MTBE in Gasoline: Clean Air and Drinking Water Issues

Congressional research reportJan 2, 2004

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MTBE in Gasoline:

Clean Air and Drinking Water Issues

Updated January 2, 2004

James E. McCarthy and Mary Tiemann

Specialists in Environmental Policy

Resources, Science, and Industry Division

Congressional Research Service ˜ The Library of Congress

MTBE in Gasoline:

Clean Air and Drinking Water Issues

Summary

Concern over water contamination caused by the gasoline additive methyl

tertiary butyl ether (MTBE) has raised questions concerning the desirability of using

the additive as a means of producing cleaner burning fuel. MTBE has been used by

most refiners to produce the reformulated gasoline (RFG) required under the Clean

Air Act in portions of 17 states and the District of Columbia. It is credited with

producing marked reductions in carbon monoxide emissions; RFG has also reduced

emissions of toxic substances and the volatile organic compounds that react with

other pollutants to form smog. Over the last few years, however, incidents of

drinking water contamination by MTBE, particularly in California, have raised

concerns and led to calls for restrictions on its use. In March 1999, Governor Davis

of California ordered a phase-out of MTBE use in the state by December 31, 2002

(later amended to December 31, 2003). Sixteen other states, including New York,

have subsequently enacted limits or phase-outs of the substance.

EPA responded to initial reports of water contamination by intensifying research

and focusing on the need to minimize leaks from underground fuel tanks. As reports

of contamination spread in 1998 and 1999, however, EPA’s position evolved. On

March 20, 2000, the Agency announced it was beginning the process of requiring a

reduction or phase-out of MTBE use under Section 6 of the Toxic Substances

Control Act. Because regulatory action could take years to complete, EPA urged

Congress to amend the Clean Air Act to provide specific authority to reduce or

eliminate use of the substance. Since then, the Senate Environment and Public

Works Committee has reported bills to provide such authority three times (S. 791 in

the 108th Congress). Language similar to S. 791 passed the Senate in its version of

H.R. 6, the comprehensive energy bill, July 31. The House approved somewhat

different MTBE provisions in its version of H.R. 6, April 11. The conference report

on the bill includes more extensive assistance for MTBE producers – some of it

controversial. The House adopted the conference report November 18. It awaits

Senate action.

If MTBE were removed from gasoline without amending the Clean Air Act,

there would be a need for refiners to use alternative sources of oxygen in RFG. The

potential alternatives are other forms of ether, or alcohols such as ethanol. Ethanol

is the most likely substitute, but it costs more to produce than MTBE, poses

challenges to the gasoline distribution system, and, some studies suggest that it

increases the risk of water contamination compared to non-oxygenated gasoline.

Also, in the short term, ethanol is unlikely to be available in sufficient quantity to

replace MTBE nationwide. Gasoline that meets the performance requirements for

RFG without using oxygenates at all can be made, but current law requires the use

of oxygenates in RFG.

The principal issues for Congress are whether MTBE use should be limited or

phased out and whether there should be a “safe harbor” from product liability

lawsuits for gasoline refiners and marketers who used MTBE.

Contents

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1

Air Quality Benefits Resulting from MTBE Use . . . . . . . . . . . . . . . . . . . . . . 4

Health-related Questions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Water Quality and Drinking Water Issues . . . . . . . . . . . . . . . . . . . . . . . . . . . 6

Occurrence of MTBE in Drinking Water . . . . . . . . . . . . . . . . . . . . . . . 7

Occurrence of MTBE in Ambient Ground Water . . . . . . . . . . . . . . . . . 8

EPA’s Responses to MTBE Occurrence in Water . . . . . . . . . . . . . . . . . . . . . 9

Safe Drinking Water Act Initiatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9

Underground Storage Tank Regulation . . . . . . . . . . . . . . . . . . . . . . . . 10

Blue Ribbon Panel on Oxygenates in Gasoline . . . . . . . . . . . . . . . . . . . . . . 11

Findings and Recommendations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11

Alternatives to MTBE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13

Current Statutory Authority to Control the Use of MTBE . . . . . . . . . . . . . 15

Legislation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17

California and Other State Initiatives . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19

NAFTA Arbitration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20

Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21

MTBE in Gasoline:

Clean Air and Drinking Water Issues

Introduction

This report provides background information concerning the gasoline additive

methyl tertiary butyl ether (MTBE), discusses air and water quality issues associated

with it, and reviews options available to congressional and other policy-makers

concerned about its continued use. It includes a discussion of legislation in the 108th

Congress.

Under the Clean Air Act Amendments of 1990, numerous areas with poor air

quality are required to add chemicals called “oxygenates” to gasoline as a means of

improving combustion and reducing emissions. The Act has two programs that

require the use of oxygenates, but the more significant of the two is the reformulated

gasoline (RFG) program, which took effect January 1, 1995.1 Under the reformulated

gasoline program, areas with “severe” or “extreme” ozone pollution (90 counties

with a combined population of 64.8 million) must use reformulated gasoline; areas

with less severe ozone pollution may opt into the program as well, and many have.

In all, portions of 17 states and the District of Columbia use reformulated gasoline

(see Table 1 and Figure 1); a little more than 30% of the gasoline sold in the United

States is RFG.

The law requires that RFG contain at least 2% oxygen by weight. Refiners can

meet this requirement by adding a number of ethers or alcohols, any of which contain

oxygen and other elements. Because these substances are not pure oxygen, the

amount used to obtain a 2% oxygen level is greater than 2% of the gasoline blend.

For example, MTBE is only 19% oxygen and, thus, RFG made with MTBE must

contain 11% MTBE by volume to meet the 2% requirement.

By far the most commonly used oxygenate is MTBE. In 1999, 87% of RFG

contained MTBE, a number since reduced to about 70%. MTBE has also been used

1

The requirements for reformulated gasoline (RFG), to reduce air toxics and the emissions

that contribute to smog formation, are found in Section 211(k) of the Clean Air Act.

Separate requirements for oxygenated fuel, to reduce carbon monoxide formation, are

contained in Section 211(m). Of the two programs, that for RFG has a much larger impact

on the composition of the nation’s gasoline, because RFG requirements are in effect yearround and apply to a larger percentage of the country. The Section 211(m) requirements,

by contrast are in effect during winter months only and affect a small percentage of the

nation’s gasoline. Ethanol is the primary oxygenate used in winter oxygenated fuels and

MTBE the primary oxygenate used in RFG, although either can be used in both fuels.

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Table 1

Areas Using Reformulated Gasoline (as of January 2003)

Mandatory RFG Areas*

Baltimore, MD

Chicago, IL (and portions of Indiana and Wisconsin)**

Hartford, CT

Houston, TX

Los Angeles, CA

Milwaukee, WI**

New York, NY (and portions of CT and NJ)

Philadelphia, PA (and portions of DE, MD, and NJ)

Sacramento, CA

San Diego, CA

San Joaquin Valley, CA

Southeast Desert, CA

Ventura County, CA

Opt-In RFG Areas***

Connecticut (entire state)

Dallas / Fort Worth, TX

Delaware (entire state)

District of Columbia

Kentucky portion of Cincinnati metropolitan area

Louisville, KY

Maryland (DC suburbs)

Massachusetts (entire state)

New Hampshire portion of Greater Boston

New Jersey (entire state)

New York (counties near New York City)

Rhode Island (entire state)

St. Louis, MO

Virginia (DC suburbs, Richmond, Norfolk - Virginia Beach - Newport News)

_______________

* RFG use required by the Clean Air Act.

