not pose a threat to the environment. Thus, section 608(c) provides EPA authority to promulgate regulations to interpret, implement, and enforce this prohibition on venting, releasing, or disposing of class I or class II substances and their refrigerant substitutes, which we also refer to as the “venting prohibition” in this proposed action. EPA's authority under section 608(c) includes authority to implement section 608(c)(2) by exempting certain substitutes for class I or class II substances from the venting prohibition when the Administrator determines that such venting, release, or disposal does not pose a threat to the environment.

EPA issued a rule on March 12, 2004 (69 FR 11946), and a second rule on April 13, 2005 (70 FR 19273), clarifying how the venting prohibition in section 608(c) applies to substitutes for CFC and HCFC refrigerants (

e.g.,

HFCs and perfluorocarbons (PFCs)). These regulations are codified at 40 CFR part 82, subpart F. In relevant part, they provide that no person maintaining, servicing, repairing, or disposing of appliances may knowingly vent or otherwise release into the environment any refrigerant or substitute from such appliances, with the exception of certain specified substitutes in the specified end-uses, as provided in 40 CFR 82.154(a).

EPA has exempted from the venting prohibition several hydrocarbon (HC) refrigerant substitutes, including R-290, in specific end-uses where the Agency had also listed the substitutes as acceptable, subject to use conditions, under the SNAP program. See, for example, EPA's regulations issued May 23, 2014 (79 FR 29682), April 10, 2015 (80 FR 19453), and December 1, 2016 (81 FR 86778).

3

Those regulatory exemptions do not apply to blends of HCs with other refrigerants or containing any amount of any CFC, HCFC, HFC, or PFC. The current exemptions for R-290 by end-use are codified at 40 CFR 82.154(a)(1)(viii).

3

The United States Court of Appeals for the District of Columbia Circuit (“the court”) issued a partial vacatur of the December 1, 2016 rule “`to the extent' it required manufacturers to replace already lawfully installed HFC substitutes.”

See Mexichem Fluor, Inc.

v.

EPA,

Judgment, Case No. 17-1024 (D.C. Cir., April 5, 2019), 760 Fed. Appx. 6 (Mem). The court's decision on the December 1, 2016 rule did not affect the portion of that rule that exempted certain HC refrigerant substitutes from the venting prohibition. This proposed rule is not EPA's response to the court's decision.

In establishing those exemptions, EPA determined that for the purposes of CAA section 608(c)(2), the venting, release, or disposal of such HC refrigerant substitutes in the specified end-uses does not pose a threat to the environment, considering both the inherent characteristics of these substances and the limited quantities used in the relevant applications., see,

e.g.,

December 1, 2016 (81 FR 86778). EPA further concluded that other authorities, controls, or practices that apply to such refrigerant substitutes help to mitigate environmental risk from the release of those saturated HC refrigerant substitutes.

B. Does this action apply to me?

The following list identifies regulated entities that may be affected by this rule and their respective North American Industrial Classification System (NAICS) codes:

• Plumbing, Heating, and Air Conditioning Contractors (NAICS 238220)

• All Other Basic Organic Chemical Manufacturing (NAICS 325199)

• Air Conditioning and Warm Air Heating Equipment and Commercial and Industrial Refrigeration Equipment Manufacturing (NAICS 333415)

• Refrigeration Equipment and Supplies Merchant Wholesalers (NAICS 423740)

• Recyclable Material Merchant Wholesalers (NAICS 423930)

• Supermarkets and Other Grocery (except Convenience) Stores (NAICS 445110)

• Convenience Stores (NAICS 445120)

• Limited-Service Restaurants (NAICS 722211)

• Appliance Repair and Maintenance (NAICS 811412)

This list is not intended to be exhaustive, but rather to provide a guide for readers regarding entities likely to be affected by this action. To determine whether your facility, company, business, or organization could be affected by this action, you should carefully examine the regulations at 40 CFR part 82, subpart G, and the proposed revisions. If you have questions regarding the applicability of this action to a particular entity, consult the person listed in the

FOR FURTHER INFORMATION CONTACT

section.

C. What acronyms and abbreviations are used in the preamble?

Below is a list of acronyms and abbreviations used in the preamble of this document:

AC—Air Conditioning

AEL—Acceptable Exposure Limit

AIHA—American Industrial Hygiene Association

ANSI—American National Standards Institute

ASHRAE—American Society of Heating, Refrigerating and Air-Conditioning Engineers

ASTM—American Society for Testing and Materials

ATEL—Acute Toxicity Exposure Limit

CAA—Clean Air Act

CAS Reg. No.—Chemical Abstracts Service Registry Identification Number

CBI—Confidential Business Information

CFC—Chlorofluorocarbon

CFR—Code of Federal Regulations

CO

2

—Carbon Dioxide

DOE—United States Department of Energy

DOT—United States Department of Transportation

DX—Direct Heat Exchange

EPA—United States Environmental Protection Agency

FR—Federal Register

GHS—Global Harmonized System of Classification and Labelling of Chemicals

GWP—Global Warming Potential

HC—Hydrocarbon

HCFC—Hydrochlorofluorocarbon

HCFO—Hydrochlorofluoroolefin

HFC—Hydrofluorocarbon

HFO—Hydrofluoroolefin

HP—Heat Pump

IBC—International Building Code

ICC—International Code Council

ICF—ICF International, Inc.

IEC—International Electrotechnical Commission

IPCC—Intergovernmental Panel on Climate Change

IPR—Industrial Process Refrigeration

ISO—International Organisation for Standardisation

LFL—Lower Flammability Limit

MIR—Maximum Incremental Reactivity

NAAQS—National Ambient Air Quality Standards

NAICS—North American Industrial Classification System

NARA—National Archives and Records Administration

ODP—Ozone Depletion Potential

ODS—Ozone Depleting Substances

OMB—United States Office of Management and Budget

OSHA—United States Occupational Safety and Health Administration

PEL—Permissible Exposure Limit

PFC—Perfluorocarbons

PMS—Pantone® Matching System

ppm—Parts Per Million

PRA—Paperwork Reduction Act

RCRA—Resource Conservation and Recovery Act

RFA—Regulatory Flexibility Act

SDS—Safety Data Sheet

SIP—State Implementation Plan

TLV—Threshold Limit Value

TSCA—Toxic Substances Control Act

TWA—Time Weighted Average

UL—UL, formerly known as Underwriters Laboratories, Inc.

UMRA—Unfunded Mandates Reform Act

VOC—Volatile Organic Compound, Volatile Organic Compounds

WEEL—Workplace Environmental Exposure Limit

WMO—World Meteorological Organization

II. What is EPA proposing in this action?

A. Retail Food Refrigeration—Proposed Listing of HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Stand-Alone Units, Remote Condensing Units, Supermarket Systems, and Refrigerated Food Processing and Dispensing Equipment and Proposed Listing of R-454A as Acceptable, Subject to Use Conditions, for Use in New Remote Condensing Units and Supermarkets Systems

EPA is proposing to list HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in all end-use categories under retail food refrigeration (

i.e.,

stand-alone units, remote condensing units, supermarket systems, and refrigerated food processing and dispensing equipment). EPA is also proposing to list R-454A as acceptable, subject to use conditions, for use in two end-use categories under retail food refrigeration (remote condensing units and supermarket systems).

EPA is proposing several use conditions for these end-use categories that are identical to those proposed for other end-uses (commercial ice machines, IPR, cold storage warehouses, and ice skating rinks with a remote compressor) discussed elsewhere in this proposal. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in Section II.H. In summary, the common use conditions EPA is proposing include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

For use of these substitutes in retail food refrigeration equipment, EPA is also proposing a use condition related to adherence to the American National Standards Institute (ANSI)/American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) Standard 15-2022 “Safety Standard for Refrigeration Systems” (hereafter “ASHRAE 15-2022”). Specifically, we are proposing that these refrigerants may only be used in commercial refrigeration equipment that meets all requirements listed in ASHRAE 15-2022. In cases where the final rule includes requirements that are different than those of ASHRAE 15-2022, EPA is proposing that the appliance would need to meet the requirements of this rule in place of the requirements in ASHRAE 15-2022. This additional use condition is discussed further in section II.A.4.

EPA is also proposing the following use condition for R-454A in supermarkets and remote condensing units: this substitute may only be used either in equipment with a refrigerant charge capacity less than 200 pounds or in the high-temperature side of a cascade system.

1. Background on Retail Food Refrigeration

Retail food refrigeration, an end-use within the SNAP program, encompasses the equipment used for storing and displaying (generally for sale) food and beverages at different temperatures necessary for the different products (

e.g.,

chilled and frozen food). The designs and refrigerating capacities of equipment vary widely to ensure the proper temperatures are achieved and maintained.

Retail food refrigeration is composed of four categories of equipment: stand-alone units; refrigerated food processing and dispensing equipment; remote condensing units; and supermarket systems. EPA treats each of these four end-use categories as a separate end-use for purposes of our comparisons of the overall impact on human health and the environment and of the availability of refrigerants.

Stand-alone units are refrigerators, freezers, and reach-in coolers (either

open or with doors) where all refrigeration components are integrated and, for the smallest types, the refrigeration circuit is entirely brazed or welded. These systems are charged with refrigerant at the factory and typically require only an electricity supply to begin operation. Such systems are used to chill and temporarily store perishable items for commercial sale, such as beverages and food.

Refrigerated food processing and dispensing equipment dispenses and often processes a variety of food and beverage products. For instance, some such equipment will process the product by combining ingredients, mixing, and preparing it at the proper temperature, while others function mainly as a holding tank to deliver the product at the desired temperature or to deliver chilled ingredients for processing, mixing, and preparation. Some may use a refrigerant in a heat pump, or utilize waste heat from the cooling system, to provide hot beverages. Some may also provide heating functions for melting or dislodging ice or for sanitation purposes.

Refrigerated food processing and dispensing equipment can be self-contained or can be connected via piping to a dedicated condensing unit located elsewhere. Equipment within this end-use category include but are not limited to refrigerated equipment used to process and dispense beverages and food such as: chilled and frozen beverages (carbonated and uncarbonated, alcoholic and nonalcoholic); frozen custards, gelato, ice cream, Italian ice, sorbets, and yogurts; milkshakes, “slushies” and smoothies, and whipped cream.

Remote condensing units exhibit refrigerating capacities ranging typically from 1kW to 20kW (0.3 to 5.7 refrigeration tons). They are composed of one (and sometimes two) compressor(s), one condenser, and one receiver assembled into a single unit, which is normally located external to the sales area. This equipment is connected to one or more nearby evaporator(s) used to cool food and beverages stored in display cases and/or walk-in storage rooms. Remote condensing units are commonly installed in convenience stores and specialty shops such as bakeries and butcher shops.

Typical supermarket systems are also known as multiplex or centralized systems. They operate with racks of compressors installed in a machinery room; different compressors turn on to match the refrigeration load necessary to maintain temperatures. Two main design classifications are used: direct and indirect systems. In the United States, direct systems are the most widespread. The plurality of supermarkets in the United States use centralized direct expansion (DX) systems to cool their display cases.

4

The refrigerant circulates from the machinery room to the sales area, where it evaporates in display-case heat exchangers, and then returns in vapor phase to the suction headers of the compressor racks. The supermarket walk-in cold rooms are often integrated into the system and cooled similarly, but an alternative option is to provide a dedicated condensing unit for a given storage room. Another type of supermarket design, often referred to as a distributed refrigeration system, uses an array of separate compressor racks located near the display cases rather than having a central compressor rack system. Each of these smaller racks handles a portion of the supermarket load, with five to ten such systems in a store.

4

www.epa.gov/greenchill/advanced-refrigeration.

Indirect supermarket system designs include secondary loop systems and cascade refrigeration. Indirect systems use a chiller or other refrigeration system to cool a secondary fluid that is often circulated throughout the store to the cases. Examples of secondary fluids include water, air, HCs, ammonia, and carbon dioxide (CO

2

). Compact chiller versions of an indirect system rely on a lineup of ten to 20 units, each using small charge sizes. As the refrigeration load changes, more or fewer of the chillers are active. Compact chillers are used in a secondary loop system whereby the chillers cool a secondary fluid that is then circulated throughout the store to the display cases. Each compact chiller is an independent unit with its own refrigerant charge, reducing the potential for refrigerant to be released from leaks or for a catastrophic failure. Cascade systems use a compressor to raise the low-temperature, secondary fluid from low-temperature conditions up to an intermediate temperature while a separate, primary refrigerant system uses a different, higher temperature refrigerant to condense the secondary fluid. Each system within the cascade design contains its own refrigerant charge, allowing the use of different refrigerants in each system. This application has generally used a lower global warming potential (GWP) refrigerant, specifically CO

2

(R-744), in the low-temperature system, with a variety of refrigerants in the high temperature system.

