# National Emission Standards for Hazardous Air Pollutants for Certain Source Categories; Final Rule ENVIRONMENTAL PROTECTION AGENCY

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URL: https://www.frixlaw.com/law-library/documents/fr%3A94-6043

## Record

- **Collection:** Federal Register
- **Document type:** Uncategorized Document
- **Published:** April 22, 1994

## Text

SUMMARY: On December 31, 1992, the EPA proposed to regulate the
emissions of certain organic hazardous air pollutants from synthetic
organic chemical manufacturing industry (SOCMI) production processes
which are part of major sources under section 112 of the Clean Air Act
as amended in 1990 (the Act). This Federal Register action announces
the EPA's final decisions on the rule which is referred to as the
hazardous organic NESHAP or the HON.
The HON requires sources to achieve emission limits reflecting the
application of the maximum achievable control technology consistent
with sections 112(d) and 112(h) of the Act. The rule regulates the
emissions of 112 of the organic chemicals identified in the Act's list
of 189 hazardous air pollutants at both new and existing SOCMI sources
and from equipment leaks at sources in certain polymer and resin
production processes, certain pesticide production processes, and
certain miscellaneous processes as described in the Source Category
Schedule for Standards (58 FR 63941). The EPA is also finalizing
Methods 304 and 305 with the standard. These methods can be used to
demonstrate compliance with control requirements for wastewater
streams.

EFFECTIVE DATE: April 22, 1994. The incorporation by reference of
certain publications in these standards is approved by the Director of
the Office of the Federal Register as of April 22, 1994. The
information collection requirements contained in 40 CFR Part 63
subparts F, G, H, and I have not been approved by the Office of
Management and Budget (OMB) and are not effective until OMB has
approved them.
See Supplementary Information section concerning judicial review.

ADDRESSES:
Dockets. The following dockets contain supporting information used
in developing the proposed rule. Docket Number A-90-19 contains
information specific to process vents, emissions averaging and general
information used to characterize emissions and control costs for the
industry; Docket A-90-20 contains information on equipment leaks;
Docket A-90-21 contains information on storage vessels; Docket A-90-22
contains information on transfer operations; and Docket A-90-23
contains information specific to wastewater operations. Supporting
information used in developing the negotiated standard for equipment
leaks is available in Docket Number A-89-10. These dockets are
available for public inspection and copying between 8 a.m. and 4 p.m.,
Monday through Friday, at the EPA's Air and Radiation Docket and
Information Center (formerly known as the Air Docket), room M1500, U.
S. Environmental Protection Agency, 401 M Street, SW., Washington, DC
20460. A reasonable fee may be charged for copying.

FOR FURTHER INFORMATION CONTACT: Dr. Janet S. Meyer, Standards
Development Branch, Emission Standards Division (MD-13), U. S.
Environmental Protection Agency, Office of Air Quality Planning and
Standards, Research Triangle Park, North Carolina 27711, telephone
number (919) 541-5299.

SUPPLEMENTARY INFORMATION: Under section 307(b)(1) of the Act, judicial
review of NESHAP is available only by filing a petition for review in
the United States Court of Appeals for the District of Columbia Circuit
within 60 days of today's publication of this rule. Under section
307(b)(2) of the Act, the requirements that are the subject of today's
notice may not be challenged later in civil or criminal proceedings
brought by the EPA to enforce these requirements.
The following outline is provided to aid in reading the preamble to
the standards.

I. Definitions, Acronyms, and Abbreviations
A. Definitions
B. Acronyms
C. Abbreviations
II. Background
A. Development of Hazardous Organic NESHAP and Public
Participation
B. Previous Federal Register Citations and Background Documents
C. Statutory Requirements for NESHAP
III. Summary of Promulgated Rule and Significant Changes
A. Summary of Subpart F
B. Summary of Subpart G
C. Summary of Subpart H
D. Summary of Subpart I
IV. Impacts
A. Environmental Impacts
B. Energy Impacts
C. Cost Impacts
D. Economic Impacts
V. Summary of Significant Comments and Associated Changes to the
Proposed Subparts F and G
A. Selection of Source Category and Source
B. Selection of Pollutants
C. Selection of the Rule
D. Emissions Averaging
E. Compliance, Recordkeeping, and Reporting
F. Coordination with Other Clean Air Act Requirements
G. Miscellaneous Technical Comments
VI. Summary of Significant Comments and Changes to Proposed Subpart
H
A. Applicability
B. Compliance Schedule
C. Selection of Requirements
D. Recordkeeping and Reporting
VII. Administrative requirements
A. Docket
B. Executive Order 12866
C. Paperwork Reduction Act
D. Regulatory Flexibility Act
E. Review

I. Definitions, Acronyms, and Abbreviations

The following lists of definitions, acronyms, and abbreviations for
units of measure are provided to aid in reading the preamble to the
final rule. Additional definitions are provided near the beginning of
subparts F, G, H, and I.