** In the Chicago and Milwaukee areas, RFG is made with ethanol rather than

MTBE.

*** RFG use required by State Implementation Plan as a means of attaining the

ozone air quality standard. These “opt-in” areas may opt out of the program by

substituting other control measures achieving the necessary reductions in

emissions, but not before January 1, 2004.

Source: U.S. EPA

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since the late 1970s in non-reformulated gasoline, as an octane enhancer, at lower

concentrations. As a result, gasoline with MTBE has been used virtually everywhere

in the United States, whether or not an area has been subject to RFG requirements.

Air Quality Benefits Resulting from MTBE Use

State and local environmental agencies and EPA attribute marked improvements

in air quality to the use of fuels containing MTBE and other oxygenates, but the exact

role of oxygenates in achieving these improvements is subject to discussion. In Los

Angeles, which has had the worst air quality in the country, the use of reformulated

gasoline was credited with reducing ground-level ozone by 18% during the 1996

smog season, compared to weather-adjusted data for the same period in 1994 and

1995. Use of RFG also reduced the cancer risk associated with exposure to vehicle

emissions by 30 to 40%, according to the California EPA, largely because it uses less

benzene, a known human carcinogen.2

Whether the oxygenates themselves should be given credit for these

improvements has been the subject of debate, with the answer depending to some

extent on what one assumes would replace the oxygenates if they were removed.

Asked to look at the ozone-forming potential of different oxygenates used in

reformulated gasoline, a National Academy of Sciences panel concluded that “... the

addition of commonly available oxygenates to RFG is likely to have little air-quality

impact in terms of ozone reduction.”3 An EPA advisory panel, by contrast,

concluded that the use of oxygenates “appears to contribute to reduction of the use

of aromatics with related toxics and other air quality benefits.”4

Less controversy exists regarding oxygenates’ role in reducing carbon monoxide

emissions. Both EPA and an interagency group chaired by the White House Office

of Science and Technology Policy (OSTP) have reported improvements in carbon

monoxide (CO) levels due to the use of oxygenates. According to the June 1997

OSTP report, “analyses of ambient CO measurements in some cities with winter

oxygenated gasoline programs find a reduction in ambient CO concentrations of

about 10%.”5

2

See “Reformulated Fuels Help Curb Peak Ozone Levels in California,” Daily Environment

Report, November 6, 1996, pp. A-1 and A-2.

3

Committee on Ozone-Forming Potential of Reformulated Gasoline, National Research

Council, Ozone-Forming Potential of Reformulated Gasoline, May 1999, p. 5. The NAS

study concluded that other characteristics of RFG, notably “lowering the Reid Vapor

Pressure (RVP) of the fuel, which helps depress evaporative emissions of VOC [volatile

organic compounds], and lowering the concentration of sulfur in the fuel, which prevents

poisoning of a vehicle’s catalytic converter” result in a reduction of about 20% in VOC

emissions.

4

U.S. Environmental Protection Agency, Blue Ribbon Panel on Oxygenates in Gasoline,

Executive Summary and Recommendations, July 27, 1999, Appendix A. Available at

Internet website: [http://www.epa.gov/otaq/consumer/fuels/oxypanel/blueribb.htm].

5

Executive Office of the President, National Science and Technology Council, Interagency

Assessment of Oxygenated Fuels, Washington, D.C., June 1997, p. iv. Referred to hereafter

(continued...)

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EPA also “believes that the reductions estimated in air quality studies are

significant and that these reductions help to protect the public from the adverse health

effects associated with high levels of CO in the air.”6 The Agency based its

conclusions on both its own analysis and on a report prepared for two industry

groups. The latter, using hourly data for more than 300 monitoring sites gathered

over a 9-year period, concluded that use of oxygenated fuels was associated with a

14% reduction in ambient CO concentrations.7

Health-related Questions

The improvements in measured air quality have not come without questions.

In several cities, residents have complained of a variety of health effects from

exposure to MTBE/gasoline exhaust: headaches, dizziness, nausea, sore eyes, and

respiratory irritation. Some complaints have centered around the use of MTBE in

cold weather, two of the principal areas noting complaints being Alaska and

Milwaukee, Wisconsin.

The Interagency Task Force examined these complaints and concluded:

With regard to exposures ... experienced by the general population and motorists,

the limited epidemiological studies and controlled exposure studies conducted

to date do not support the contention that MTBE as used in the winter

oxygenated fuels program is causing significant increases over background in

acute symptoms or illnesses.8

Additional research is being conducted by EPA, universities, and others. Under the

authority of Section 211 of the Clean Air Act, EPA has requested that refiners

conduct a number of health effects studies on oxygenated, reformulated, and

conventional gasoline, which should provide additional information.

Much discussion has centered on whether MTBE has the potential to cause

cancer. Although there are no studies on the carcinogenicity of MTBE in humans,

several rodent studies have been done. Based on these animal studies (which looked

primarily at inhalation effects), EPA has concluded that MTBE poses a potential for

carcinogenicity to humans at high doses; however, because of uncertainties and

5

(...continued)

as the OSTP Report.(Executive summary and recommendations are available at Internet

website [http://wwwsd.cr.usgs.gov/nawqa/pubs/abstracts/zogorski/ostp.exec.sum.html]).

The report expressed some hesitation about its conclusions, particularly regarding the

impacts of MTBE in colder weather. It also noted methodological difficulties in identifying

statistically significant reductions smaller than 10%, and recommended additional research.

6

U.S. EPA Response to Interagency Assessment of Oxygenated Fuels, undated, p. 2.

7

Systems Applications International, Inc., for the Renewable Fuels Association and the

Oxygenated Fuels Association, Regression Modeling of Oxyfuel Effects on Ambient CO

Concentrations, Final Report, January 8, 1997, p. 1.

8

OSTP Report, p. vi. The report did suggest that “greater attention should be given to the

potential for increased symptoms reporting among workers exposed to high concentrations

of oxygenated fuels containing MTBE,” however.

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limitations in the data EPA has been unable to make a confident estimation of risk

at low exposure levels.9 In 1998, the International Agency for Research on Cancer

(IARC), the U.S. National Toxicology Program, and California’s Carcinogen

Identification Committee all determined not to list MTBE as a human carcinogen.

Regarding noncancer effects, another California advisory committee determined

that there was not clear scientific evidence to support listing MTBE as a toxic

substance affecting human development or reproduction. In reviewing available

research on both cancer and noncancer effects, these groups generally noted that

research gaps exist, and that the data were particularly limited on health effects

associated with MTBE ingestion.