Refrigerant choice depends on the refrigerant charge, ambient temperatures and the temperature required, system performance, energy efficiency, and health, safety and environmental considerations, among other things. In addition to regulations pursuant to the SNAP program, other federal or local regulations may also affect refrigerant choice. For instance, regulations from OSHA may restrict or place requirements on the use of some refrigerants, such as ammonia (R-717). Building codes from local and state agencies may also incorporate limits on the types and amounts of particular refrigerants used. There are and will continue to be multiple factors that retailers must consider when selecting the refrigerant and operating system design, including: energy efficiency; system performance; potential impact on community safety; ambient temperatures; risk to personnel safety; cost; and minimization of direct and indirect environmental impacts.

2. What are the ASHRAE classifications for refrigerant flammability?

The ANSI/ASHRAE Standard 34-2022 “Designation and Safety Classification of Refrigerants” (hereafter “ASHRAE 34-2022”) assigns a safety group classification for each refrigerant which consists of two to three alphanumeric characters (

e.g.,

A2L or B1). The initial capital letter indicates the toxicity, and the numeral denotes the flammability. ASHRAE classifies Class A refrigerants as refrigerants for which toxicity has not been identified at concentrations less than or equal to 400 parts per million (ppm) by volume, based on data used to determine threshold limit value-time-weighted average (TLV-TWA) or consistent indices. Class B signifies refrigerants for which there is evidence of toxicity at concentrations below 400 ppm by volume, based on data used to determine TLV-TWA or consistent indices.

The refrigerants are also assigned a flammability classification of 1, 2, 2L, or 3. Tests for flammability are conducted in accordance with American Society for Testing and Materials (ASTM) E681 using a spark ignition source at 140 °F (60 °C) and 14.7 psia (101.3 kPa).

5

The flammability classification “1” is given to refrigerants that, when tested, show no flame propagation. The flammability classification “2” is given to refrigerants that, when tested, exhibit flame propagation, have a heat of combustion

less than 19,000 kJ/kg (8,169 Btu/lb), and have a lower flammability limit (LFL) greater than 0.10 kg/m

3

. The flammability classification “2L” is given to refrigerants that, when tested, exhibit flame propagation, have a heat of combustion less than 19,000 kJ/kg (8,169 Btu/lb), have an LFL greater than 0.10 kg/m

3

, and have a maximum burning velocity of 10 cm/s or lower when tested in dry air at 73.4 °F (23.0 °C) and 14.7 psi (101.3 kPa). The flammability classification “3” is given to refrigerants that, when tested, exhibit flame propagation and that either have a heat of combustion of 19,000 kJ/kg (8,169 Btu/lb) or greater or have an LFL of 0.10 kg/m

3

or lower.

5

ASHRAE, 2022b. ANSI/ASHRAE Standard 34-2022: Designation and Safety Classification of Refrigerants.

For flammability classifications, refrigerant blends are designated based on the worst case of formulation for flammability and the worst case of fractionation for flammability determined for the blend.

EP24MY23.000

Using these safety group classifications, ASHRAE 34-2022 categorizes HFO-1234yf, HFO-1234ze(E), HFC-32 and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A, which are discussed in this section of this proposed rule, as being in the A2L Safety Group, while R-290 is in the A3 Safety Group.

3. What are HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

HFO-1234yf and HFO-1234ze(E) are lower flammability refrigerants, and R-454A, R-454C, R-455A, R-457A, and R-516A are lower flammability refrigerant blends, all with an ASHRAE safety classification of A2L.

6

The respective Chemical Abstracts Service Registry Identification Numbers (CAS Reg. Nos.) of HFO-1234yf, HFO-1234ze(E), and the components of the refrigerant blends are listed here.

6

EPA previously listed HFO-1234yf as acceptable, subject to use conditions, in motor vehicle AC in light-duty vehicles (74 FR 53445, October 19, 2009), in heavy-duty pickup trucks and complete heavy-duty vans (81 FR 86778, December 1, 2016) and in nonroad vehicles and service fittings for small refrigerant cans (87 FR 26276, May 4, 2022). EPA previously listed R-454A, R-454C, and R-457A as acceptable, subject to use conditions, as a substitute in residential and light commercial AC and heat pumps (HPs) (86 FR 24444, May 6, 2021).

HFO-1234yf, also known by the trade names “Solstice® yf” and “Opteon

TM

YF,” is also known as 2,3,3,3-tetrafluoroprop-1-ene (CAS Reg. No. 754-12-1). HFO-1234ze(E), also known by the trade names “Solstice® ze and Solstice® 1234ze”, is also known as

trans

-1,3,3,3,tetrafluoroprop-1-ene (CAS Reg. No. 29118-24-9). R-516A, also known by the trade name “Forane® 516A,” is a blend consisting of 77.5 percent HFO-1234yf, 14 percent HFC-152a, and 8.5 percent HFC-134a. R-457A, also known by the trade name “Forane® 457A,” is a blend consisting of 18 percent HFC-32, 12 percent HFC-152a, and 70 percent HFO-1234yf. R-455A, also known by the trade name “Solstice® L40X,” is a blend consisting of 21.5 percent HFC-32, 75.5 percent HFO-1234yf, and three percent R-744 (CO

2

). R-454A, also known by the trade name “Opteon

TM

XL 40,” is a blend consisting of 35 percent HFC-32 and 65 percent HFO-1234yf. R-454C, also known by the trade name “Opteon

TM

XL 20,” is a blend consisting of 21.5 percent HFC-32 and 78.5 percent HFO-1234yf.

Redacted submissions and supporting documentation for HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A are provided in the docket for this proposed rule (EPA-HQ-OAR-2023-0043) at

https://www.regulations.gov.

EPA performed a risk screening assessment to examine the health and environmental risks of each of these substitutes. These risk screens are available in the docket for this proposed rule.

7 8 9 10 11 12 13

7

ICF, 2023a. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: HFO-1234yf.

8

ICF, 2023b. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: HFO-1234ze(E) (Solstice® ze, Solstice® 1234ze)

9

ICF, 2023c. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: R-454A (Opteon® XL40).

10

ICF, 2023d. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: R-454C (Opteon

TM

XL20).

11

ICF, 2023e. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: R-455A (Solstice® L40X).

12

ICF, 2023f. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: R-457A (Forane® 457A).

13

ICF, 2023g. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: R-516A (Forane® 516A).

Environmental information:

HFO-1234yf, HFO-1234ze(E) and R-454A, R-454C, R-455A, R-457A, and R-516A have ozone depletion potentials (ODPs) of zero.

HFO-1234yf has a GWP of less than four.

14 15 16

HFO-1234ze(E) has a GWP of less than six.

17 18

The refrigerant blends are made up of the components HFC-32, HFC-125, HFC-152a, CO

2

, and HFO-1234yf, which have GWPs of 675, 3,500, 124, one, and less than four, respectively.

19

If these values are weighted by mass percentage, then R-454A, R-454C, R-455A, R-457A, and R-516A have GWPs of about 240, 150, 146, 140, and 142, respectively.

14

World Meteorological Organization (2018). Burkholder

et al.

Appendix A, Table A-1 in

Scientific Assessment of Ozone Depletion: 2018, Global Ozone Research and Monitoring Project,

Report No. 58, World Meteorological Organization, Geneva, Switzerland,

https://ozone.unep.org/science/assessment/sap.

(WMO, 2018)

15

Nielsen et al., 2007. Nielsen, O.J., Javadi, M.S., Sulbaek Andersen, M.P., Hurley, M.D., Wallington, T.J., Singh, R. 2007. Atmospheric chemistry of CF3CF=CH2: Kinetics and mechanisms of gas-phase reactions with Cl atoms, OH radicals, and O3. Chemical Physics Letters 439, 18-22. Available online at:

www.cogci.dk/network/OJN_174_CF3CF=CH2.pdf.

16

Hodnebrog Ø. et al., 2013. Hodnebrog Ø., Etminan, M., Fuglestvedt, J.S., Marston, G., Myhre, G., Nielsen, C.J., Shine, K.P., Wallington, T.J.: Global Warming Potentials and Radiative Efficiencies of Halocarbons and Related Compounds: A Comprehensive Review,

Reviews of Geophysics, 51, 300-378, doi:10.1002/rog.20013,

2013.

17

Javadi et al., 2008. Atmospheric chemistry of trans-CF

3

CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation,' M.S. Javadi, R. Søndergaard, O.J. Nielsen, M.D. Hurley, and T.J. Wellington,

Atmospheric Chemistry and Physics Discussions 8, 1069-1088,

2008.

18

Ibid.

19

Unless otherwise specified, GWP values are 100-year values from Intergovernmental Panel on Climate Change (IPCC) (2007) Climate Change 2007: The Physical Science Basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. S. Solomon, D. Qin, M. Manning, Z. Chen, M. Marquis, K.B. Averyt, M. Tignor and H.L. Miller (eds.). Cambridge University Press. Cambridge, United Kingdom 996 pp.

HFO-1234yf, HFO-1234ze(E), and the other components of the refrigerant blends, CO

2

, HFC-32, HFC-125, and HFC-152a, are excluded from EPA's regulatory definition of volatile organic compounds (VOC) (see 40 CFR 51.100(s)) addressing the development of State Implementation Plans (SIPs) to attain and maintain the National Ambient Air Quality Standards (NAAQS). That definition provides that “any compound of carbon” which “participates in atmospheric photochemical reactions” is considered a VOC unless expressly excluded in that provision based on a determination of “negligible photochemical reactivity.”

Under section 608(c)(2) of the CAA and EPA's regulations at 40 CFR 82.154(a)(1), it is unlawful for any person, in the course of maintaining, servicing, repairing, or disposing of an appliance or industrial process refrigeration, to knowingly vent or otherwise knowingly release or dispose of any substitute substance for a class I or class II substance used as a refrigerant in such appliance (or industrial process refrigeration) in a manner which permits such substance to enter the environment. EPA has established certain limited exemptions to this venting prohibition, as listed in 40 CFR 82.154(a)(1), but none of those exemptions apply to HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, or R-516A.

Flammability information:

HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A have lower flammability, with an ASHRAE flammability classification of 2L.

Toxicity and exposure data:

HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A have an ASHRAE toxicity classification of A (lower toxicity). Potential health effects of exposure to these substitutes include drowsiness or dizziness. The substitutes may also irritate the skin or eyes or cause frostbite. At sufficiently high concentrations, the substitutes may cause irregular heartbeat. The substitutes could cause asphyxiation if air is displaced by vapors in a confined space. These potential health effects are common to many refrigerants.

OSHA has established a Permissible Exposure Limit (PEL) for CO

2

of 5,000 ppm as an 8-hr TWA. The American Industrial Hygiene Association (AIHA) has established Workplace Environmental Exposure Limits (WEELs) of 1,000 ppm as an 8-hr TWA for HFC-32, HFC-125, and HFC-152a; 500 ppm as an 8-hr TWA for HFO-1234yf; and 800 ppm as an 8-hr TWA for HFO-1234ze(E). The manufacturers of R-454A, R-454C, R-455A, R-457A, and R-516A recommend acceptable exposure limits (AELs) for the workplace, respectively, of 690, 615, 650, 650, and 590 ppm on an 8-hr TWA for these blends.

20

EPA anticipates that users will be able to meet the OSHA PEL, AIHA WEELs, and manufacturers' AELs and address potential health risks by following requirements and recommendations in the manufacturers' safety data sheets (SDSs), the use conditions proposed (including adherence to Underwriters Laboratories (UL) 60335-2-89 and ASHRAE 15-2022), and other safety precautions common to the refrigeration and AC industry.

20

The 8-hr TWA AEL recommendations of these refrigerant blends are based upon a mass-weighting of the PEL and WEELs of their components.

Comparison to other substitutes in these end-uses:

HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A all have an ODP of zero, comparable to or lower than some of the acceptable substitutes in these end-uses, such as CO

2,

with an ODP of zero.

For new refrigerated food processing and dispensing equipment, R-454A, R-454C, R-455A, R-457A, and R-516A have GWPs ranging from 140 to 240, higher than to that of CO

2

, an acceptable substitute in this end-use category, with a GWP of 1, while HFO-1234yf and HFO-1234ze(E) have comparable GWPs to CO

2

of less than four and less than six, respectively. The GWPs of HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A are lower than those of other acceptable substitutes for new refrigerated food processing and dispensing equipment, such as R-450A, R-513A, and HFC-134a, with GWPs of approximately 600, 630, and 1,430, respectively.

For new remote condensing units and supermarket systems, R-454A, R-454C, R-455A, R-457A, and R-516A have GWPs ranging from 140 to 240, higher than that of ammonia and CO

2

, acceptable substitutes in these end-use categories, with GWPs of zero and one, respectively, while HFO-1234yf and HFO-1234ze(E) have comparable GWPs to CO

2

of less than four and less than six, respectively. The GWPs of HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A are lower than those of some of the acceptable substitutes for new remote condensing units and new supermarket systems, such as R-450A, R-513A, HFC-134a, R-407A, and R-404A, with GWPs of approximately 600, 630, 1,430, 2,110, and 2,630, respectively.