A. Definitions

The following definitions were developed for use in preparing and
describing the final rule.
Control device means any equipment used for recovering or oxidizing
organic hazardous air pollutant vapors. Such equipment includes, but is
not limited to, absorbers, carbon adsorbers, condensers, incinerators,
flares, boilers, and process heaters. For process vents, recovery
devices are not considered control devices.
Discount factor is a specified percentage used to reduce the value
of emission credits. A discount factor of 10 percent reduces 10 Mg of
potential emission credits to 9 Mg of actual emission credits that
could be used to balance an emissions debit. For regulatory purposes, a
10 percent discount factor is represented as 0.9 in credit estimation
equations.
Emissions averaging is a means of complying with subpart G of part
63 at existing sources. Emissions averaging allows a source to create
emission credits by reducing emissions from specific points to a level
below that required by subpart G. Those credits are used to offset
emission debits from points that are not controlled to the level
required by subpart G.
Emission credits are excess emission reductions above those
required by subpart G that are used to offset emission debits in
emissions averaging.
Emission debits are increased emissions that result when a source
elects not to control a Group 1 emission point to the level required by
subpart G.
Emission point means an individual process vent, storage vessel,
transfer rack, wastewater stream, or equipment leak.
Group 1 emission point means an individual process vent, storage
vessel, transfer rack, or wastewater stream that satisfies the
applicability criteria for the control requirements of subpart G.
Group 2 emission point means an individual process vent, storage
vessel, transfer rack, or wastewater stream that does not satisfy the
applicability criteria for the control requirements of subpart G.
Halogenated vent stream or halogenated stream means a vent stream
from a process vent or transfer operation determined to have a mass
emission rate of halogen atoms contained in organic compounds of 0.45
kilograms per hour or greater.
Hazardous Air Pollutant or HAP means any air pollutant listed under
section 112(b) of the Act.
Plant site means all contiguous or adjoining property that is under
common control, including properties that are separated only by a road
or other public right-of-way. Common control includes properties that
are owned, leased, or operated by the same entity, parent entity,
subsidiary, or any combination thereof.
Reference control technology means a device or devices that can be
used to comply with the control requirements in subpart G. Subpart G
specifies the reference control technologies for each kind of emission
point and establishes a control efficiency that the devices should
achieve when being used to comply with this rule.
Very volatile hazardous air pollutant or very volatile HAP means
one of the chemicals listed in table 8 of subpart G.
Volatile organic concentration or VO concentration refers to the
concentration of organic compounds (including both hazardous air
pollutant and nonhazardous air pollutant organic compounds) in a
wastewater stream that is measured by Method 25D, as found in 40 CFR
60, appendix A.
Volatile organic hazardous air pollutant concentration or VOHAP
concentration means the concentration of an individually-speciated
organic hazardous air pollutant in a wastewater stream or a residual
that is measured by proposed Method 305.
Waste management unit means any component, piece of equipment,
structure, or transport mechanism used in conveying, storing, treating,
or disposing of any waste, including a wastewater stream or a residual.
Wastewater tanks are an example of a waste management unit.
Wastewater means organic hazardous air pollutant-containing water,
raw material, intermediate, product, by- product, co-product, or waste
material that is discharged into an individual drain system and either:
(1) contains a concentration of at least 5 parts per million by
weight total organic hazardous air pollutant and has a flow rate of
0.02 liter per minute or greater; or
(2) contains a concentration of at least 10,000 parts per million
by weight total organic hazardous air pollutant at any flow rate.
Wastewater includes process wastewater and maintenance wastewater.