For practical purposes, the interpretation of any health risks associated with the

addition of MTBE to gasoline requires a comparison to the health risks associated

with conventional gasoline. The Interagency Task Force, EPA, and some

environmental groups have all argued that current knowledge suggests that MTBE

is a less serious pollutant than the gasoline components it replaced. According to the

OSTP report, the cancer risk from exposure to MTBE is “substantially less than that

for benzene, a minor constituent of gasoline that is classified as a known human

carcinogen; and more than 100 times less than that for 1,3-butadiene, a carcinogenic

emission product of incomplete fuel combustion.”10

Water Quality and Drinking Water Issues

A major issue regarding the use of MTBE concerns its detection at low levels

in ground water in numerous locations nationwide and at elevated levels in some

municipal drinking water wells and reservoirs. MTBE is very soluble and, once

released, it moves through soil and into water more rapidly than other chemical

compounds present in gasoline. Once in ground water, it is slow to biodegrade and

is more persistent than other gasoline-related compounds. In surface water, it

dissipates more rapidly: studies show that most of it evaporates from the upper levels

of surface water in a few weeks, while it persists longer at greater depths.11

The available data indicate that the primary source of MTBE in ground water

has been petroleum releases from leaking underground storage tank (UST) systems.

Other significant sources include leaking above ground storage tanks, fuel pipelines,

refueling facilities, and accidental spills. The most significant source of MTBE in

9

U.S. Environmental Protection Agency. Drinking Water Advisory: Consumer Acceptability

Advice and Health Effects Analysis on Methyl Tertiary-Butyl Ether (MTBE). EPA-822-F-97009, December 1997. p. 1-2. This and other health effects information is available at

Internet website: [http://www.epa.gov/OST/drinking/mtbe.html]. (Also, see additional

drinking water risk discussion on p. 9 and 10 of this report.)

10

11

Ibid., p. vii.

Keller, Arturo, et al., Health and Environmental Assessment of MTBE, Report to the

Governor and Legislature of the State of California as Sponsored by SB 521, Volume I,

Summary and Recommendations, University of California, November 1998. p. 35.

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lakes and reservoirs appears to be exhaust from motorized watercraft, while smaller

sources include gasoline spills, runoff, and ground water flow.12

Occurrence of MTBE in Drinking Water. Available information on the

occurrence of MTBE in public drinking water supplies has increased substantially

over the past few years but has been somewhat limited geographically. Although a

number of serious contamination incidents have been reported, particularly in

California, the available data generally do not indicate a broad presence of MTBE in

drinking water supplies at levels of public health concern. However, as monitoring

has increased among the states, so has the number of public water systems and

private wells showing low-level detections of MTBE.

The most extensive MTBE monitoring data for drinking water are available for

California, where testing for MTBE was made mandatory for most public water

systems in February 1997. As of April 3, 2002, 2,957 systems had tested 9,905

sources of drinking water. MTBE was detected in 85 (0.9%) of these sources,

including 54 (0.6%) of 9,234 ground water sources and 31 (4.6%) of 671 surface

water sources. Overall, 53 (1.8%) of the 2,957 public water systems reported

detections of MTBE in at least 1 of their drinking water sources, and 13 (0.4%) of the

systems reported that a total of 21 (0.2%) sources of water had MTBE concentrations

exceeding California’s MTBE drinking water standard of 13 micrograms per liter

(:g/L).13

In 1998, the State of Maine tested nearly 800 public water supplies and 950

randomly selected private wells and found detectable levels of MTBE in 16% of the

public water supplies and 15.8% of the private wells. None of the public water supply

samples exceeded the state drinking water standard of 35 :g/L, while 1% of private

well samples contained MTBE concentrations above the standard. Roughly 94% of

public water supply samples showed MTBE levels that were either not detectable or

below 1 :g/L; the remaining 6% of samples were between 1 :g/L and 35 :g/L.14

Nationwide, the data on the presence of MTBE in drinking water have been

more limited. In July 1999, the EPA-appointed Blue Ribbon Panel on Oxygenates in

Gasoline reported that between 5% and 10% of drinking water supplies tested in high

oxygenate use areas show at least detectable amounts of MTBE, and that the vast

12

Keller. p. 33-34.

13

California Environmental Protection Agency. MTBE in California Drinking Water, April

3, 2002. Regular updates are available at Internet website:

[http://www.dhs.cahwnet.gov/ps/ddwem/chemicals/MTBE/mtbeindex.htm].

(Micrograms per liter(:g/L) are equivalent to parts per billion (ppb) for fresh water.)

14

Maine Department of Human Services, Department of Environmental Protection, and

Department of Conservation. The Presence of MTBE and Other Gasoline Compounds in

Maine’s Drinking Water, A Preliminary Report. October 13, 1998. 24 p. (Maine was not

required to use RFG but had done so voluntarily; the state opted out of the RFG program in

October 1998 because of concerns over MTBE contamination of ground water and drinking

water wells.)

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majority of these detections have been well below levels of public health concern,

with roughly 1% of detections exceeding 20 :g/L.15

More recent federal and state monitoring efforts have been advancing the

knowledge about the presence of MTBE in drinking water. Perhaps most notably,

the United States Geological Survey (USGS), in cooperation with EPA, recently

assessed the occurrence of MTBE and other volatile organic compounds (VOCs) in

public water supplies in 10 mid-Atlantic and Northeastern states where MTBE use

is common.16 The study analyzed water from 1,194 randomly selected community

water systems. The USGS reported that MTBE was detected in 8.9% of the tested

water systems and was strongly associated with areas where reformulated and/or

oxygenated (RFG/OXY) fuels are used. Fifteen percent of systems in RFG/OXY

areas reported detecting MTBE at concentrations of 1 :g/L or more, while 3% of

systems outside of RFG/OXY areas reported such detections. Most MTBE

concentrations ranged from 0.5 to 5 :g/L, and less than 1% of the systems reported

MTBE at levels equal to or exceeding 20 :g/L, the lower limit of EPA’s drinking

water advisory.17

Occurrence of MTBE in Ambient Ground Water. Looking at ground

water generally (not only drinking water wells), the data indicate that low-levels of

MTBE are found often. Nationally, the most comprehensive ground water research

has been conducted by the USGS through the National Water Quality Assessment

Program (NAWQA). USGS data for some 2,743 monitoring, observation, and water

supply wells in 42 states (from 1993-1998) showed MTBE present in about 5% (145)

of the wells, with MTBE levels exceeding 20 :g/L in 0.5% (12) of the wells. In all,

MTBE was detected in ground water in 22 of the 42 states. The USGS further

evaluated the occurrence data based on whether or not detections occurred in RFG

or winter oxyfuel program areas. The researchers reported that low concentrations of

MTBE were detected in 21% of ambient ground water samples in high MTBE-use

areas and in 2.3% of samples in low or no-MTBE use areas.18

MTBE has been detected most frequently in ground water associated with

leaking underground storage tank (UST) sites. The California Environmental

Protection Agency has estimated that, based on monitoring information available for

15

The Blue Ribbon Panel on Oxygenates in Gasoline. Executive Summary and

Recommendations. July 27, 1999. Summary and full report are available at Internet website:

[http://www.epa.gov/otaq/consumer/fuels/oxypanel/blueribb.htm].

16

For further information on MTBE research at the USGS, see Internet website:

[http://wwwsd.cr.usgs.gov/nawqa/vocns/].