For new stand-alone units, R-454A, R-454C, R-455A, R-457A, and R-516A have GWPs ranging from 140 to 240, higher than some of the acceptable substitutes in this end-use category such as CO

2

, R-290, and R-441A with GWPs of one, three, and less than five, while HFO-1234yf and HFO-1234ze(E) have comparable GWPs to GWPs of CO

2

, R-290, and R-441A of less than four and less than six, respectively. The GWPs of HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A are lower than some of the acceptable substitutes for new stand-alone units, such as R-450A and R-513A, with GWPs of 601 and 630, respectively.

Information regarding the toxicity of other available alternatives is provided in the listing decisions previously made (see

https://www.epa.gov/snap/retail-

food-refrigeration

). Toxicity risks of use, determined by the likelihood of exceeding the exposure limit, of HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A in these end-uses are evaluated in the risk screens referenced above. The toxicity risks of using HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A in retail food refrigeration equipment are comparable to or lower than toxicity risks of other available substitutes in the same end-uses. Toxicity risks of the proposed refrigerants can be minimized by use consistent with UL 60335-2-89—which would be required by our proposed use conditions—and other industry standards, such as ASHRAE 15-2022—which applies under the use conditions—as well as recommendations in the manufacturers' SDS and other safety precautions common in the refrigeration and AC industry.

The flammability risks with HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A in these end-uses, determined by the likelihood of exceeding their respective lower flammability limits, are evaluated in the risk screens referenced above. In conclusion, while these refrigerants may pose greater flammability risk than other available substitutes in the same end-uses, this risk can be minimized by use consistent with ASHRAE 15-2022, which would be required for equipment with certain charge sizes by our proposed use conditions, and other industry standards such as UL 60335-2-89, which would also be required by our proposed use conditions, as well as recommendations in the manufacturers' SDS and other safety precautions common in the refrigeration and AC industry. EPA is proposing use conditions that maintain the low potential risk associated with the flammability of these alternatives so that they will not pose significantly greater risk than other acceptable substitutes in this end-use category.

In addition, the proposed substitutes have lower GWPs than most other available alternatives for the same uses. The proposed refrigerants provide additional lower-GWP options for situations where other refrigerants with lower GWPs are not viable, such as for use of HCs in systems with remote compressors or equipment requiring larger charge sizes, or where equipment using CO

2

may not be able to meet energy conservation standards from the U.S. Department of Energy (DOE). Given the wide range of applications for retail food refrigeration, not all refrigerants listed as acceptable under SNAP will be suitable for the range of equipment in the retail food refrigeration end-use or in the four end-use categories within retail food refrigeration. To provide additional options to ensure the availability of substitutes for the full range of retail food refrigeration equipment with lower GWP and, therefore, lower overall risk to human health and the environment, EPA is proposing the listings for HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in all types of retail food refrigeration equipment. In addition, to account for the additional challenges for finding lower GWP refrigerants with higher capacity for remote condensing units and supermarket systems with moderate charge sizes and for cascade systems, EPA is proposing to list R-454A as acceptable, subject to use conditions, for use in remote condensing units and supermarket systems with a charge size capacity less than 200 pounds or for use in the high-temperature side of a cascade system.

4. Why is EPA proposing these specific use conditions?

This proposal applies to end-uses covered by UL 60335-2-89. This standard applies to commercial and industrial refrigeration equipment, including the SNAP end-uses of retail food refrigeration, commercial ice machines, IPR, cold storage warehouses, and ice skating rinks. In addition, ASHRAE 15-2022 applies to these refrigeration systems.

The standard UL 60335-2-89 discussed in section II.H indicates that refrigerant charges greater than a specific amount (called “m

3

” in the standard and based on the refrigerant's LFL) are beyond its scope and that national standards might apply, such as ASHRAE 15-2022. Hence, EPA is proposing to require adherence to both standards as use conditions for remote condensing units and supermarket systems, broadening the coverage under this proposed rule.

EPA is proposing to incorporate by reference ASHRAE 15-2022, including all addenda published by the date of this proposal, in use conditions that apply to use of the proposed A2L refrigerants in new remote condensing units and supermarket systems. Where the requirements specified in this proposed rule (if finalized) and ASHRAE 15-2022 differ, the requirements of this rule would apply.

A partial summary of ASHRAE 15-2022 is provided here for information only. This is not meant to be a full explanation of the standard or how it is applied. ASHRAE 15-2022 specifies requirements for refrigeration systems, based on the safety group classification of the refrigerant used, the type of occupancy in the location for which the system is used, and whether refrigerant-containing parts of the system enter the space or ductwork and so leakage in the space is deemed “probable.” “High-probability” installations are those such that leaks or failures will result in refrigerant entering occupied space. As previously explained, HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A are all classified as A2L refrigerants. Occupancies are divided into six classifications: institutional, public assembly, residential, commercial, large mercantile, and industrial. Examples of these include jails, theaters, apartment buildings, office buildings, shopping malls, and chemical plants, respectively.

Sections 7.2 and 7.3 of ASHRAE 15-2022 determine the maximum amount of refrigerant allowed in the system, while section 7.4 provides an option to locate equipment outdoors or in a machinery room constructed and maintained under conditions specified in the standard. Section 7.7 of ASHRAE 15-2022 addresses the A2L refrigerants in this proposal when used in “high-probability” systems that are not for human comfort, including requirements for nameplates, labels, refrigerant detectors (under certain conditions), airflow initiation and other actions (if a rise in refrigerant concentration is detected), and other restrictions.

EPA recognizes that ASHRAE 15-2022 is undergoing continuous maintenance with publication of periodic addenda and is typically updated and republished every three years. While this proposed rule incorporates all addenda published by the date of this proposal, there may be additional changes to ASHRAE 15-2022 by the time EPA issues a final rule based upon this proposal. However, given EPA would not have reviewed and proposed use conditions based on those changes, EPA is not proposing to include addenda or other changes made to ASHRAE 15-2022 after the date of the proposed rule.

EPA is proposing to list R-454A as acceptable, subject to use conditions, in supermarkets and remote condensing units with a use condition that this substitute may only be used either in equipment with a refrigerant charge capacity less than 200 pounds or in the high-temperature side of a cascade system. The Agency is proposing this use condition to allow use of R-454A less broadly than for the other

refrigerants proposed for use in remote condensing units and supermarket systems because its GWP is higher than those of the other proposed listings for these end-use categories (about 240, compared to less than four to 150). EPA's understanding is that there are two particular situations where use of refrigerants is likely to be more constrained, and thus, additional refrigerant options may be helpful. The first of those situations is in what the industry standard ASHRAE 15-2022 identifies as a refrigerating system having a “high probability” that leaked refrigerant from a failed connection, seal, or component could enter an occupied area. An example of such a constraint is that ASHRAE 15-2022 and UL 60335-2-89 effectively set charge limits for A2L refrigerants to less than 200 pounds for applications inside a supermarket or convenience store that are open to the general public. In contrast, larger charge sizes could be used in “low-probability” locations where the general public is unlikely to come in contact with the refrigerant, such as systems used outdoors or in a machinery room with access restricted to store employees. Where the general public is unlikely to come into contact with any leaked refrigerant, such as where charge sizes of 200 pounds or more of A2L refrigerant would be allowed under the use conditions incorporating UL 60335-2-89 and ASHRAE 15-2022, there would be fewer space constraints and greater flexibility in equipment design, so refrigeration system designers can accommodate a narrower set of substitutes. Conversely, where the general public is more likely to come into contact with any leaked refrigerant in an interior space, refrigerant charge capacities of a system would be less than 200 pounds; there would be more space constraints, less flexibility in equipment design, and potentially stricter code requirements, leading to a need for more refrigerant options. Allowing the additional option of R-424A for supermarket systems and remote condensing units with smaller refrigerant charges would enable the use of a wider set of available substitutes to manage safety (in particular, flammability and toxicity), as well as allowing more options to achieve adequate performance where there may be more constraints. Therefore, EPA is proposing to list R-454A as acceptable, subject to use conditions, only for supermarket systems and remote condensing units with a refrigerant charge capacity less than 200 pounds.

EPA is also proposing to list R-454A as acceptable, subject to use conditions, for use in the high temperature side of cascade systems used for supermarket systems and remote condensing units. As discussed above in section II.A.1, “Background on retail food refrigeration,” each system of a cascade system uses a different refrigerant that is most suitable for the given temperature range. High temperature systems, or the “high temperature side,” have typically used HFCs as a refrigerant; however, it is technologically achievable and has become more common to use ammonia in the high temperature side. For lower temperature systems, or the “low temperature side” of the cascade system, low boiling refrigerants such as R-744 can be used. Considerations for the choice of refrigerant on the high or low temperature side of cascade systems are influenced by many factors including, but not limited to, a refrigerant's toxicity and flammability, its temperature glide, and its suitability for lower temperature applications. EPA understands that use of flammable or toxic refrigerants, such as ammonia, on the high temperature side of a cascade may be limited in certain circumstances (

e.g.,

based on building codes and/or standards). The Agency considered whether to propose to list R-454A as acceptable, subject to narrowed use limits. For listings with narrowed use limits, the refrigerant user (

e.g.,

equipment manufacturer or end user) intending to adopt a substitute with narrowed use limits “must ascertain that other alternatives are not technically feasible.” 40 CFR 82.180(b)(3). In the case of the high side of a cascade system, EPA is currently aware of a limited number of available options with a GWP below R-454A; therefore, EPA does not consider it necessary to require users to first consider those lower GWP refrigerants before selecting R-454A. The Agency notes that there are multiple substitutes available for the low temperature side of the cascade system with GWPs lower than that of R-454A, but there are few options for the high temperature side of the cascade system. Therefore, instead of proposing to list R-454A as acceptable, subject to narrowed use limits and subject to use conditions, EPA is proposing to list R-454A as acceptable, subject to use conditions, when it is used in the high temperature side of cascade systems; this would expand the refrigerant options that can comply with local building codes and industry safety standards while meeting the more challenging application of the high temperature side of a cascade system.

5. What additional information is EPA including in these proposed listings?

EPA is providing additional information related to these proposed listings. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute under the SNAP program. The additional information applies to multiple end-uses covered in this proposal. Because of this similarity, EPA discusses the proposed additional information in these proposed listings that would apply to all five end-uses in section II.H.2 While the items listed are not legally binding under the SNAP program, EPA encourages users of substitutes to apply all statements in the

FURTHER INFORMATION

column in their use of these substitutes.

6. On which topics is EPA specifically requesting comment?

EPA is requesting comment on all aspects of the proposed decision to list HFO-1234yf, HFO-1234ze(E), R-454A, R-454C, R-455A, R-457A, and R-516A acceptable, subject to use conditions, in new supermarket systems and new remote condensing units as discussed in this section II.A. We also request comment on the use conditions specifically for R-454A, restricting its use to supermarket systems and remote condensing units used either with a refrigerant charge capacity of less than 200 pounds or in the high temperature side of a cascade system, and whether EPA should use different criteria in the final use conditions. We request comment on our proposal to find HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A acceptable, subject to use conditions, for use in new refrigerated food processing and dispensing equipment (self-contained equipment) and new stand-alone units. EPA also seeks specific comments on the use conditions including the proposed requirements to comply with UL 60335-2-89, and for charge sizes larger than “m

3

,” also to comply with ASHRAE 15-2022 including addenda as of the date of this proposal. With respect to these standards, EPA is requesting comment on the risk mitigation offered by compliance with the current version of the standards proposed as use conditions,

i.e.,

UL 60335-2-89 and ASHRAE 15-2022, the nature of updates proposed for these standards, and the expected timeline for those updates. EPA is requesting comment on the applicability of the 2nd edition of UL 60335-2-89 to retail food refrigeration equipment, including which types of equipment and under which

applications the standard applies, as well as on the applicability of ASHRAE 15-2022 with the addenda published as of the date of this proposal. Finally, EPA requests comment on whether there are any specific cases of conflicts between UL 60335-2-89 and ASHRAE 15-2022 that require a clarification as to which standard should apply.

B. Retail Food Refrigeration—Proposed Listing of R-290 as Acceptable, Subject to Use Conditions, for Use in New Refrigerated Food Processing and Dispensing Equipment and Proposed Revision of Use Conditions Provided in the Previous Listing of R-290 as Acceptable, Subject to Use Conditions, for Use in Stand-Alone Units

This proposed listing for R-290 would be a new listing for one end-use category under retail food refrigeration,

i.e., new refrigerated food processing and dispensing equipment.

Further, EPA is also proposing to revise use conditions provided in the previous listing of R-290 as acceptable, subject to use conditions, for use in new stand-alone units. More specifically, EPA previously listed R-290 as acceptable, subject to use conditions, in new stand-alone units in SNAP Rule 17 (76 FR 78832, December 20, 2011). In this document, we are proposing to update those use conditions to be consistent with the most recent U.S. national standard for retail food refrigeration equipment, the 2nd edition of UL 60335-2-89. Similar use conditions apply to other refrigerants with lower flammability as proposed in this SNAP action in section II.A above. The proposed use conditions would be allowed for such equipment manufactured on or after the effective date of any final rule and would not apply to nor affect equipment manufactured before the effective date of any final action and manufactured in compliance with the SNAP requirements applicable at the time of manufacture.