B. Acronyms

------------------------------------------------------------------------
Acronym Term
------------------------------------------------------------------------
Act....... Clean Air Act.
ALAPCO.... Association of Local Air Pollution Control Officers.
ASPEN..... Advanced system for process engineering.
BACT...... Best available control technology.
BAT....... Best available technology.
BD........ Butadiene.
BID....... Background information document.
BIF....... Boilers and industrial furnaces.
CEM....... Continuous emissions monitoring.
CFR....... Code of Federal Regulations.
CMA....... Chemical Manufacturers Association.
CMPU...... Chemical manufacturing process unit.
CO........ Carbon monoxide.
CTG....... Control techniques guideline.
CWA....... Clean Water Act.
DMS....... Dual mechanical seal.
DOT....... Department of Transportation.
DRE....... Destruction and removal efficiency.
EB/S...... Ethylbenzene/styrene.
EDC....... Ethylene dichloride.
EFR....... External floating roof.
EO........ Ethylene oxide.
E.O....... Executive Order.
EPA....... Environmental Protection Agency.
Fe........ Fraction emitted.
Fm........ Fraction measured.
FR........ Federal Register.
Fr........ Fraction removed.
FTIR...... Fourier transform infrared.
HAP....... Hazardous air pollutant.
HON....... Hazardous organic national emission standards for hazardous
air pollutants.
IFR....... Internal floating roof.
LDAR...... Leak detection and repair.
LAER...... Lowest achievable emission rate.
MACT...... Maximum achievable control technology.
MIBK...... Methyl isobutyl ketone.
MR........ Mass removal (actual).
NCS....... Notification of Compliance Status.
NESHAP.... National emission standards for hazardous air pollutants.
NOX....... Nitrogen oxides.
NPDES..... National Pollutant Discharge Elimination System.
NRDC...... Natural Resources Defense Council.
NSPS...... New source performance standards.
NSR....... New source review.
OCCM...... Office of Air Quality Planning and Standards Control Cost
Manual.
OCPSF..... Organic chemicals, plastics, and synthetic fibers.
OMB....... Office of Management and Budget.
OSHA...... Occupational Safety and Health Administration.
P.L....... Public Law.
PAV....... Product accumulator vessel.
POM....... Polycyclic organic matter.
POTW...... Publicly owned treatment works.
PRA....... Paperwork Reduction Act.
PRV....... Pressure relief valve.
PSD....... Prevention of significant deterioration.
QIP....... Quality improvement program.
R&D....... Research and development.
RCRA...... Resource Conservation and Recovery Act.
RCT....... Reference control technology.
RIA....... Regulatory Impact Analysis.
RMR....... Required mass removal.
SARA...... Superfund Amendment and Reauthorization Act.
SIP....... State Implementation Plan.
SMS....... Single mechanical seal.
SOCMI..... Synthetic organic chemical manufacturing industry.
STAPPA.... State and Territorial Air Pollution Program Administrators.
TAC....... Total annual cost.
TACB...... Texas Air Control Board.
TCI....... Total capital investment.
THC....... Total hydrocarbon.
TIC....... Total industry control.
TOC....... Total organic compound.
TRE....... Total resource effectiveness.
TRI....... Toxics release inventory.
TSDF...... Treatment, storage, and disposal facility.
VHAP...... Volatile hazardous air pollutant.
VO........ Volatile organics measurable by Method 25D.
VOC....... Volatile organic compound.
VOHAP..... Volatile organic hazardous air pollutant.
------------------------------------------------------------------------

C. Abbreviations

------------------------------------------------------------------------
Abbreviation Unit of measure
------------------------------------------------------------------------
bbl............. Barrel.
BOE............. Barrels of oil equivalent.
Btu............. British thermal unit.
Btu/kW-hr....... British thermal unit per kilowatt-hour.
deg.C.......... Degrees Celsius.
deg.F.......... Degrees Fahrenheit.
gal............. Gallon.
gpm............. Gallons per minute.
hr.............. Hour.
kg/hr........... Kilograms per hour.
kPa............. Kilopascals.
kW-hr/yr........ Kilowatt-hour per year.
l/hourm2 Liters per hour per square meter.
lpm............. Liters per minute.
gal............. Gallons.
m3.............. Cubic meters.
Mg.............. Megagrams.
mg.............. Milligrams.
mg/dscm......... Milligram per dry standard cubic meter.
MW.............. Megawatts.
ppb............. Parts per billion.
ppm............. Parts per million.
ppmv............ Parts per million by volume.
ppmw............ Parts per million by weight.
psia............ Pounds per square inch absolute.
scm/min......... Standard cubic meter per minute.
TJ.............. Terajoules.
yr.............. Year.
------------------------------------------------------------------------