17

Grady, Stephen J. and George D. Casey. MTBE and other VOCs in Drinking Water in the

Northeast and Mid-Atlantic Region. Available at Internet

website:[http://sd.water.usgs.gov/nawqa/pubs/abstracts/grady/Grady_iccssw_abs.pdf ].

MTBE was the second most frequently detected VOC in drinking water, after

trihalomethanes (disinfection byproducts) which were detected in 45% of systems tested.

Chloroform, the most frequently detected trihalomethane, was found in 39% of systems.

18

U.S. Geological Survey. Data summary submitted to the EPA Blue Ribbon Panel on the

Use of MTBE and Other Oxygenates in Gasoline. January 22, 1999. Available at Internet

website: [http://www.epa.gov/otaq/consumer/fuels/oxypanel/blueribb.htm#Presentations].

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these sites, MTBE can be expected to be found in shallow, unused ground water at

thousands of UST sites in the state, and often at high concentrations (in the parts per

million range).19 Moreover, a 1998 report by the Lawrence Livermore National

Laboratory found that MTBE was not significantly degrading in the monitoring

networks for these leaking UST sites.20

The picture nationwide may be similar. As of late 2000, 42 states had begun to

require testing for MTBE in ground water at leaking UST sites. In a September 2000

survey of state leaking underground storage tank (LUST) programs, 31 states

reported that MTBE was found in ground water at 40% or more of gasolinecontaminated sites in their states; 24 states reported MTBE at 60% to 100% of sites.21

EPA’s Responses to MTBE Occurrence in Water

Safe Drinking Water Act Initiatives. To address concerns raised by the

detection of MTBE in ground water and drinking water supplies, EPA has undertaken

a variety of activities. In December 1997, the Agency issued a drinking water

advisory for MTBE based on consumer acceptability (for taste and smell). EPA

issues drinking water advisories to provide information on contaminants in drinking

water that have not been regulated under the Safe Drinking Water Act (SDWA).22

Advisories are not enforceable, but provide guidance to water suppliers and other

interested parties regarding potential health effects or consumer acceptability. While

the MTBE advisory is not based on health effects, EPA notes that keeping MTBE

levels in the range of 20-40 :g/L or lower for consumer acceptability reasons would

also provide a large margin of safety from adverse health effects. Specifically, the

advisory states that,

[c]oncentrations in the range of 20 to 40 :g/L are about 20,000 to 100,000 (or

more) times lower than the range of exposure levels in which cancer or

noncancer effects were observed in rodent tests. This margin of exposure is in

the range of margins of exposure typically provided to protect against cancer

effects by the National Primary Drinking Water Standards under the Federal Safe

19

California Environmental Protection Agency, MTBE Briefing Paper, p. 17.

20

Happel, Anne, E. H. Beckenbach, and R. U. Halden. An Evaluation of MTBE Impacts

to California Groundwater Resources. Lawrence Livermore National Laboratory and the

University of California, Berkeley. June 11, 1998. p. iv.

21

New England Interstate Water Pollution Control Commission (NEIWPCC). Survey of

State Experiences with MTBE Contamination at LUST Sites (August 2000). Available at

Internet website: [http://www.neiwpcc.org/mtbe1.html]. The survey shows that some states

began requiring testing at LUST sites in the 1980s (Maine in 1986 and Minnesota in 1987)

while others recently began to do so (Kentucky in 2000 and Washington in 2001).

22

At least 7 states have set health-based drinking water standards for MTBE ranging from

13 parts per billion (ppb) to 240 ppb. (Parts per billion are equivalent to :g/L.) At least 5

states have adopted a secondary standard (based on aesthetic qualities, i.e., taste and odor),

ranging from 5 ppb to 70 ppb. At least 32 states have adopted a very wide range of ground

water cleanup levels; some are guidelines, some are enforceable, and some vary depending

on the use of ground water; some states apply these levels to ground-water cleanup at

leaking underground storage tank sites where ground water is used for drinking water.

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Drinking Water Act. This margin is greater than such standards typically

provided to protect against noncancer effects. Thus, protection of the water

source from unpleasant taste and odor as recommended will also protect

consumers from potential health effects.23

Additionally, EPA is taking steps that could lead to the development of an

enforceable drinking water standard for MTBE. In February 1998, EPA included

MTBE on a list of contaminants that are potential candidates for regulation under the

Safe Drinking Water Act. Compounds on the contaminant candidate list are

categorized as regulatory determination priorities, research priorities, or occurrence

priorities. Because of data gaps on MTBE health effects and occurrence, EPA placed

MTBE in the category of contaminants for which further occurrence data collection

and health effects research are priorities. Thus, while EPA has not selected MTBE

for regulation to date, the Agency is pursuing research to fill the existing data gaps

so that a regulatory determination may be made.

The Safe Drinking Water Act also directed EPA to publish a rule by August

1999, requiring public water systems to conduct monitoring for a list of unregulated

contaminants that may require regulation. EPA included MTBE in this rule and

directed large public water systems to begin monitoring for MTBE in January 2001.24

The occurrence data generated under the Unregulated Contaminant Monitoring

Rule, combined with the results of ongoing health effects studies, are intended to

provide information needed by EPA to make a regulatory determination for MTBE.

Under SDWA, the next round of regulatory determinations will be made in 2006.

EPA typically requires roughly three and one-half years to promulgate a drinking

water regulation; thus, the earliest EPA would be expected to issue a drinking water

regulation for MTBE is 2010.

Underground Storage Tank Regulation. A key EPA and state

contamination prevention effort involves implementing the underground storage tank

program established by the 1984 amendments to the Resource Conservation and

Recovery Act (RCRA). Under this program, EPA has set operating requirements and

technical standards for tank design and installation, leak detection, spill and overfill

control, corrective action, and tank closure. As of 1993, all tanks were required to

comply with leak detection regulations. Additionally, all tanks installed before

December 1988 (when standards for new tanks took effect) were required to be

upgraded, replaced or closed by December 22, 1998. Federal and state regulators

anticipate that as tank owners and operators comply with these requirements, the

number of petroleum and related MTBE leaks from UST systems should decline

significantly. Based on reporting by states, EPA estimates that, by the end of fiscal

year 2003, 79% of facilities were in “significant operational compliance” with the

1998 release prevention requirements and 72% of facilities were in significant

operational compliance with the release detection requirements. However, MTBE

23

24

EPA Drinking Water Advisory, p. 2.

64 Federal Register 50555, September 17, 1999. The law requires monitoring by all

large public water systems (serving more than 10,000 people) and requires a representative

sampling of smaller systems.

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has been detected at thousands of leaking tank sites, and this additive is proving more

difficult and costly to remediate than conventional gasoline. Moreover, many sites

have not been tested for MTBE. A key concern for states is that, as testing increases,

it is likely that the number and scope of needed cleanups may increase as well.