This proposed revision to the use conditions would incorporate by reference a different industry standard, changing the reference from Supplement SB to the 10th edition of UL 471, “Commercial Refrigerators and Freezers,” which is required in the current SNAP listing for R-290, to the 2nd edition of UL 60335-2-89. EPA is proposing a transition period during which stand-alone units manufactured with R-290 may follow either the earlier standard UL 471 or UL 60335-2-89. After the transition period ends, stand-alone units manufactured with R-290 would need to follow UL 60335-2-89 for purposes of the SNAP program.

Several use conditions proposed for these end-use categories are similar to those proposed for other end-uses. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. In summary, the common use conditions proposed include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

If the regulatory text is finalized as proposed, EPA would revise the existing listing for R-290 in new stand-alone units in appendix R to 40 CFR part 82, subpart G, and would add the new listing for R-290 in refrigerated food processing and dispensing units in appendix Y to 40 CFR part 82, subpart G. The proposed regulatory text contains revised listing decisions for new stand-alone units in appendix R, as well as certain other previous listings that EPA is republishing for purposes of formatting for the

Federal Register

;

EPA is not proposing substantive changes to, and is not taking comment on, those earlier decisions (

e.g.,

listings for R-290, R-441A, and R-600a in household refrigerators and freezers and in vending machines).

1. Background on Retail Food Refrigeration

See section II.A.1 for background on the retail food refrigeration end-use and particularly for the stand-alone units and refrigerated food processing and dispensing equipment end-use categories.

2. What are the ASHRAE classifications for refrigerant flammability?

ASHRAE 34-2022 categorizes R-290 as being in the A3 Safety Group. See section II.A.2 for further discussion on ASHRAE classifications.

3. What is R-290 and how does it compare to other refrigerants in the refrigerated food processing and dispensing equipment end-use category?

R-290 is also known as propane and has the formula C

3

H

8

(CAS Reg. No. 74-98-6). Redacted submissions and supporting documentation for R-290 in retail food refrigeration are provided in the docket for this proposed rule (EPA-HQ-OAR-2023-0043) at

https://www.regulations.gov.

EPA performed a risk screening assessment to examine the health and environmental risks of this substitute. This risk screen is available in the docket for this proposed rule.

21

21

ICF, 2023h. Risk Screen on Substitutes in Retail Food Refrigeration (New Equipment); Substitute: Propane (R-290).

Environmental information:

R-290 has an ODP of zero. R-290 has a GWP of three. R-290 is regulated as a VOC under CAA regulations (40 CFR 51.100(s)) addressing the development of SIPs to attain and maintain the NAAQS. EPA previously exempted R-290 in retail food refrigerators and freezers (stand-alone units only) from the prohibition under CAA section 608(c)(2) on knowingly venting, releasing, or disposing of substitute refrigerants, finding that such venting, release, or disposal does not pose a threat to the environment (79 FR 29682, May 23, 2014).

EPA evaluated potential impacts of R-290 and other HC refrigerants on local air quality. R-290 (propane) is considered a VOC and is not excluded from EPA's regulatory definition of VOC (see 40 CFR 51.100(s)) addressing the development of SIPs to attain and maintain the NAAQS. As described below, EPA estimates that potential emissions of saturated HC refrigerants, such as R-290 and R-600a (isobutane), do not have a significant impact on local air quality.

22

22

ICF, 2014a. Assessment of the Potential Impact of Hydrocarbon Refrigerants on Ground Level Ozone Concentrations. February, 2014.

EPA has conducted multiple analyses of various scenarios to consider the potential impacts on local air quality if HC refrigerants were used widely.

23

The analyses considered both worst-case and more realistic scenarios. In an analysis supporting the listings of R-290, R-600a, and the HC blend R-441A in multiple refrigeration and air conditioning end-uses in SNAP Rule 19 (80 FR 19454, April 10, 2015), the worst-case scenario assumed that the most reactive HC listed as acceptable as of the time of those listings (R-600a) was used in all refrigeration and AC uses and that all refrigerant used was emitted to the atmosphere rather than most being recovered. In that extreme scenario, the model predicted that the maximum increase in any single 8-hour average ground-level ozone concentration would be 0.72 parts per billion (ppb) in Los Angeles, which is the area with the highest level of ozone pollution in the United States. At the time of the analysis in 2014, 0.72 ppb was less than 1% of the NAAQS, and

we stated at the time that the use of R-600a consistent with the use conditions required in EPA's regulations would not result in significantly greater risk to the environment than other alternatives. Using the current ozone NAAQS value of 70 ppb, use of the most reactive saturated HC, R-600a, with a 100% market penetration would just exceed a level that might raise concerns for EPA. However, considering that R-290 is less reactive than R-600a

24

and that R-290 would have a market penetration at least as high as that of R-600a,

25

we still consider use of saturated HC refrigerants not to result in significantly greater risk.

23

Ibid.

24

R-600a has a maximum incremental reactivity (MIR) of 1.34 g O

3

/g R-600a, while R-290 has a MIR of 0.56 g O

3

/g R-290. ICF, 2023h, Op. cit.; Carter, 2010. “Development of the SAPRC-07 Chemical Mechanism and Updated Ozone Reactivity Scales,” Report to the California Air Resources Board by William P.L. Carter. Revised January 27, 2010.

In a less conservative analysis of potential impacts on ambient ozone levels, EPA looked at a set of end-uses that would be more likely to use HC refrigerants between now and 2030, including end-uses where they previously have been listed as acceptable and where they are proposed to be acceptable under this rule. For example, we assumed use of R-290 in refrigerated food processing and dispensing equipment

25

and in end-uses where it is already listed as acceptable, including retail food refrigeration—stand-alone units, vending machines, water coolers, self-contained commercial ice machines, room air conditioners, and household refrigerators and freezers. We also assumed the use of other HC refrigerants such as R-600a and R-441A in end-uses where they are listed as acceptable, such as in retail food refrigeration—stand-alone units, vending machines, and household refrigerators and freezers. For further information on the specific assumptions, see the docket for this rulemaking.

26

Based on this still conservative but more probable assessment of refrigerant use, we found that even if all the refrigerant in appliances in end-uses addressed in this proposed rule and in appliances in end-uses for which other HCs are listed as acceptable were to be emitted, there would be a worst-case impact of a 0.15 ppb increase in ozone for a single 8-hour average concentration in the Los Angeles area, which is the area with the highest level of ozone pollution in the United States. In the other cities examined in the analysis, Houston and Atlanta, impacts were smaller (no more than 0.03 and 0.01 ppb for a single 8-hour average concentration, respectively).

27

For areas in the analysis that were not violating the 2008 ozone NAAQS, the impacts did not cause an exceedance of the 2008 ozone NAAQS.

25

In the analysis, refrigerated food processing and dispensing equipment was evaluated under the category of “small retail food” refrigeration equipment, along with stand-alone units, vending machines, and water coolers.

26

ICF, 2014a. Assessment of the Potential Impact of Hydrocarbon Refrigerants on Ground Level Ozone Concentrations. February 2014.

27

Ibid.

EPA also has performed more recent air quality analyses, considering additional end-uses and refrigerants that have been listed acceptable more recently (

e.g.,

R-1150 in very low temperature refrigeration) and using updated models.

28

EPA found that the revised air quality models showed slightly greater impacts compared to our 2014 analyses in all scenarios, but not enough to change our earlier conclusions in 2015 and 2016 that use of saturated HCs as refrigerants, including release of R-290, R-600a, and R-441A during repairing, maintaining, servicing, or disposing of appliances, would not result in a significant increase in ground-level ozone. Further, there would be no change in the prior conclusion that use of the saturated HCs R-290, R-600a, and R-441A, consistent with the SNAP listings, including their use conditions and the proposed use conditions in this rule, would not result in significantly greater risk to people's health or the environment than other alternatives available for the same end-use, refrigerated food processing and dispensing equipment.

28

ICF, 2020. Additional Assessment of the Potential Impact of Hydrocarbon Refrigerants on Ground Level Ozone Concentrations. May 2020. Updated models included VM IO file_v5.1_10.01.19 and CMAQ 5.2.1 with carbon bond 06 (CB06) mechanism, as cited in ICF, 2020.

Based on the results of these analyses, EPA is proposing to list R-290 as acceptable, subject to use conditions, in refrigerated food processing and dispensing equipment. Because of the relatively minimal air quality impacts of R-290 if it is released to the atmosphere from the end-uses where it is listed as acceptable subject to use conditions and from the proposed refrigerated processing and dispensing equipment end-use category, even in a worst-case scenario, we conclude that R-290 does not have a significantly greater overall impact on human health and the environment based on its effects on local air quality than other refrigerants listed as acceptable in the same end-uses.

Flammability information:

R-290 is a higher flammability refrigerant, with an ASHRAE safety classification of A3. However, the proposed substitute is not expected to present a flammability concern provided the proposed use conditions are followed.

Toxicity and exposure data:

R-290 has an ASHRAE toxicity classification of A (lower toxicity). Potential health effects of exposure to this substitute include drowsiness or dizziness. The substitute may also irritate the skin or eyes or cause frostbite. This substitute could cause asphyxiation if air is displaced by vapors in a confined space. These potential health effects are common to many refrigerants.

OSHA has established a PEL of 1,000 ppm as an 8-hr TWA for propane (R-290). EPA anticipates that users will be able to meet OSHA's PEL and address potential health risks by following requirements and recommendations in the manufacturers' SDSs, the use conditions proposed (including compliance with UL 60335-2-89), adherence to ASHRAE 15-2022, and other safety precautions common to the refrigeration and AC industry.

Comparison to other substitutes in the refrigerated food processing and dispensing end-use category:

R-290 has an ODP of zero, comparable to or lower than some of the acceptable substitutes in new refrigerated food processing and dispensing equipment, such as CO

2,

R-450A, and R-513A, with ODPs of zero.

R-290's GWP of 3 is comparable to that of other acceptable substitutes for new refrigerated food processing and dispensing equipment, including CO

2

, with a GWP of 1. The GWP of R-290 is lower than some of the acceptable substitutes for new refrigerated food processing and dispensing equipment, such as R-450A, R-513A, R-134a, and R-407H, with GWPs of approximately 600, 630, 1,430, and 1,500, respectively.

EPA's risk screen for R-290 in retail food refrigeration,

29

including refrigerated food processing and dispensing equipment, found that R-290 can be used without exceeding its PEL of 1,000 ppm (8-hr TWA); thus, the toxicity risks of R-290 are comparable to those of other acceptable substitutes in the refrigerated food processing and dispensing equipment end-use category, which also are used without exceeding their workplace exposure limits.

29

ICF, 2023h. Op. cit.

Although we noted that the flammability of R-290 may be greater than that of other available, substitutes with an ASHRAE 1, 2, or 2L flammability classification in the same end-use, we found its flammability risk to be not significant even under worst-case assumptions in this end-use category when following the proposed

use conditions.

30

We note that flammability risk can be minimized by use consistent with industry standards such as UL 60335-2-89—which would be required by our proposed use conditions—and ASHRAE 15-2022, as well as recommendations in the manufacturers' SDS and other safety precautions common in the refrigeration and air conditioning industry. The proposed use conditions for refrigerated food processing and dispensing equipment would maintain low potential risk associated with the flammability of this alternative so that it will not pose significantly greater risk than other acceptable substitutes in this end-use category.

30

ICF, 2023h. Op. cit.

The proposed substitute, R-290, has a GWP of 3, lower than that of most other available alternatives for the same end-use category with similarly low toxicity. R-290 provides an additional lower-GWP option for situations where other refrigerants with lower GWPs are not viable, such as where equipment using CO

2

may not be able to meet DOE's energy conservation standards. To provide additional, lower-GWP options with lower overall risk to human health and the environment, EPA is proposing the listing of R-290 as acceptable, subject to use conditions, for use in refrigerated food processing and dispensing equipment.

4. Why is EPA proposing these specific use conditions for refrigerated food processing and dispensing equipment?

For refrigerated food processing and dispensing equipment, EPA proposes to require use of UL 60335-2-89, for purposes of the SNAP program, as of the effective date of the final rule based on this proposal. Several of the use conditions proposed for refrigerated food processing and dispensing equipment are common to those proposed for R-290 in the commercial ice machine end-use in section II.D, and others are common to all five end-uses in this proposed rule. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. In summary, the common use conditions proposed include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

5. How would the proposed listing for R-290 in refrigerated food processing and dispensing equipment relate to regulations implementing the venting prohibition under CAA section 608?

In section II.I of this document, EPA is proposing to exempt R-290 used as a refrigerant in refrigerated food processing and dispensing equipment from the prohibition under CAA section 608(c)(2) on knowingly venting or otherwise knowingly releasing or disposing of any substitute refrigerant in the course of maintaining, servicing, repairing, or disposing of an appliance or industrial process refrigeration.