II. Background

A. Development of Hazardous Organic NESHAP and Public Participation

On December 31, 1992, the EPA proposed to regulate, under section
112 of the Act, the emissions of 112 organic HAP's from SOCMI processes
which are part of major sources. Following publication of the proposed
rule, two public hearings were held and 339 written comments were
received regarding the proposed rule. The EPA considered all public
comments and made appropriate changes to the provisions. The final rule
issued today represents the EPA's final decisions for the MACT standard
for the SOCMI.
A background information document summarizing and responding to
legal comments and technical comments pertaining to this rulemaking may
be obtained from either: (1) The National Technical Information Service
(NTIS), 5285 Port Royal Road, Springfield, VA 22161, telephone (703)
487-4650, or (2) the EPA Technology Transfer Network (TTN). The TTN is
an electronic bulletin board system which is free, except for the
normal long distance charges. To access the HON BID: (1) Set software
to data bits: 8, N; stop bits: 1; (2) Use access number (919) 541-5742
for 1200, 2400, or 9600 bps modems [access problems should be directed
to the system operator at (919) 541-5384]; (3) Specify TTN Bulletin
Board: Clean Air Act Amendments; and (4) Select menu item: Recently
Signed Rules.
Please refer to ``Hazardous Air Pollutant Emissions from Process
Units in the Synthetic Organic Chemical Manufacturing Industry--
Background Information for Promulgated Standards,'' and specify volume
number(s).
Volume 2A: Comments on Process Vents, Storage Vessels,
Transfer Operations, and Equipment Leaks (EPA-453/R-94-003a);
Volume 2B: Comments on Wastewater (EPA-453/R-94-003b);
Volume 2C: Comments on Emissions Averaging (EPA-453/R-94-
003c);
Volume 2D: Comments on Applicability, National Impacts,
and Overlap with Other Rules (EPA-453/R-94-003d);
Volume 2E: Comments on Recordkeeping, Reporting,
Compliance, and Test Methods (EPA-453/R-94-003e); and
Volume 2F: Commenter Identification List (EPA-453/R-94-
003f).

B. Previous Federal Register Citations and Background Documents

Previous Federal Register Notices. Previous Federal Register
notices pertaining to this rulemaking are listed below in chronological
order. Since the complete Federal Register citation and dates are
listed here, they will not be repeated throughout this notice. Where
appropriate, an abbreviated descriptive title used to refer to the
document throughout this notice is also listed.
(1) ``National Emission Standards for Hazardous Air Pollutants for
Source Categories: Organic Hazardous Air Pollutants from the Synthetic
Organic Chemical Manufacturing Industry and Seven Other Processes;
Proposed rule and notice of public hearing,'' 57 FR 62608, December 31,
1992. Proposal notice.
(2) ``National Emission Standards for Hazardous Air Pollutants for
Source Categories: Organic Hazardous Air Pollutants from the Synthetic
Organic Chemical Manufacturing Industry and Seven Other Processes;
Correction,'' 58 FR 11667, February 26, 1993. Correction notice.
(3) ``National Emission Standards for Hazardous Air Pollutants for
Source Categories: Organic Hazardous Air Pollutants from the Synthetic
Organic Chemical Manufacturing Industry and Seven Other Processes;
Reopening of public comment period and correction to Regulatory
Flexibility Act certification,'' 58 FR 53478, October 15, 1993.
Supplemental notice.
Previous Background Documents. The following is a listing of
background documents pertaining to this rulemaking. The complete title,
EPA publication number, publication date, and National Technical
Information Service [NTIS] numbers are included. Where appropriate, an
abbreviated descriptive title used to refer to the document throughout
this notice is also listed.
(1) ``Hazardous Air Pollutant Emissions from Process Units in the
Synthetic Organic Chemical Manufacturing Industry--Background
Information for Proposed Standards, Volume 1A: National Impacts
Assessment,'' EPA-453/D-92-016a. November 1992. (NTIS Number PB93-
156552) (Docket item A-90-19: III-B-1). Proposal BID Volume 1A.
(2) ``Hazardous Air Pollutant Emissions from Process Units in the
Synthetic Organic Chemical Manufacturing Industry--Background
Information for Proposed Standards, Volume 1B: Control Technologies,''
EPA-453/D-92-016b. November 1992. (NTIS Number PB93-156560) (Docket
Item A-90-19: III-B-1). Proposal BID Volume 1B.
(3) ``Hazardous Air Pollutant Emissions from Process Units in the
Synthetic Organic Chemical Manufacturing Industry--Background
Information for Proposed Standards, Volume 1C: Model Emission
Sources,'' EPA-453/D-92-016c. November 1992. (NTIS Number PB93-156578)
(Docket item A-90-19: III-B-1). Proposal BID Volume 1C.