In 1986, Congress created a federal response program for cleaning up releases

from leaking petroleum USTs through the Superfund Amendments and

Reauthorization Act, which amended RCRA Subtitle I. These provisions created the

Leaking Underground Storage Tank (LUST) Trust Fund and authorized EPA and

states to use the Fund to clean up underground storage tank spills and leaks in cases

where tank owners or operators do not clean up sites. EPA and states use the annual

Trust Fund appropriation primarily to oversee and enforce corrective actions

performed by responsible parties. EPA and states also use Fund monies to conduct

corrective actions where no responsible party has been identified, where a responsible

party fails to comply with a cleanup order, or in the event of an emergency, and to

take cost recovery actions against parties. For FY2003, Congress provided $72.3

million for the program, and the President has requested $72.5 million for FY2004.25

Blue Ribbon Panel on Oxygenates in Gasoline

As part of its effort to gather information and focus research, in November 1998,

EPA established an independent Blue Ribbon Panel on Oxygenates in Gasoline to

review the broad range of issues posed by the use of MTBE and other oxygenates.

The panel was established under the auspices of the Clean Air Act Advisory

Committee, and its membership reflected a broad range of experts and stakeholders.26

The panel was directed to perform the following tasks:

examine the role of oxygenates in meeting the nation’s goal of clean

air,

! evaluate the efficiency of each of the available oxygenates in

providing clean air benefits and the existence of alternatives,

! assess the behavior of oxygenates in the environment,

! review any known health effects, and

! compare the cost of production and use, and each product’s

availability.

!

The panel also was directed to study the causes of ground water and drinking water

contamination from motor vehicle fuels, to explore prevention and cleanup

technologies for water and soil, and to make recommendations to EPA “on how to

ensure public health protection and continued improvement in both air and water

quality.”

25

For more information on the LUST program and related legislation, see CRS Report

RS21201, Leaking Underground Storage Tanks: Program Status and Issues.

26

A list of Blue Ribbon Panel members is provided, along with the panel report and related

materials, at Internet website: [http://www.epa.gov/oar/caaac/mtbe.html].

CRS-12

Findings and Recommendations. In releasing its recommendations July

27, 1999, the Blue Ribbon Panel stressed that “RFG has provided substantial

reductions in the emissions of a number of air pollutants from motor vehicles, most

notably volatile organic compounds (precursors of ozone), carbon monoxide, and

mobile-source air toxics (benzene, 1,3-butadiene, and others), in most cases resulting

in emissions reductions that exceed those required by law.”27

However, the panel noted water quality problems associated with MTBE

releases and made a number of recommendations. Specifically, the panel:

!

recommended that Congress act to remove the current Clean Air Act

requirement that 2% of RFG, by weight, consist of oxygen, in order

to ensure that adequate fuel supplies can be blended in a costeffective manner while reducing usage of MTBE;

!

recommended that the winter oxygenated fuels program be

continued;

!

agreed broadly that use of MTBE should be reduced substantially

(with some members supporting its complete phase out), and that

Congress should act to provide clear federal and state authority to

regulate and/or eliminate the use of MTBE and other gasoline

additives that threaten drinking water supplies;

!

recommended that EPA seek mechanisms to ensure that there is no

loss of current air quality benefits (i.e., no backsliding); and

!

recommended a comprehensive set of improvements to the nation’s

water protection programs, including over 20 specific actions to

enhance Underground Storage Tank, Safe Drinking Water, and

private well protection programs.

The panel’s numerous water protection recommendations addressed prevention,

treatment, and remediation. For example, the panel recommended that EPA work

with Congress to determine whether aboveground petroleum storage tanks (which

generally are not regulated) should be regulated; work to enhance state and local

efforts to protect lakes and reservoirs that serve as drinking water supplies by

restricting use of recreational water craft; and accelerate research for developing costeffective drinking water treatment and remediation technologies.

With regard to the recommendation to reduce substantially the use of MTBE,

the panel noted that accomplishing such a major change in gasoline supply without

27

Blue Ribbon Panel on Oxygenates in Gasoline, “Panel Calls for Action to Protect Water

Quality While Retaining Benefits from National Clean Burning Gas,” press release, July 27,

1999, p. 2. Available at [http://www.epa.gov/oms/consumer/fuels/oxypanel/blueribb.htm].

Regarding dissenting views, one member endorsed the water protection reforms but

disagreed with the recommendation to limit the use of MTBE, noting that the panel had not

identified any increased public health risk associated with MTBE use in gasoline; another

member supported maintaining the existing oxygenate standard for the air quality benefits.

CRS-13

disruptions to fuel supply and price would require up to 4 years lead time if the use

of MTBE were eliminated (or less if use was substantially reduced).

The panel also suggested that EPA and others should accelerate ongoing health

effects and environmental behavior research of other oxygenates and gasoline

components that would likely increase in use in the absence of MTBE.

Then-EPA Administrator Carol Browner concurred with the recommendation

of the Blue Ribbon Panel calling for a significant reduction in the use of MTBE. She

also stated her commitment to work with Congress for “a targeted legislative solution

that maintains our air quality gains and allows for the reduction of MTBE, while

preserving the important role of renewable fuels like ethanol.”28

On March 20, 2000, she announced that EPA would begin the process of issuing

regulations to reduce or phase out use of MTBE (discussed at greater length below

in the section on “Current Statutory Authority”). Recognizing that this process could

take several years to complete, she renewed her call for congressional action to

“amend the Clean Air Act to provide the authority to significantly reduce or eliminate

the use of MTBE,” to “ensure that air quality gains are not diminished,” and to

“replace the existing oxygen requirement contained in the Clean Air Act with a

renewable fuel standard for all gasoline.”29

In its few public statements on MTBE, the Bush Administration has not

indicated any change in the Clinton Administration’s policy, although EPA’s effort

to regulate MTBE using its existing authority has slowed noticeably. This

Administration, like the previous one, would defer to a legislative solution. As one

EPA official described it, “If the ethanol and oil industries can come to an agreement,

we’ll support it.”

Alternatives to MTBE

The major potential alternatives to MTBE are other oxygenates. This is so both

for practical and for regulatory reasons: at present, oxygenates are required by the

Clean Air Act, and, they possess several advantages, including high octane and the

ability to replace toxic components of conventional gasoline.

Oxygenates that could replace MTBE include ethers, such as ethyl tertiary butyl

ether (ETBE), and alcohols, such as ethanol. These other oxygenates may pose

health and environmental impacts, but inadequate data make it difficult to reach

definite conclusions. EPA’s Blue Ribbon Panel concluded:

The other ethers (e.g., ETBE, TAME, and DIPE) have been less widely used and

less widely studied than MTBE. To the extent that they have been studied, they

28

Statement by former EPA Administrator Carol Browner on Findings by the EPA’s Blue

Ribbon MTBE Panel, July 26, 1999, available on the Blue Ribbon Panel home page,

previously cited.

29

U.S. Environmental Protection Agency. “Clinton-Gore Administration Acts to Eliminate

MTBE, Boost Ethanol,” EPA Headquarters Press Release, March 20, 2000, pp. 7-8.

CRS-14

appear to have similar, but not identical, chemical and hydrogeologic

characteristics. The Panel recommends accelerated study of the health effects

and groundwater characteristics of these compounds before they are allowed to

be placed in widespread use.30

Ethanol and other alcohols are considered relatively innocuous on their own;

they generally do not persist in ground water and are readily biodegraded. However,

research suggests that the presence of ethanol in a gasoline plume can extend the

spread of benzene and other toxic constituents of gasoline through ground water.31

This is largely because ethanol is likely to be degraded preferentially by

microorganisms that would otherwise feed on other chemical components of gasoline

including benzene, toluene, ethylbenzene, and xylene (BTEX).