6. What use conditions currently apply to this refrigerant in the stand-alone units end-use category?

EPA previously listed R-290 acceptable, subject to use conditions, in new stand-alone units in SNAP Rule 17 (76 FR 78832, December 20, 2011). Those requirements are codified in appendix R to 40 CFR part 82, subpart G. EPA provided information on the potential environmental and health risks of R-290 and the various substitutes available at that time for use in this end-use category. Additionally, EPA's previous risk screen for this refrigerant in this end-use category, based on the use conditions in that rule, is available in the docket for that previous rulemaking (EPA-HQ-OAR-2009-0286).

R-290 has an ASHRAE classification of A3, indicating that it has low toxicity and higher flammability. In the presence of an ignition source (

e.g.,

static electricity, a spark resulting from a closing door, or a cigarette), an explosion or a fire could occur if the concentration of R-290 were to exceed the LFL of 21,000 ppm (2.1 percent) by volume.

The use conditions established in the 2011 listing for R-290 in new stand-alone units addressed safe use of this flammable refrigerant based on information available at that time and included the following: incorporation by reference of Supplement SB to the 10th edition (November 24, 2010) of the standard UL 471 “Commercial Refrigerators and Freezers”; refrigerant charge size limits based on cooling capacity and type of equipment; and requirements for markings and warning labels on equipment using the refrigerant to inform consumers, technicians, and first responders of potential flammability hazards. EPA explained in that rulemaking that without appropriate use conditions, the flammability risk posed by this refrigerant could be higher than non-flammable refrigerants because individuals may not be aware that their actions could potentially cause a fire, and because the refrigerant could be used in existing equipment that has not been designed specifically to minimize flammability risks. Our assessment and listing decisions in SNAP Rule 17 (76 FR 78832, December 20, 2011) found that with the use conditions, the overall risk of R-290, including the risk due to flammability, was not significantly greater in the stand-alone units end-use than other substitutes that are currently or potentially available for that same end-use.

7. What updates to existing use conditions for stand-alone units is EPA proposing?

EPA is proposing to update the use conditions that apply to R-290 in new stand-alone units manufactured on or after the effective date of any final rule based on this proposal. Several of the updated use conditions proposed for use of R-290 in stand-alone units are common to those proposed for the commercial ice machine end-use in section II.D, and others are common to all five end-uses in this proposed rule. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. For R-290 in stand-alone units, these are the only revised use conditions EPA is proposing. In summary, with the updates proposed to the use conditions for stand-alone units, the common use conditions proposed include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

If finalized as proposed, the use conditions in this action would apply to new stand-alone units on or after the effective date of any final rule. Any final rule would not apply to nor affect equipment manufactured before the effective date of this action and manufactured in compliance with the SNAP use conditions applicable at the time of manufacture as stipulated in SNAP Rule 17 and appendix R to 40 CFR part 82, subpart G. EPA views equipment to be manufactured at the date upon which the appliance's

refrigerant circuit is complete, the appliance can function, the appliance holds a full refrigerant charge, and the appliance is ready for use for its intended purposes. For stand-alone units (and most refrigerated food processing and dispensing equipment), this occurs at the factory. If this rule is finalized as proposed, new stand-alone units manufactured between February 21, 2012, and the effective date of the final rule would be required to meet the use conditions in SNAP Rule 17 (which took effect February 21, 2012) and as listed in appendix R to 40 CFR part 82, subpart G, including the use condition incorporating by reference Supplement SB to the 10th edition of UL 471. Such products would be permitted to be warehoused and sold through normal channels, even if they are sold or installed after the effective date of any final rule based on this proposed rule. Stand-alone units using R-290 manufactured on or after the effective date of any final rule based on this proposal would be required to meet the use conditions so finalized and listed in the revisions to appendix R. Those use conditions would allow manufacturers of new stand-alone units using R-290 to follow either UL 471 or UL 60335-2-89 from the effective date of any final rule based on this proposal and would last through September 29, 2024. On and after September 30, 2024, the use condition for use of R-290 in equipment that meets UL 60335-2-89 only would apply under SNAP.

EPA is proposing use conditions allowing new stand-alone units to be manufactured consistent with Supplement SB of UL 471, up to and including September 29, 2024, which is the date when UL is sunsetting UL 471. Therefore, during the time between the effective date of any final rule based on this proposal and September 29, 2024, manufacturers would be allowed to follow either UL 471, 10th Edition or UL 60335-2-89, 2nd Edition. EPA is proposing allowing manufacturers to adhere to either standard for this limited time because the Agency recognizes that manufacturers may need time to make necessary changes including to their product labels. The period during which manufacturers may follow either standard should provide sufficient time for manufacturers to transition from UL 471 to UL 60335-2-89. EPA proposes that, beginning September 30, 2024, R-290 may only be used in new stand-alone units that meet all requirements in UL 60335-2-89 for the purposes of the SNAP program. See section II.H.1 for further discussion on the requirements of this standard that EPA is proposing to incorporate by reference.

In addition, we are proposing that manufacturers would need to follow the set of use conditions that correspond with a specific UL standard (

i.e.,

when using UL 471, follow all use conditions in listing 2 and when using UL 60335-2-89, follow all use conditions in listing 4 in the proposed revisions to appendix R). After the transition period ends, stand-alone units manufactured with R-290 would need to follow UL 60335-2-89 for purposes of the SNAP program.

EPA also notes that we are not proposing to change two use conditions that currently apply, nor are we taking comment on those other use conditions. The use conditions that restrict the use of R-290 to new equipment specifically designed for this refrigerant, and that require red-colored markings on service ports, pipes, hoses, and other devices through which the refrigerant is serviced, repeat the current use conditions for R-290 in new stand-alone units. If the regulatory text is finalized as proposed, EPA would amend to add use conditions that apply to R-290 in new stand-alone units manufactured on or after the effective date of the final rule. Equipment manufactured before the effective date of the final rule would not be affected by this action and would hence be subject to the current use conditions included in appendix R.

8. How do the proposed use conditions for stand-alone units differ from the existing ones and why is EPA proposing to change the use conditions?

The revised use conditions EPA is proposing for stand-alone units are similar to the ones that exist today in appendix R to 40 CFR part 82, subpart G, for R-290 in this end-use category. The requirements that R-290 must be used in new equipment only, and that new stand-alone units must include red markings at service ports, pipes, hoses, and other devices through which the refrigerant is serviced, are repeated in this proposed listing. The updated use conditions concern incorporating by reference the most recent U.S. national standard and updated labeling requirements consistent with that new standard. Stand-alone units using R-290 manufactured before the effective date of a final rule to this proposal would not be affected by the updated use conditions.

Warning labels are required under EPA's current regulations, and EPA is proposing to continue to require them, although with some specific language changes. The proposed warning labels are similar to those required currently as use conditions for the use of R-290 in stand-alone units. EPA finds that using a common set of labels, similar to those from UL 60335-2-89, would aid in compliance and could reduce burden for the industry, especially for a manufacturer that uses more than one refrigerant. EPA is proposing that the labels must be provided in letters no less than 6.4 millimeter (

1/4

inch) high and must be permanent, which is identical to the current requirement for R-290 in stand-alone units.

EPA is proposing to incorporate by reference a new industry standard in the use conditions, including use of the 2nd edition of UL 60335-2-89 instead of continuing to require the standard Supplement SB of the 10th edition of UL 471 for equipment manufactured on or after the effective date of any final rule based on this proposal. UL 60335-2-89 was developed in an open and consensus-based approach, with the assistance of experts in the refrigeration and AC industry as well as experts involved in assessing the safety of products. The revision cycle for the 2nd edition, including final recirculation, concluded with its publication on October 27, 2021. The 2nd edition of UL 60335-2-89 replaces the previously published version of several standards, including UL 471, which had already been published as a 10th edition by that time. EPA was aware of the continuing progress of UL standards to address flammable refrigerants more appropriately. In SNAP Rule 23 (86 FR 24444, May 6, 2021), which listed a number of A2L refrigerants for use in the residential and light commercial AC and heat pumps (HPs) end-use, we stated, “EPA understands that the standard we relied on in [SNAP] Rule 19 might `sunset' in the future. Therefore, we will continue to evaluate the market for the equipment addressed in that rule, including R-290 in stand-alone units, and whether to establish new or revised use conditions that reference UL 60335-2-89.” In this document, we are proposing such a change knowing that UL is replacing the standard to which such equipment is certified from UL 471 to the newer standard UL 60335-2-89 starting September 30, 2024.

To allow time for manufacturers of stand-alone units to transition between the current use condition using the 10th edition of UL 471, and the new use condition using the 2nd edition of UL 60335-2-89, EPA is proposing to allow R-290 to be used in stand-alone units manufactured either following UL 471 or UL 60335-2-89 during a transition period. We propose that transition period would begin on the effective date of the final rule based on this proposal

and would last through September 29, 2024. It is EPA's understanding that UL intends to sunset UL 471 on September 29, 2024, and EPA is proposing to coordinate with that sunset date. Beginning September 30, 2024, the use condition in effect would only allow R-290 to be used in new stand-alone units that follow UL 60335-2-89. In addition, we are proposing that manufacturers would need to follow the set of use conditions that correspond with a specific UL standard (

i.e.,

when using UL 471, follow all use conditions in listing 4 and when using UL 60335-2-89, follow all use conditions in listing 6 in the proposed revisions to appendix R).

Updating the UL standard incorporated as a use condition will provide more consistency amongst the products within the retail food refrigeration end-use. This change will allow the industry to focus on the most recent standard. The change will be helpful in implementing any transitions needed or planned for manufacturers, installers, and technicians. A manufacturer, who may offer different products within this end-use with different refrigerants, could use similar processes, such as in developing and applying the warning labels required. Installers and technicians, likewise, would not need to reference different standards depending on the type of equipment and the particular flammable refrigerant being used in that equipment, when putting in a new piece of equipment or servicing that equipment.

Another proposed revision to the use conditions is the limit on charge sizes. The current use conditions from SNAP Rule 17 require the charge sizes calculated consistent with UL 471, with a maximum charge of 150 g allowed. The proposed revised use conditions for equipment manufactured on or after the effective date of any final rule would allow charge sizes calculated based on UL 60335-2-89, which allows charges of up to 500 g of R-290 for open stand-alone units, or 300 g for those with doors and drawers.

Because of the differences between UL 471 and UL 60335-2-89, EPA performed a new risk screen for R-290 as a refrigerant in retail food refrigeration equipment, including stand-alone units.

31

In this risk screen, EPA adjusted charge sizes to be consistent with the larger charge sizes of 300 g and 500 g allowed for R-290 under UL 60335-2-89. The risk screen also considered the impact of mitigation methods such as valves that would restrict the amount of refrigerant that could be released. The updated risk screen found that concentrations of R-290 still would not exceed the LFL when used according to the proposed use condition and consistent with UL 60335-2-89, and thus the proposed new use conditions would also address potential flammability risks of using R-290.

32

In addition, the risk screen modeled the reasonable work case scenario of short-term exposure (15-minute TWA) due to a catastrophic release of the charge. Under this highly conservative scenario, the worst-case exposure of 5,770 ppm was still significantly lower than the Acute Toxicity Exposure Limit (ATEL) of 50,000 ppm.

33

For further information, see the risk screen in the docket for this rulemaking.

31

ICF, 2023h. Op. cit.

32

Ibid.

33

The source of the ATEL is ASHRAE 34-2022, as cited in ICF, 2023h. Op cit.

9. What additional information is EPA including in these proposed listings?

EPA is providing additional information related to the proposed listing for R-290 in new refrigerated food processing and dispensing equipment and the proposed revised listing for R-290 in new stand-alone units. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute under the SNAP program. See section II.H.2 for further discussion on what additional information EPA is including in these proposed listings. EPA notes that the additional information is similar to, but not identical with, the addition information in the listing for R-290 in stand-alone units in SNAP Rule 17. EPA is proposing additional information consistent with that included in the other proposed listings for stand-alone units in this rule and consistent with that included in the listings for R-290 as acceptable, subject to use conditions, in stand-alone units in Rule 17. While the items listed are not legally binding under the SNAP program, EPA encourages users of substitutes to apply all statements in the “Further Information” column in their use of these substitutes.

10. On which topics is EPA specifically requesting comment?

EPA is requesting comment on all aspects of the proposed decision to list R-290 acceptable, subject to use conditions, in new refrigerated food processing and dispensing equipment as discussed in this section II.B. EPA also requests comments on the proposed change in use conditions for use of R-290 in stand-alone units, and if and how such change would affect the safety of stand-alone units using R-290. The Agency requests comment on the time periods during which manufacturers are to follow UL 471, either UL 471 or UL 60335-3-89, or only UL 60335-2-89. EPA also requests comments on the proposed use conditions for use of R-290 in new refrigerated food processing and dispensing equipment, including the proposed requirements to comply with UL 60335-2-89. With respect to this standard, EPA is requesting comment on the risk mitigation offered by compliance with the current version of the standard proposed as use conditions,

i.e.,

UL 60335-2-89, the nature of updates proposed for this standard, and the expected timeline for those updates. EPA is requesting comment on the applicability of the 2nd edition of UL 60335-2-89 to refrigerated food processing and dispensing equipment, including which types of equipment, under which applications the standard applies, and whether the listing of R-290 should apply to refrigerated food processing and dispensing equipment that has a remote compressor and is not self-contained.