In announcing the phase-out of MTBE in his state, March 25, 1999, California’s

Governor Davis required three state agencies to conduct additional research on the

health and environmental impacts of ethanol, the most likely substitute. In reports

approved in January 2000, the agencies concluded that if ethanol were substituted for

MTBE, there would be “some benefits in terms of water contamination” and “no

substantial effects on public-health impacts of air pollution.”32

A more recent article, based on the California ethanol review, focused

specifically on the relative risks of ground-water contamination by spills of ethanolblended gasoline, MTBE-blended gasoline, and non-RFG gasoline. The authors

concluded that,

relative to risks associated with standard formulation gasoline, there is an

increase in the risk that wells will be contaminated by RFG using either MTBE

or ethanol as an oxygenate. (Emphasis added.) With ethanol, the risk of

contaminating wells decreases after approximately five years. However, the risk

continues to grow for MTBE because of the assumption that this chemical is not

degraded in the subsurface. The conservative approach used in this analysis,

including the low biodegradation rates and assumption that the gasoline source

areas are not remediated, results in an overstatement of the risks associated with

these additives to gasoline. Nevertheless, the relative trends do favor ethanol

when considering risk associated with RFG spills.33

The switch from MTBE to ethanol is not without technical problems as well.

Ethanol costs substantially more to produce than MTBE; it poses challenges to the

30

Blue Ribbon Panel Report, p. 8.

31

See, for example, “Ethanol-Blended RFG May Cause Small Hike in Gasoline Plume

Size,” Mobile Source Report, December 2, 1999, p. 11, or “Experts Charge Cal/EPA

Rushing Approval of Ethanol in RFG,” Inside Cal/EPA, January 14, 2000, p. 1.

32

California Air Resources Board, Water Resources Control Board, and Office of

Environmental Health Hazard Assessment. Health and Environmental Assessment of the

Use of Ethanol as a Fuel Oxygenate. Report to the California Environmental Policy Council

in Response to Executive Order D-5.-99. Dec. 1999. Volume 1, Executive summary. P. 1-22.

Report is available at Internet website: [http://www-erd.llnl.gov/ethanol/]).

33

Powers, Susan, et al. “Will Ethanol-Blended Gasoline Affect Groundwater Quality?”

Environmental Science & Technology. American Chemical Society. January 1, 2001. p 28A.

CRS-15

gasoline distribution system (it would separate from gasoline if transported long

distances by pipeline, so it must be mixed with non-oxygenated gasoline blendstock

close to the market in which it is to be sold); and, in the short term, it is unlikely to

be available in sufficient quantity to replace MTBE nationwide.34

Since late 1997, some refiners have discussed the possibility of making gasoline

that meets the performance requirements for RFG without using oxygenates. Tosco

and Chevron, two firms with large stakes in the California gasoline market, asked for

changes in the rules to allow the sale of RFG not meeting the oxygenate requirement

in late 1997. In October 1997, Tosco expressed concern about the growing evidence

of the potential for extensive MTBE contamination in asking the California Air

Resources Board to “take decisive action” to “begin to move away from MTBE.”35

Chevron, California’s largest refiner, followed suit, announcing that it “may be

possible to make a cleaner burning gasoline without oxygenates, and still reduce

emissions to the same extent achieved with current standards.”36 The company stated

its support for legislation allowing it to stop or reduce its use of oxygenates. These

statements were supported by the Western States Petroleum Association. The

American Petroleum Institute now also supports legislation to remove the RFG

oxygenate requirement, which was a key recommendation of the Blue Ribbon Panel.

Affected industries have not been united in seeking authority to replace MTBE,

however. The major producers of MTBE have not joined the efforts to promote

alternatives, and ethanol producers and agricultural interests (most ethanol is made

from corn) are concerned that removing the oxygenate requirement would negatively

affect the sales of their products. Nearly 10% of the nation’s corn crop is used to

produce ethanol. If MTBE use were reduced or phased out, but the oxygenate

requirement remained in effect, ethanol use would likely soar, increasing demand for

corn. Conversely, if the oxygenate requirement is removed by legislation, not only

would MTBE use decline, but so, likely, would demand for ethanol.

As a result, Members, Senators, and Governors from corn-growing states have

taken a keen interest in MTBE legislation. Unless their interests were addressed,

they would have posed a potent obstacle to its passage. Reflecting these concerns,

both the House and Senate versions of MTBE legislation in the 108th Congress

eliminated the oxygen requirement, but mandated a more than doubling of the use of

renewable fuels such as ethanol by 2012 or 2015. This provision appears to have

generated broad support for most provisions of the legislation.

Current Statutory Authority to Control the Use of MTBE

34

For additional information on ethanol, see CRS Report RL30369, Fuel Ethanol:

Background and Public Policy Issues.

35

Letter of Duane B. Bordvick, Vice President, Environmental and External Affairs, Tosco,

to John D. Dunlap III, Chairman, California Air Resources Board, October 17, 1997.

36

“Chevron Seeks Changes to Reformulated Gasolines,” Press Release, Chevron

Corporation Public Affairs Department, December 1, 1997.

CRS-16

Whether EPA has authority to take steps to regulate or ban MTBE use in the

absence of specific congressional authorization is a question many have raised as the

Agency and Congress consider their responses to MTBE contamination. In theory,

if the Agency determines that MTBE poses what it considers a significant threat to

air quality, water quality, or human health, it can take action to restrict or ban the

substance using existing authority under the Toxic Substances Control Act (TSCA).37

Until early 2000, based on its public statements, the Agency seemed unlikely to make

such a determination. In April 1998 testimony before a House Commerce

subcommittee, for example, EPA’s then Acting Assistant Administrator for Air and

Radiation stated: “One needs to be very cautious about initiating changes to the RFG

program that could upset the balance of previous agreements that have led to the

significant emissions reductions we are seeing today.”38 Instead, the Agency focused

attention on the need to prevent leaks from underground fuel storage tanks, which,

it argued, would address the major cause of drinking water contamination by MTBE.

On March 20, 2000, however, former EPA Administrator Browner announced

that the Agency would start a regulatory process “aimed at phasing out MTBE,”39

using Section 6 of TSCA. According to the Agency’s press release, EPA expected

to issue a proposed rule to ban or phase down MTBE within 6 months. As the

Agency noted, however, a TSCA rulemaking is procedurally burdensome and may

take “several years” to complete. To use the authority, the Agency will have to

conclude that MTBE poses an unreasonable risk to health or the environment. In the

27 years since TSCA was enacted, the Agency has successfully invoked this authority

against fewer than half a dozen classes of chemicals.

The first step in the TSCA rule-making process was the issuance of an Advance

Notice of Proposed Rulemaking (ANPRM) on March 24, 2000.40 The ANPRM

solicited the input of interested parties regarding EPA’s course of action, including:

!

whether some use of MTBE as a gasoline additive

should be allowed to continue,

!

how much lead time would be necessary to allow

refiners to eliminate MTBE from RFG or from all fuels

without unacceptable impacts on the price or supply of

fuel,

37

Under the Clean Air Act, EPA has authority to waive the RFG oxygenate requirement if

the oxygenate interferes with the attainment of an air quality standard; however, EPA has

no authority to waive the requirement for water quality reasons.

38

Statement of Richard D. Wilson, former Acting Assistant Administrator, Office of Air and

Radiation, U.S. EPA, in “Implementation of the Reformulated Gasoline Program in

California,” Hearing before the Subcommittee on Health and Environment, Committee on

Commerce, U.S. House of Representatives, April 22, 1998, Serial No. 105-94, p. 30.

39

U.S. Environmental Protection Agency. “Clinton-Gore Administration Acts to Eliminate

MTBE, Boost Ethanol,” EPA Headquarters Press Release, March 20, 2000, p. 2.

40

65 FR 16093, March 24, 2000.

CRS-17

!

whether EPA should eliminate or cap the use of any

other gasoline additives (e.g., other ethers) in addition

to MTBE, and

!

whether MTBE presents significantly greater risk to

public health and/or water quality than alternative

gasoline additives.

The Agency also requested additional information regarding releases of gasoline

containing MTBE, the extent of contamination of water resources by the substance,

remediation technologies, alternatives to MTBE and their potential impacts on health

and the environment, and the cost of limiting or phasing out MTBE over various time

frames.41 As of August 2003, the Agency was still preparing a proposed rule, but

Agency staff familiar with the process have described it as “basically on hold,”42 with

the Administration deferring to what they think will be congressional action.

In addition to TSCA authority, Section 303 of the Clean Air Act could possibly

have been invoked. Section 303 allows the Administrator to seek a restraining order

(and temporarily to issue such orders on his own authority) in cases where “a

pollution source or combination of sources ... is presenting an imminent and

substantial endangerment to public health or welfare, or the environment....” In

EPA’s assessment, however, studies to date suggest that MTBE is less toxic than

certain other gasoline components, such as benzene, so it might be difficult to justify

a finding of imminent and substantial endangerment.

Legislation

Legislation that could affect MTBE use has been introduced in every Congress

since the 104th, but until 2002, did not reach the floor of either chamber.43 In the

107th Congress, however, the Senate included MTBE provisions in its version of H.R.

4, the comprehensive energy bill that it passed April 25, 2002. The House included

authorization of funds to clean up MTBE leaks in its version of the bill, but did not

address MTBE use, the oxygenate requirement, or other issues. Senate and House

conferees did not reach agreement on the bill.

Relying heavily on the work of the 107th Congress, however, the 108th Congress

moved quickly to address MTBE and related issues. On April 11, 2003, the House

passed H.R. 6, a comprehensive energy bill. The Senate passed its version July 31,

and the conferees reported the bill (H.Rept. 108-375) on November 18. The House

adopted the conference report the same day, 246-180. In the Senate, a cloture vote

41

The specific request for information is found on pp. 16106-16107 of the March 24, 2000

Federal Register notice.

42

Personal communication, U.S. EPA, Office of Transportation and Air Quality, January

6, 2003.

43

Prior to the 107th Congress, the only legislation that had reached the floor of either house

was a Senate amendment to the FY2000 agricultural appropriations bill (S. 1233), offered

by Senator Boxer, expressing the sense of the Senate that use of MTBE should be phased

out. The Senate adopted the amendment on August 4, 1999.

CRS-18

on the bill, November 21, failed to achieve the 60 votes necessary to limit debate.

Thus, the bill remains on the Senate calendar for possible action in the second

session.

The conference version of the bill (in Title XV) would amend the Clean Air Act

to eliminate the requirement that RFG contain 2% oxygen and establish a new

requirement that an increasing amount of gasoline contain renewable fuels such as

ethanol. The bill would require that 3.1 billion gallons of renewable fuel be used in

2005, increasing to 5.0 billion gallons by 2012 (as compared to 2.1 billion gallons

used in 2002). It would authorize $2.0 billion to assist the conversion of merchant

MTBE production facilities to the production of other fuel additives, preserve the

reductions in emissions of toxic substances achieved by the RFG program, and

provide a “safe harbor” from product liability lawsuits for producers of MTBE and

renewable fuels.

The bill would ban the use of MTBE in motor vehicle fuel, except in states that

specifically authorize its use, not later than December 31, 2014. The ban has two

possible exceptions. First, EPA may allow MTBE in motor fuel up to 0.5 percent by

volume, in cases that the Administrator determines to be appropriate; and second, the

President may make a determination, not later than June 30, 2014, that the

restrictions on the use of MTBE shall not take place.

The safe harbor provision is among the most controversial provisions in the

entire bill. It would protect anyone in the product chain, from manufacturers down

to retailers, from liability for cleanup of MTBE and renewable fuels or for personal

injury or property damage based on the nature of the product (a legal approach that

has been successfully used in California to require refiners to shoulder liability for

MTBE cleanup). The safe harbor would be retroactive to September 5, 2003. Prior

to that date, five lawsuits had been filed. After that date, at least 150 suits were filed,

on behalf of 210 communities in 15 different states.

With liability for manufacturing and design defects ruled out, plaintiffs would

be forced to demonstrate negligence in the handling of such fuels in these and any

future cases, a more difficult legal standard to meet. As a result, drinking water

suppliers widely oppose the safe harbor provision and have expressed concern that

it could leave communities paying much of the cost for cleaning up contamination

caused by fuels containing MTBE or ethanol. Manufacturers counter that the

problem lies with leaking tanks, not with the fuels the tanks contain. They argue that

a product liability safe harbor provision is reasonable, given that the fuels are used

to meet federal fuel mandates.44

The legislation also addresses the issue of MTBE and other fuel leaks from

underground storage tanks. Title XV, Subtitle B, of the conference report would

make extensive amendments to Subtitle I of the Solid Waste Disposal Act (SWDA)

to enhance the leak prevention and enforcement provisions of the federal

underground storage tank regulatory program, and to broaden the allowable uses of

44

For more information on this issue, see CRS Report RS21676, The Safe-Harbor Provision

for Methyl Tertiary Butyl Ether (MTBE).

CRS-19

the Leaking Underground Storage Tank (LUST) Trust Fund. The conference report

essentially incorporates the language of H.R. 3335, the Underground Storage Tank

Compliance Act of 2003, which shares many similarities with Senate-passed S. 195.

The provisions would add new tank inspection and operator training requirements,

prohibit fuel delivery to ineligible tanks, and expand underground storage tank

requirements for federal facilities. The provisions also would authorize states to use

funds from the LUST Trust Fund to help tank owners or operators pay the costs of

remediating tank leaks in cases of economic hardship, and would allow EPA and

states to use LUST funds to enforce UST release prevention and detection

requirements. The conference report would authorize LUST Trust Fund

appropriations of $200 million annually, FY2004 through FY2008, specifically for

cleaning up leaks containing MTBE or other oxygenated fuel additives (e.g.,

ethanol), and another $200 million annually for the same years for responding to tank

leaks, generally.

(For a more detailed discussion of the MTBE and ethanol provisions of the

conference report, and a comparison of the conference, House, and Senate bills, see

CRS Report RL31912, Renewable Fuels and MTBE: Side-by-Side Comparison of

House and Senate Energy Bills and the Conference Report on H.R. 6.)