C. Commercial Ice Machines—Proposed Listing of HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Commercial Ice Machines

EPA is proposing to list HFC-32, HFO-1234yf, and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new commercial ice machines.

Several use conditions proposed for commercial ice machines are common to those proposed for other end-uses. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. For commercial ice machines, those are the only use conditions EPA is proposing. In summary, the common use conditions proposed include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

If the regulatory text is finalized as proposed, EPA would revise the existing listing for R-290 in new self-contained commercial ice machines in appendix V to 40 CFR part 82, subpart G. The proposed regulatory text contains listing decisions for the commercial ice machines end-use, as well as certain other previous listings that EPA is republishing for purposes of formatting for the

Federal Register

; EPA is not proposing substantive changes to, and is not taking comment on, those earlier decisions (

i.e.,

listings for R-290 in new water coolers and in new very low temperature refrigeration equipment).

1. Background on Commercial Ice Machines

Commercial ice machines are used in commercial establishments (

e.g.,

hotels, restaurants, convenience stores) to produce ice for consumer use. Commercial ice machines

34

are another subset of commercial refrigeration and are considered a separate end-use within the SNAP program from retail food refrigeration due to differences in where such equipment is placed and the additional mechanical and electronic components required to make and dispense ice. Ice machines produce ice in various sizes and shapes, and with different retrieval mechanisms (

e.g.,

dispensers or self-retrieval from bins). Many commercial ice machines are self-contained units, while some have the condenser separated from the portion of the machine making the ice and have refrigerated lines running between the two (also known as remote equipment). Commercial ice machines fall under the scope of UL 60335-2-89, “Household and Similar Electrical Appliances—Safety—Part 2-89: Requirements for Commercial Refrigerating Appliances and Ice-Makers with an Incorporated or Remote Refrigerant Unit or Motor-Compressor.”

34

Industry standards for this type of equipment,

e.g.,

UL 563 and UL 60335-2-89, use the terms “ice maker” or “ice-maker” rather than commercial ice machines. The terms may be used interchangeably and refer to the same equipment.

This proposal, if finalized, would list HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, in new commercial ice machines.

2. What are the ASHRAE classifications for refrigerant flammability?

ASHRAE 34-2022 categorizes the refrigerants proposed for commercial ice machines in this section as being in the A2L Safety Group. See section II.A.2 for further discussion on ASHRAE classifications of these refrigerants.

3. What are HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

See section II.A.3 for further discussion on the environmental, flammability, toxicity, and exposure information for HFC-32, HFO-1234yf, R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A.

35

35

EPA previously listed HFO-1234yf as acceptable, subject to use conditions, in motor vehicle AC in light-duty vehicles (74 FR 53445, October 19, 2009), in heavy-duty pickup trucks and complete heavy-duty vans (81 FR 86778, December 1, 2016) and in nonroad vehicles and service fittings for small refrigerant cans (87 FR 26276, May 4, 2022). EPA previously listed R-454A, R-454B, R-454C, and R-457A as acceptable, subject to use conditions, as substitutes in residential and light commercial AC and HPs (86 FR 24444, May 6, 2021). EPA previously listed HFC-32 as acceptable, subject to use conditions, in self-contained room air conditioners (80 FR 19453, April 10, 2015) and listed HFC-32 as acceptable, subject to use conditions, in the remaining types of residential and light commercial air conditioning and heat pumps.

HFC-32 is also known as R-32 or difluoromethane (CAS Reg. No. 75-10-5). R-454B, also known by the trade names “Opteon

TM

XL 41” and “Puron Advance

TM

,” is a blend consisting of 68.9 percent HFC-32 and 31.1 percent HFO-1234yf. Redacted submissions and supporting documentation for HFC-32, HFO-1234yf, and the refrigerant blends are provided in the docket for this proposed rule (EPA-HQ-OAR-2023-0043) at

https://www.regulations.gov.

EPA performed a risk screening assessment to examine the health and environmental risks of each of these substitutes. These risk screens are available in the docket for this proposed rule.

36

37

38

39

40

41

42

43

36

ICF, 2023i. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: HFC-32.

37

ICF, 2023j. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: HFO-1234yf.

38

ICF, 2023k. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-454A (Opteon® XL40).

39

ICF, 2023l. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-454B.

40

ICF, 2023m. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-454C (Opteon

TM

XL20).

41

ICF, 2023n. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-455A (Solstice® L40X).

42

ICF, 2023o. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-457A (Forane® 457A).

43

ICF, 2023p. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: R-516A (Forane® 516A).

Comparison to other substitutes in this end-use:

HFC-32, HFO-1234yf, and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A all have an ODP of zero, comparable to or lower than some of the acceptable substitutes in new commercial ice machines, such as HFC-134a, R-410A, and R-513A, with ODPs of zero.

HFO-1234yf has a GWP of less than four, comparable to that of R-290 and ammonia with GWPs of 3 and zero. R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A have GWPs ranging from 140 to 470, higher than some of the acceptable substitutes for new commercial ice machines, including R-290 and ammonia with GWPs of 3 and zero, respectively, and lower than those of other substitutes such as R-450A and R-513A, with GWPs of about 600 and 630. HFC-32 has a GWP of 675, higher than some of the acceptable substitutes including R-290, R-450A, and R-513A; however, the GWP of HFC-32 is lower than those of R-410A and R-404A, with GWPs of approximately 2,090 to 3,920, which are refrigerants that have typically been employed in such systems. Our initial evaluation is that the characteristics of HFC-32 meet the technical needs of larger commercial ice machines, providing larger charge sizes, greater capacity and no glide, allowing for even formation of ice, while lower-GWP alternatives do not. For instance, R-513A and R-450A have lower capacity than HFC-32, and R-290 is restricted to smaller charge sizes (see section II.D for further information). Remote appliances using A2L refrigerants, including remote condensers, may be either self-contained or field erected and may be factory or field charged.

Information regarding the toxicity of other available alternatives is provided in the previous listing decisions for new commercial ice machines (

https://www.epa.gov/snap/substitutes-commercial-ice-machines

). Toxicity risks of use, determined by the likelihood of exceeding the exposure limit of HFC-32, HFO-1234yf, and the refrigerant blends in these end-uses are evaluated in the risk screens referenced previously. The toxicity risks of using HFC-32, HFO-1234yf, and the refrigerant blends in new commercial ice machines are comparable to or lower than toxicity risks of other available substitutes in the same end-use. Toxicity risks of the proposed refrigerants can be mitigated by use consistent with UL 60335-2-89, ASHRAE 15-2022, and other industry standards; recommendations in the manufacturers' SDS; and other safety precautions common in the refrigeration and AC industry.

The flammability risks of HFC-32, HFO-1234yf, and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-

457A, and R-516A in the new commercial ice machine end-use, determined by the likelihood of exceeding their respective lower flammability limits, are evaluated in the risk screens referenced previously in this section. While these refrigerants may pose greater flammability risk than other available, non-flammable substitutes in the new commercial ice machines end-use, this risk can be mitigated by use consistent with ASHRAE 15-2022 and UL 60335-2-89, required by our proposed use conditions, as well as recommendations in the manufacturers' SDS and other safety precautions common in the refrigeration and AC industry. EPA is proposing use conditions to reduce the potential risk associated with the flammability of these alternatives so that they will not pose significantly greater risk than other acceptable substitutes in the new commercial ice machines end-use.

In addition, the proposed substitutes have lower GWPs than most other available alternatives for new commercial ice machines. The proposed refrigerants provide additional lower-GWP options for situations where other refrigerants with lower GWPs are not viable, such as for use of HCs in systems with remote compressors or equipment requiring larger charge sizes, where equipment using CO

2

may not be able to meet energy conservation standards from the DOE, or where a refrigerant must have minimal glide to ensure consistent freezing while manufacturing ice. Given the wide range of applications and exacting performance requirements for commercial ice machines, not all refrigerants listed as acceptable under SNAP will be suitable for the range of equipment in new commercial ice machines. To provide additional options to ensure the availability of substitutes with lower GWP for the full range of new commercial ice machines and, therefore, lower overall risk to human health and the environment, EPA is proposing the listings for HFC-32, HFO-1234yf, and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new commercial ice machines.

4. Why is EPA proposing these specific use conditions?

EPA is proposing to list HFC-32, HFO-1234yf, and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new commercial ice machines. The use conditions identified in these proposed listings are explained in section II.H.1 in greater detail.

5. What additional information is EPA including in these proposed listings?

EPA is providing additional information related to these proposed listings. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute under the SNAP program. See section II.H.2 for further discussion on what additional information EPA is including in these proposed listings. While the items listed are not legally binding under the SNAP program, EPA encourages users of substitutes to apply all statements in the “Further Information” column in their use of these substitutes.

6. On which topics is EPA specifically requesting comment?

EPA is requesting comment on all aspects of the proposed decision to list HFC-32, HFO-1234yf, and R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A acceptable, subject to use conditions, in new commercial ice machines as discussed in this section II.C. EPA seeks comment on the risk mitigation offered by the proposed use conditions, including requiring compliance with UL 60335-2-89, except to the extent the proposed rule conflicts with the UL Standard, in which case we propose that the use conditions specified in the rule would apply. We also request comment on whether EPA should consider other use conditions to further mitigate potential risk from the proposed refrigerants in this end-use. EPA requests comment on whether commercial ice machines have been designed for or manufactured with the refrigerants proposed and any information on the safety of such equipment in other countries, and if and how such experience would translate to safe use in the United States.

D. Commercial Ice Machines—Proposed Revision of Use Conditions in the Previous Listing of R-290 as Acceptable, Subject to Use Conditions, for Use in New Self-Contained Commercial Ice Machines

EPA is proposing to revise use conditions in the previous listing of R-290 as acceptable, subject to use conditions, for use in new self-contained commercial ice machines. More specifically, EPA previously listed R-290 as acceptable, subject to use conditions, in new self-contained commercial ice machines in SNAP Rule 21 (81 FR 86779, December 1, 2016). In this document, we are proposing to update those use conditions to be consistent with the most recent U.S. national standard for commercial refrigeration equipment, including commercial ice machines, the 2nd edition of UL 60335-2-89. Similar use conditions would apply to other refrigerants with lower flammability as proposed in this SNAP action in section II.C above. The proposed revised use conditions would be allowed for such equipment manufactured on or after the effective date of any final rule and would not apply to nor affect equipment manufactured before the effective date of any final action and manufactured in compliance with the SNAP requirements applicable at the time of manufacture.

This proposed revision to the use conditions would incorporate by reference a different industry standard, changing the reference from Supplement SA to the 8th edition, dated July 31, 2009, of the standard UL 563, “Ice Makers” to the 2nd edition of UL 60335-2-89. EPA is proposing a transition period during which self-contained commercial ice machines manufactured with R-290 may follow either the earlier standard UL 563 or UL 60335-2-89. After the transition period ends, self-contained commercial ice machines manufactured with R-290 would need to follow UL 60335-2-89 for purposes of the SNAP program.

Several use conditions proposed for this end-use are similar to those proposed for other end-uses. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. In summary, the common use conditions proposed include the following: restricting the use of the refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards. The regulatory text of the proposed decisions appears in tables at the end of this document.

If the regulatory text is finalized as proposed, EPA would revise the existing listing for R-290 in new self-contained commercial ice machines in appendix V to 40 CFR part 82, subpart G. The proposed regulatory text contains listing decisions for new self-contained commercial ice machines in appendix V, as well as certain other previous listings that EPA is republishing for purposes of formatting for the

Federal

Register

;

EPA is not proposing substantive changes to, and is not taking comment on, those earlier decisions (

i.e.,

listings for R-290 in new water coolers and in new very low temperature refrigeration equipment).

1. Background on commercial ice machines

See section II.C.1 for background on this end-use.

2. What are the ASHRAE classifications for refrigerant flammability?

ASHRAE 34-2022 categorizes R-290 as being in the A3 Safety Group. See section II.A.2 for further discussion on ASHRAE classifications.

3. What is R-290 and were is there information on its use in this end-use?

See section II.B.3 for further discussion on the identity, environmental, flammability, toxicity, and exposure information for R-290.

Redacted submissions and supporting documentation for R-290 are provided in the docket for this proposed rule (EPA-HQ-OAR-2023-0043) at

https://www.regulations.gov.

EPA performed a risk screening assessment to examine the health and environmental risks of this substitute in self-contained commercial ice machines. The risk screen is available in the docket for this proposed rule.

44

44

ICF, 2023q. Risk Screen on Substitutes in Commercial Ice Machines (New Equipment); Substitute: (R-290).

4. What use conditions currently apply to this refrigerant in this end-use?

EPA previously listed R-290 acceptable, subject to use conditions, in new self-contained commercial ice machines in SNAP Rule 21 (81 FR 86779, December 1, 2016). Those requirements are codified in appendix V to 40 CFR part 82, subpart G. EPA provided information on the environmental and health risks of R-290 and the various substitutes available at that time for use in this end-use. Additionally, EPA's previous risk screen for this refrigerant, based on the use conditions in that rule, is available in the docket for that previous rulemaking (EPA-HQ-OAR-2015-0663).