California and Other State Initiatives

Among the states, California has arguably been the most active in addressing

MTBE issues. Actions taken by the State Legislature and the Governor helped propel

the issue to national prominence. Legislation, signed October 8, 1997, required the

state to set standards for MTBE in drinking water, and required the University of

California to conduct a study of the health effects of MTBE and other oxygenates and

risks associated with their use. The UC report, which was issued in November 1998,

recommended a gradual phase-out of MTBE from gasoline in California.45 Based on

the report and on public hearings, Governor Davis issued a finding that “on balance,

there is a significant risk to the environment from using MTBE in gasoline in

California,” and required the state’s Energy Commission to develop a timetable for

the removal of MTBE from gasoline at the earliest possible date, but not later than

December 31, 2002.46 (This date was amended, in March 2002, to December 31,

2003.) The Governor also required the California Air Resources Board (CARB) to

make a formal request to U.S. EPA for a waiver from the requirement to use

oxygenates in reformulated gasoline and required three state agencies to conduct

additional research on the health and environmental impacts of ethanol, the most

likely substitute for MTBE.

The waiver request resulted in months of negotiation between EPA and CARB,

with EPA expressing skepticism that it had authority to grant a waiver under the

45

See Keller, Arturo, et al., Health & Environmental Assessment of MTBE, Report to the

Governor and Legislature of the State of California As Sponsored by SB 521, November

1998. Available on the web at [http://www.tsrtp.ucdavis.edu/mtberpt/homepage.html].

46

Governor Gray Davis, Executive Order D-5-99. The Executive Order and related

materials can be found at: [http://www.governor.ca.gov/state/govsite/gov_homepage.jsp].

(Search “MTBE”).

CRS-20

circumstances.47 The Clean Air Act authorizes waiver of the RFG oxygenate

requirement only if the Administrator determines that oxygenates would prevent or

interfere with the attainment of a National Ambient Air Quality Standard.48 More

than 2 years later, on June 12, 2001, the Agency finally denied California’s request.

Without a waiver, gasoline sold in ozone nonattainment areas in the state will be

required to contain another oxygenate (most likely, ethanol) when the MTBE ban

takes effect, unless Congress acts to change the oxygenate requirement. As of May

2003, about 80% of California’s motor fuels were reported to have phased out MTBE

in favor of ethanol.

Following California’s decision to phase-out MTBE, at least 16 other states

(Arizona, Colorado, Connecticut, Illinois, Indiana, Iowa, Kansas, Kentucky,

Michigan, Minnesota, Missouri, Nebraska, New York, Ohio, South Dakota, and

Washington) have acted to limit or phase out its use. The largest of these, New York,

set a date of January 1, 2004, to ban MTBE. Maine (which is not required to use

RFG, but had chosen to do so) also opted out of the RFG program in October 1998

as a result of concerns over MTBE contamination of ground water, and subsequently

substituted a low-volatility gasoline to provide similar reductions in emissions of

ozone-forming compounds, without requiring the use of oxygenates.

NAFTA Arbitration

Another MTBE issue that emerged in the wake of California’s decision to phase

out the use of MTBE in gasoline concerns the applicability of certain provisions in

the North American Free Trade Agreement (NAFTA). Chapter 11, Article 1110, of

the NAFTA requires the United States, Canada, and Mexico to treat each other’s

investors and investments in accordance with the principles set out in the Chapter.

It also allows these investors to submit to arbitration a claim that a NAFTA party has

breached Chapter 11 obligations and to recover damages from any such breach.

In June 1999, the Methanex Corporation, a Canadian company that produces

methanol in the United States and Canada, notified the U.S. Department of State of

its intent to institute an arbitration against the United States under the investor-state

dispute provisions of the NAFTA, claiming that the phase-out of MTBE ordered by

the Governor of California March 25, 1999 breaches U.S. NAFTA obligations

regarding fair and equitable treatment and expropriation of investments, entitling the

company to recover damages which it estimated at $970 million. (Methanol is a

major component of MTBE and is Methanex’s only product. The California market

for MTBE reportedly accounts for roughly 6% of global demand for methanol.) The

1999 Methanex claim asserted that California’s phase-out was motivated by a desire

to favor an MTBE competitor, ethanol, which is produced in the United States.

NAFTA, Chapter 11, requires the disputing investor to deliver a written notice

of its intent to the NAFTA country involved at least 90 days before the claim is

47

See statements of Robert Perciasepe, former Assistant Administrator for Air and

Radiation, U.S. EPA, at the May 6, 1999 House Commerce subcommittee hearing,

previously cited, pp. 47-52.

48

The waiver language is found in Section 211(k)(2)(B).

CRS-21

submitted to arbitration under the appropriate international arbitral rules. NAFTA

also requires 6 months to elapse “since the events giving rise to a claim” before the

investor may proceed with arbitration. Because no settlement was reached within

that timeframe, the matter proceeded to arbitration. In August 2002, an arbitration

panel ordered Methanex to file a fresh claim more specifically relating the actions of

California to the company’s manufacture of methanol. Methanex filed a new claim

in November 2002, and a hearing is scheduled for June, 2004.49

Conclusion

Controversy continues to surround the use of MTBE in gasoline. Research

conducted to date suggests that the air quality benefits of its use are substantial.

However, numerous detections of MTBE in ground and surface water, and

particularly in municipal and private drinking water wells, have raised significant

concerns about the use of this oxygenate. Research on MTBE and other oxygenates

is ongoing and should provide additional information to help advance the current

understanding of MTBE-related health and environmental issues and those of its

potential alternatives.

Legislation introduced in Congress initially focused on the limited issue of

MTBE use in California, where federal requirements have prevented refiners from

adopting a more flexible approach permitted by state regulations. Modifying the

federal requirements as they pertain to California has had substantial support among

the California congressional delegation. As MTBE has been detected in drinking

water wells in other parts of the country, and in surface waters in addition to

underground sources, broader legislation has been introduced. These bills emerged

in a context of ongoing activities aimed at reducing releases of petroleum, generally,

or MTBE, specifically. The effectiveness and sufficiency of these efforts (such as the

continued implementation of UST regulations and stricter emissions standards for

marine engines), combined with concerns and uncertainties about potential

replacements for MTBE, add complexity to the debate. Also, some lawmakers have

cautioned against acting precipitously to replace MTBE with other additives without

adequate research and consideration of potential adverse consequences. Others view

the debate over MTBE as an opportunity to encourage the greater use of ethanol, a

competing oxygenate generally made from corn.

Developments in the states, particularly California and the Northeast, have

driven reconsideration of the petroleum industry’s reliance on MTBE as the principal

means of meeting RFG requirements. These developments have generated continued

congressional interest in the issue. Differences remain over whether to ban MTBE,

whether to provide a product liability safe harbor for MTBE (or renewable fuels)

producers, and other issues that may delay or prevent enactment of legislation.

49

For more information, see CRS Report RL31638, International Investor Protection:

“Indirect Expropriation” Claims under NAFTA Chapter 11.

This is a copy of a public record, reproduced as it was published. It is not legal advice, and it may not be the version a court would rely on. Check the official source before you cite it.

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