R-290 has an ASHRAE classification of A3, indicating that it has low toxicity and higher flammability. In the presence of an ignition source (

e.g.,

static electricity, a spark resulting from a closing door, or a cigarette), an explosion or a fire could occur if the concentration of R-290 were to exceed the LFL of 21,000 ppm (2.1 percent) by volume.

The use conditions established in the 2016 listing for R-290 in new self-contained commercial ice machines addressed safe use of this flammable refrigerant and included the following: incorporation by reference of Supplement SA to the 8th edition (July 31, 2009, including revisions through November 29, 2013) of the standard UL 563, “Ice Makers”; refrigerant charge size limits based on cooling capacity and type of equipment; and requirements for markings and warning labels on equipment using the refrigerant to inform consumers, technicians, and first responders of potential flammability hazards. Our assessment and listing decisions in SNAP Rule 21 (81 FR 86779, December 1, 2016) found that with the use conditions, the overall risk of this substitute, including the risk due to flammability, was not significantly greater risk in this end-use than other substitutes that are currently or potentially available for that same end-use.

5. What updates to the existing use conditions for commercial ice machines is EPA proposing?

EPA is proposing to update the use conditions that apply to R-290 in new self-contained commercial ice machines manufactured on or after the effective date of any final rule based on this proposal. Several of the updated use conditions proposed for use of R-290 in self-contained commercial ice machines are common to those proposed for the stand-alone units end-use in section II.B, and other are common to all five end-uses in this proposed rule. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. For R-290 in self-contained commercial ice machines, these are the only revised use conditions EPA is proposing. In summary, with the updates proposed to the use conditions for new self-contained commercial ice machines, the common use conditions proposed include the following: restricting the use of the refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

If finalized as proposed, the use conditions in this action would apply to new self-contained commercial ice machines manufactured on or after the effective date of the final rule. Any final rule would not apply to nor affect equipment manufactured before the effective date of this action and manufactured in compliance with the SNAP use conditions applicable at the time of manufacture as stipulated in SNAP Rule 21 and appendix V to 40 CFR part 82, subpart G. EPA views equipment to be manufactured at the date upon which the appliance's refrigerant circuit is complete, the appliance can function, the appliance holds a full refrigerant charge, and the appliance is ready for use for its intended purposes. For new self-contained commercial ice machines, this occurs at the factory. If this rule is finalized as proposed, new self-contained commercial ice machines manufactured between January 3, 2017, and the effective date of the final rule based on this proposal would be required to meet the use conditions in SNAP Rule 21 (which took effect January 3, 2017) and as listed in appendix V to 40 CFR part 82, subpart G (in listing 1), including the use condition incorporating by reference Supplement SA to the 8th edition of UL 563. Such products would be permitted to be warehoused and sold through normal channels, even if they are sold or installed after the effective date of any final rule based on this proposed rule. Self-contained ice machines using R-290 manufactured on or after the effective date of any final rule based on this proposal through September 29, 2024, would be required to meet the use conditions so finalized and listed in the revisions to appendix V. Those use conditions would allow manufacturers of new self-contained commercial ice machines using R-290 to follow either UL 563 or UL 60335-2-89 from the effective date of any final rule based on this proposal and would last through September 29, 2024. On and after September 30, 2024, the use condition for use of R-290 in equipment that meets UL 60335-2-89 only would apply under SNAP.

EPA is proposing use conditions allowing new self-contained commercial ice machines to be manufactured consistent with Supplement SA of UL 563, up to and including September 29, 2024, which is the date when UL is sunsetting UL 563. Therefore, during the time between the effective date of any final rule based on this proposal and September 29, 2024, manufacturers would be allowed to follow either UL 563, 8th Edition or UL 60335-2-89, 2nd Edition. EPA is proposing allowing manufacturers to adhere to either

standard for this limited time because the Agency recognizes that manufacturers may need time to make necessary changes including to their product labels. The period during which manufacturers may follow either standard should provide sufficient time for manufacturers to transition from UL 563 to UL 60335-2-89. EPA proposes that, beginning September 30, 2024, R-290 may only be used in new self-contained commercial ice machines that meet all requirements in UL 60335-2-89 for the purposes of the SNAP program. See section II.H.1 for further discussion on the requirements of this standard that EPA is proposing to incorporate by reference.

In addition, we are proposing that manufacturers would need to follow the set of use conditions that correspond with a specific UL standard (

i.e.,

when using UL 563, follow all existing use conditions in listing 1 and when using UL 60335-2-89, follow all use conditions in listing 3 in the proposed revisions to appendix V). After the transition period ends, stand-alone units manufactured with R-290 would need to follow UL 60335-2-89 for purposes of the SNAP program.

EPA also notes that we are not proposing to change two use conditions that currently apply, nor are we taking comment on those other use conditions. The use conditions that restrict the use of R-290 to new equipment specifically designed for this refrigerant, and that require red-colored markings at service ports, pipes, hoses, and other devices through which the refrigerant is serviced, are current use conditions for R-290 in new self-contained commercial ice machines.

If the regulatory text is finalized as proposed, EPA would amend to add use conditions that apply to R-290 in new self-contained commercial ice machines manufactured on or after the effective date of the final rule. Equipment manufactured before the effective date of the final rule would not be affected by this action and would hence be subject to the current use conditions included in appendix V.

6. How do the proposed use conditions for commercial ice machines differ from the existing ones and why is EPA proposing to change the use conditions?

The updated use conditions EPA is proposing are similar to the ones that exist today in appendix V to 40 CFR part 82, subpart G, for R-290 in this end-use. The proposed requirements that R-290 must be used in new equipment only and that new self-contained commercial ice machines must include red markings at service ports, pipes, hoses, and other devices through which the refrigerant is serviced, are repeated in this proposed listing. The revised use conditions concern incorporating by reference the most recent U.S. national standard for commercial ice machines and labeling requirements consistent with that new standard. Self-contained commercial ice machines using R-290 manufactured before the effective date of a final rule based on this proposal would not be affected by the revised use conditions.

Warning labels are required under EPA's current regulations, and EPA is proposing to continue to require them, although with some specific language changes. EPA is proposing warning labels that are identical to those required as use conditions for the use of R-290 in self-contained commercial ice machines. EPA finds that using a common set of labels, similar to those from UL 60335-2-89, would aid in compliance and could reduce burden for the industry, especially for a manufacturer that uses more than one refrigerant. EPA is proposing that the labels must be provided in letters no less than 6.4 millimeter (

1/4

inch) high and must be permanent, which is identical to the current requirement for R-290 in self-contained commercial ice machines.

EPA is proposing to update the standard incorporated by reference in the use conditions, and after a transition period, replacing the requirement to follow Supplement SA of the 8th edition of UL 563 with the proposed requirement to adhere to the 2nd edition of UL 60335-2-89. UL 60335-2-89 was developed in an open and consensus-based approach, with the assistance of experts in the refrigeration and AC industry as well as experts involved in assessing the safety of products. The revision cycle for the 2nd edition, including final recirculation, concluded with its publication on October 27, 2021. The 2021 standard UL 60335-2-89 replaces the previously published version of several standards, including UL 563, which had already been revised into an 8th edition by that time. EPA was aware of the continuing progress of UL Standards to address flammable refrigerants more appropriately. In this document, we are proposing such a change knowing that UL is replacing the standard to which such equipment is certified from UL 563 to the newer UL 60335-2-89 as of September 30, 2024.

To allow time for manufacturers of self-contained commercial ice machines to transition between the current use condition using the 8th edition of UL 563, and the new use condition using the 2nd edition of UL 60335-2-89, EPA is proposing to allow R-290 to be used in self-contained commercial ice machines manufactured either following UL 563 or UL 60335-2-89 during a transition period. We propose that transition period would begin on the effective date of any final rule based on this proposal and would last through September 29, 2024. It is EPA's understanding that UL intends to sunset UL 563 on September 29, 2024, and EPA is proposing to coordinate with that sunset date. Beginning September 30, 2024, the use condition in effect would only allow R-290 to be used in new self-contained commercial ice machines that follow UL 60335-2-89. In addition, we are proposing that manufacturers would need to follow the set of use conditions that correspond with a specific UL standard (

i.e.,

when using UL 563, follow all use conditions in listing 1 and when using UL 60335-2-89, follow all use conditions in listing 3 in the proposed revisions to appendix V).

Incorporating UL 60335-2-89 by reference in a use condition would allow the industry to manufacture and test refrigeration equipment following the most recent standard, which provides additional flexibility and safeguards when using flammable refrigerants. The transition period when equipment may follow either UL standard would be helpful in implementing any transitions needed or planned for manufacturers, installers, and technicians. A manufacturer, who may offer different products within this end-use with different refrigerants, could use similar processes, such as in developing and applying the warning labels required.

Another proposed revision to the use conditions is the limit on charge sizes. The current use conditions from SNAP Rule 21 require the charge sizes from UL 563 calculated consistent with UL 563, with a maximum charge size of 150 g allowed. The proposed revised use conditions for equipment manufactured on or after the effective date of any final rule would allow charge sizes calculated based on UL 60335-2-89, which would allow charge sizes of R-290 up to approximately 500 g for open equipment, 300 g for equipment with doors or drawers, or 115 g for equipment near a pathway for egress. These changes would allow the use of R-290 in larger equipment than previously and would provide more options for industry, while maintaining safety.

Because of the differences between UL 563 and UL 60335-2-89, EPA performed a new risk screen for R-290 as a refrigerant in commercial ice

machines.

45

In this risk screen, EPA adjusted charge sizes to be consistent with the larger charge sizes allowed for R-290 under UL 60335-2-89. The risk screen also considered the impact of mitigation methods such as valves that would restrict the amount of refrigerant that could be released. The updated risk screen found that concentrations of R-290 still would not exceed the LFL when used according to the proposed use condition and consistent with UL 60335-2-89, and thus the proposed new use conditions would also address potential flammability risks of using R-290.

46

In addition, the risk screen modeled the reasonable worst-case scenario of short-term exposure (15-minute TWA) due to a catastrophic release of the charge. Under this highly conservative scenario, the worst-case exposure was still significantly lower than the ATEL of 50,000 ppm.

47

For further information, see the risk screen in the docket for this rulemaking.

45

ICF, 2023q. Op. cit.

46

Ibid.

47

Ibid.

7. What additional information is EPA including in this proposed listing?

EPA is providing additional information related to this proposed listing. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute under the SNAP program. See section II.H.2 for further discussion on what additional information EPA is including in these proposed listings. EPA notes that the additional information is similar to, but not identical with, the addition information in the listing for R-290 in self-contained commercial ice machines in SNAP Rule 21. EPA is proposing additional information consistent with that included in the other proposed listings for stand-alone units in this rule and consistent with that included in the listings for R-290 as acceptable, subject to use conditions, in self-contained commercial ice machines in Rule 21. While the items listed are not legally binding under the SNAP program, EPA encourages users of substitutes to apply all statements in the “Further Information” column in their use of these substitutes.

8. On which topics is EPA specifically requesting comment?

EPA is requesting comment on all aspects of the proposed updates to the use conditions as discussed in this section II.D. EPA requests comments on the proposed change in use conditions and if and how such change would affect the safety of self-contained commercial ice machines using R-290. EPA is requesting comment on the risk mitigation offered by compliance with the current version of the standard proposed as use conditions,

i.e.,

UL 60335-2-89, the nature of updates proposed for this standard, and the expected timeline for those updates. The Agency also requests comment on allowing a transition period where either of two sets of use conditions, including either UL 563 or UL 60335-2-89, may be followed and on the specific dates for the transition period. EPA is requesting comment on the applicability of the 2nd edition of UL 60335-2-89 to new self-contained commercial ice machines, including which types of equipment, under which applications the standard applies, and whether the listing of R-290 should apply to commercial ice machines that have a remote compressor and are not self-contained.

E. Industrial Process Refrigeration—Proposed Listing of HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as Acceptable, Subject to Use Conditions, for Use in New Industrial Process Refrigeration

EPA is proposing to list HFC-32, HFO-1234yf, HFO-1234ze(E), and the refrigerant blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in new industrial process refrigeration.

Most of the use conditions proposed for the proposed A2L refrigerants when used in IPR are the same as those proposed for other end-uses. Because of this similarity, EPA discusses the use conditions that would apply to all five end-uses in section II.H. In summary, the common use conditions proposed include the following: restricting the use of each refrigerant to new equipment that is specifically designed for that refrigerant; use consistent with the 2nd edition of UL 60335-2-89, including testing, charge sizes, ventilation, usage space requirements, and certain hazard warnings and markings; and requirements for warning labels and markings on equipment to inform consumers, technicians, and first responders of potential flammability hazards.

The following use condition also applies for R-32 and R-454B in industrial process refrigeration: these substitutes may only be used in chillers for IPR.

The following use condition also applies for R-454A in IPR: this substitute may only be used either in chillers for IPR, in equipment with a refrigerant charge capacity less than 200 pounds, or in the high temperature side of a cascade system.

The regulatory text of the proposed decisions appears in tables at the end of this document. If finalized as proposed, this text would be codified in appendix Y to 40 CFR part 82, subpart G. The proposed regulatory text contains listing decisions for the end-use discussed above. EPA notes that there may be other legal obligations pertaining to the manufacture, use, handling, and disposal of the proposed refrigerants that are not included in the information listed in the tables (

e.g.,

the CAA section 608(c)(2) venting prohibition, or DOT requirements for transport of flammable gases). Flammable refrigerants being recovered or otherwise disposed of from IPR equipment are likely to be hazardous waste under RCRA (see 40 CFR parts 260 through 270).

1. Background on Industrial Process Refrigeration

IPR systems cool process streams in industrial applications, for example, machining of metal products, fermentation of beer, or operation of hydraulic circuits. The choice of substitute for specific applications depends on ambient and required operating temperatures and pressures. It is EPA's understanding that this type of equipment generally falls under the scope of UL 60335-2-89, “Requirements for Commercial Refrigerating Appliances and Ice-Makers with an Incorporated or Remote Refrigerant Unit or Motor-Compressor.” In contrast, industrial process air conditioning primarily cools people, may also cool processes, and follows a different UL standard. In addition, sometimes chillers are used primarily to cool process streams, rather than for comfort cooling. EPA describes this application as “chillers in IPR.”

2. What are the ASHRAE classifications for refrigerant flammability?

ASHRAE 34-2022 categorizes the refrigerants proposed for IPR in this section as being in the A2L Safety Group. See section II.A.2 for further discussion on ASHRAE classifications.

3. What are HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A and how do they compare to other refrigerants in the same end-use?

See section II.A.3 for further discussion on the environmental, flammability, toxicity, and exposure information for these refrigerants.

The redacted submission and supporting documentation for HFC-32, HFO-1234yf, HFO-1234ze(E), blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A is provided in the docket for this proposed rule (EPA-HQ-OAR-2023-0043) at

https://www.regulations.gov.

EPA performed risk screening assessments to examine the health and environmental risks of these substitutes. These risk screens are available in the docket for this proposed rule.

48 49 50 51 52 53 54 55 56

48

ICF, 2023r. Risk Screen on Substitutes in Industrial Process Refrigeration (New Equipment); Substitute: HFC-32 (Difluoromethane).

49

ICF, 2023s. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: HFO-1234yf.

50

ICF, 2023t. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: HFO-1234ze(E) (Solstice® ze, Solstice® 1234ze).

51

ICF, 2023u. Risk Screen on Substitutes in Industrial Process Refrigeration and Cold Storage Warehouses (New Equipment); Substitute: R-454A (Opteon® XL40).

52

ICF, 2023v. Risk Screen on Substitutes in Industrial Process Refrigeration (New Equipment); Substitute: R-454B (Opteon® XL41).

53

ICF, 2023w. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: R-454C (Opteon

TM

XL20).

54

ICF, 2023x. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: R-455A (Solstice® L40X).

55

ICF, 2023y. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: R-457A.

56

ICF, 2023z. Risk Screen on Substitutes in Industrial Process Refrigeration, Cold Storage Warehouses, and Ice Skating Rinks (New Equipment); Substitute: R-516A.

Comparison to other substitutes in this end-use:

HFC-32, HFO-1234yf, HFO-1234ze(E), and blends R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A all have an ODP of zero, comparable to or lower than some of the acceptable substitutes in new IPR equipment, such as HFC-134a, R-410A, and R-513A with ODPs of zero and hydrochlorofluoroolefin (HCFO)-1233zd(E) with an ODP less than 0.0004.

57

57

WMO, 2018.

HFO-1234yf and HFO-1234ze(E) have GWPs less than four and less than six, respectively, comparable to that of R-290 and ammonia with GWPs of 3 and zero. R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A have GWPs ranging from 140 to 470, higher than some of the acceptable substitutes for new IPR equipment, including R-290 and ammonia, and lower than those of other substitutes such as R-450A and R-513A with GWPs of about 600 and 630. HFC-32 has a GWP of 675, which is higher than some of the acceptable substitutes including R-290, R-450A, and R-513A; however, the GWP of HFC-32 is lower than those of R-410A and R-404A, with GWPs of approximately 2,090 to 3,920, which are refrigerant that have typically been employed in chillers for IPR.

Information regarding the toxicity of other available alternatives is provided in the previous listing decisions for new IPR (

https://www.epa.gov/snap/substitutes-industrial-process-refrigeration

). Toxicity risks of use, determined by the likelihood of exceeding the exposure limits of HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A in this end-use, is evaluated in the risk screens referenced above. The toxicity risks of using HFO-1234yf and the refrigerant blends in IPR, and of using all nine refrigerants in chillers for IPR, are comparable to or lower than toxicity risks of other available substitutes in the same end-use. Toxicity risks of the proposed refrigerants can be mitigated by use consistent with ASHRAE 15-2022 and other industry standards, recommendations in the manufacturers' SDS, and other safety precautions common in the refrigeration and AC industry.

The flammability risks with HFC-32, HFO-1234yf, HFO-1234ze(E), R-454A, R-454B, R-454C, R-455A, R-457A, and R-516A in the IPR end-use, determined by the likelihood of exceeding their respective lower flammability limits, are evaluated in the risk screens referenced in this section above. While these refrigerants may pose greater flammability risk than available substitutes in the new IPR end-use that are non-flammable, this risk can be mitigated by use consistent with ASHRAE 15-2022 and UL 60335-2-89, required by our proposed use conditions, as well as recommendations in the manufacturers' SDS and other safety precautions common in the refrigeration and AC industry. We also note that other acceptable refrigerants in the IPR end-use have higher flammability and are classified in the A3 Safety Group, such as R-290, butane (R-600), and propylene (R-1270). EPA is proposing use conditions to reduce the potential risk associated with the flammability of the proposed alternatives so that they will not pose significantly greater risk than other acceptable substitutes in the new IPR end-use.

In addition, the proposed substitutes have lower GWPs than most other available alternatives for the same uses. The proposed refrigerants may provide additional lower-GWP options for situations where other refrigerants with lower GWPs are not viable, such as situations where sparks or flame might occur such that HCs are not suitable for use, or for systems with remote compressors or equipment requiring larger charge sizes, where refrigerant leaks are more likely to create greater flammability risk. Given the wide range of applications for IPR, not all refrigerants listed as acceptable under SNAP will be suitable for the range of equipment in the IPR end-use. To provide additional options to ensure the availability of substitutes for the full range of IPR equipment with lower GWP and, therefore, lower overall risk to human health and the environment, EPA is proposing the listings for HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A as acceptable, subject to use conditions, for use in IPR.

EPA is also proposing to list the refrigerants HFC-32 and R-454B with a use condition restricting their use to chillers in IPR. These refrigerants have higher GWPs than the other refrigerants EPA is proposing to list as acceptable, subject to use conditions; lower GWPs than many currently listed acceptable substitutes for IPR that are commonly in use; and lower flammability than HC refrigerants currently listed as acceptable in IPR. The Agency expects that these refrigerants may provide additional, lower-GWP options for chillers for IPR, where greater volumetric capacity and higher operating pressures may be required to operate properly than for other types of IPR equipment (

e.g.,

direct expansion systems), to address applications where other substitutes with lower GWPs may not be technically feasible.

EPA is also proposing to list the refrigerant R-454A with a use condition that this substitute may only be used either in chillers for IPR, in equipment with a refrigerant charge capacity less than 200 pounds, or in the high temperature side of a cascade system. This refrigerant may provide additional, lower-GWP options for chillers for IPR, where greater volumetric capacity and higher operating pressures may be required to operate properly than for other types of IPR equipment. R-454A may also address the additional challenges for finding lower GWP refrigerants with higher capacity for ice skating rinks with moderate charge sizes and for cascade systems, EPA is proposing to list R-454A as acceptable, subject to use conditions, for use in new ice skating rinks with a charge size capacity less than 200 pounds or for use

in the high-temperature side of a cascade system.

4. Why is EPA proposing these specific use conditions?

The use conditions identified in the proposed listings above for all nine refrigerants are explained in section II.H.1 in greater detail.

EPA is proposing the use condition for HFC-32 and R-454B restricting their use to chillers for IPR because these substitutes have higher GWPs than many of the available substitutes in IPR (

e.g.,

HCs, HFOs); however, because chillers may require greater volumetric capacity than other types of IPR equipment (

e.g.,

DX systems), EPA is proposing to list these two additional refrigerants to provide additional options and to address a broader range of equipment and applications. EPA also is proposing a use condition for R-454A that would allow its use in chillers for IPR, as well as other certain other applications, as described below in this section. In addition, the Agency previously listed HFC-32, R-454A, and R-454B as acceptable, subject to use conditions, in centrifugal and positive displacement chillers for comfort cooling in SNAP Rule 25. EPA is proposing to list the same refrigerants the same way for the same type of equipment (chillers) because of similar technical issues, such as volumetric capacity and operating pressure, which restrict the technical viability of alternatives for some applications.

EPA is proposing to list R-454A as acceptable, subject to use conditions, in IPR with a use condition that this substitute may only be used in chillers for IPR, in equipment with a refrigerant charge capacity less than 200 pounds or in the high-temperature side of a cascade system. EPA is proposing to allow use of R-454A for use in chillers for IPR for the same reasons as above for HFC-32 and R-454B. The Agency is also proposing this use condition to allow use of R-454A less broadly than for the refrigerants HFO-1234yf, HFO-1234ze(E), R-454C, R-455A, R-457A, and R-516A because its GWP is higher than those other proposed listings for non-chiller IPR equipment (that has a GWP of about 240, compared to less than four to 150). EPA's understanding is that, in addition to the technical constraints for refrigerant in chillers, there are two more situations where use of refrigerants is likely to be more constrained, and thus, additional refrigerant options may be helpful. The first of those situations is in what industry standard ASHRAE 15-2022 identifies as a refrigerating system having a “high probability” that leaked refrigerant from a failed connection, seal, or component could enter an occupied area. An example of such a constraint is that ASHRAE 15-2022 and UL 60335-2-89 effectively set charge limits for A2L refrigerants to less than 200 pounds for applications inside an occupied space where people might be located. In contrast, larger charge sizes could be used in “low-probability” locations where the general public is unlikely to come in contact with the refrigerant, such as systems used outdoors or in a machinery room with access restricted to facility employees. Where the general public is unlikely to come into contact with any leaked refrigerant, such as where charge sizes of 200 pounds or more of A2L refrigerant would be allowed under the use conditions incorporating UL 60335-2-89 and ASHRAE 15-2022, there would be fewer space constraints and greater flexibility in equipment design, so refrigeration system designers can accommodate a narrower set of substitutes. Conversely, where people are more likely to come into contact with any leaked refrigerant in an interior space, refrigerant charge capacities of a system would be less than 200 pounds; there would be more space constraints, less flexibility in equipment design, and potentially stricter code requirements, leading to a need for more refrigerant options. Allowing the additional option of R-424A for non-chiller IPR equipment with smaller refrigerant charges would enable the use of a wider set of available substitutes to manage safety (in particular, flammability and toxicity), as well as allowing more options to achieve adequate performance where there may be more constraints. Therefore, EPA is proposing to list R-454A as acceptable, subject to use conditions, only for non-chiller IPR equipment with a refrigerant charge capacity less than 200 pounds.

EPA is also proposing to list R-454A as acceptable, subject to use conditions, for use in the high temperature side of cascade systems used for non-chiller IPR equipment. As discussed above in section II.A.1, “Background on retail food refrigeration,” each system of a cascade system uses a different refrigerant that is most suitable for the given temperature range. Higher temperature systems, or the “high temperature side,” have typically used HFCs as a refrigerant; however, it is technologically achievable and has become more common to use ammonia in the high temperature side. For lower temperature systems, or the “low temperature side” of the cascade system, low boiling refrigerants such as R-744 can be used. Considerations for the choice of refrigerant on the high or low temperature side of cascade systems are influenced by many factors including, but not limited to, a refrigerant's toxicity and flammability, its temperature glide, and its suitability to lower temperature applications. EPA understands that use of flammable or toxic refrigerants, such as ammonia, on the high temperature side of a cascade may be limited in certain circumstances (

e.g.,

based on building codes and/or standards). EPA notes that there are a number of substitutes available for the low temperature side of the cascade system with GWPs lower than that of R-454A. Therefore, instead of proposing to list R-454A as acceptable, subject to narrowed use limits and subject to use conditions, EPA is proposing to list R-454A as acceptable, subject to use conditions, when it is used in the high temperature side of cascade systems; this would expand the refrigerant options that can comply with local building codes and industry safety standards while meeting the more challenging application of the high temperature side of a cascade system.

5. What additional information is EPA including in these proposed listings?

EPA is providing additional information related to these proposed listings. Since this additional information is not part of the regulatory decision under SNAP, these statements are not binding for use of the substitute under the SNAP program. See section II.H.2 for

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