C. Statutory Requirements for NESHAP

Section 112 of the Act requires that the EPA establish regulations
setting emission standards for categories of sources of HAP emissions.
In addition, the Act sets out specific criteria for establishing a
minimum level of control, and criteria to be considered in evaluating
control options more stringent than the minimum control level. For most
of these rules, assessment and control of any remaining unacceptable
health risk is to occur 8 years after they are promulgated. However,
for the rules required to be promulgated in the first 2 years after
enactment, EPA is not required to conduct this assessment until 9 years
after promulgation.
Specifically, section 112(c), as amended, directs the Administrator
to develop a list of all categories or subcategories of major sources
and such categories or subcategories of area sources that meet the
requirements of section 112(c)(3), emitting any of the HAP's listed in
section 112(b). Section 112(d) directs the Administrator to promulgate
emission standards for each listed category or subcategory of HAP
sources. Such standards will be applicable to both new and existing
sources and shall require:

* * * the maximum degree of reduction in emissions of the
hazardous air pollutants subject to this section (including a
prohibition on such emissions, where achievable) that the
Administrator, taking into consideration the cost of achieving such
emission reduction, and any non-air quality health and environmental
impacts and energy requirements, determines is achievable for new
and existing sources in the category or subcategory to which such
emission standard applies * * *

42 U.S.C. 7412(d)(2).
The Amendments further provide that ``the maximum degree of
reduction in emissions that is deemed achievable'' shall be subject to
a ``floor'' which is determined differently for new and existing
sources. For new sources the standards set shall not be any less
stringent than ``the emission control that is achieved in practice by
the best controlled similar source.'' For existing sources, the
standards may not be less stringent than the average emission
limitation achieved by the best performing 12 percent of existing
sources in each category or subcategory of 30 or more sources. (Smaller
categories or subcategories are limited to the average of the best
performing five sources in the category or subcategory.)

III. Summary of Promulgated Rule and Significant Changes

This section of the notice summarizes the final rule and
significant changes made in response to public comment. The rationale
for specific provisions and changes is explained in sections V and VI.
The rule consists of four subparts in 40 CFR part 63. Subpart F
provides the applicability criteria for SOCMI sources, requires that
owners and operators of SOCMI sources comply with subparts G and H, and
specifies general recordkeeping and reporting requirements. The
specific control, monitoring, reporting, and recordkeeping requirements
are stated in subpart G for process vents, storage vessels, transfer
racks, and wastewater streams, and in subpart H for equipment leaks.
Subpart I provides the applicability criteria for the non-SOCMI
processes subject to the negotiated regulation for equipment leaks and
requires owners and operators to comply with subpart H.

A. Summary of Subpart F

Subpart F lists the HAP's regulated by this rule and specifies what
is included in the SOCMI source category and thus subject to the
requirements in subparts F, G, and H. In the final rule, the EPA has
revised the procedures for determining applicability to more clearly
indicate the boundaries between processes (i.e., where one process ends
and the next begins). In addition, subpart F presents definitions and
general information on compliance, reporting, and recordkeeping
requirements that are applicable for sources subject to subparts G and
H.
1. Regulated Pollutants
Subpart F lists 112 organic HAP's that the EPA has determined may
be emitted from SOCMI processes because they are either produced as a
product or used as a reactant. The emissions of these 112 organic
chemicals are regulated by subparts F, G, and H.
2. Definition of Source Category and Source
The rule applies to chemical manufacturing process units that are:
(1) Part of a major source as defined in section 112 of the Act; (2)
produce as a primary product a SOCMI chemical listed in table 1 of
subpart F; and (3) use as a reactant or manufacture as a product, by-
product, or co-product one or more of the organic HAP's listed in table
2 of subpart F. A chemical manufacturing process unit is subject to the
provisions of subparts F, G, and H only if all of the above three
conditions are satisfied. Table 1 of subpart F is a list of 385
chemicals which defines SOCMI products that may be produced by a HAP-
emitting process.
For the SOCMI source category, a source comprises all the SOCMI
chemical manufacturing process units that are subject to the rule and
are located at contiguous or adjoining properties under common control.
Subpart F defines the SOCMI source as the collection of process vents;
storage vessels; transfer racks; wastewater and the associated
treatment residuals; and pumps, compressors, agitators, pressure relief
devices, sampling connection systems, open-ended valves or lines,
valves, connectors, and instrumentation systems in the relevant
chemical manufacturing process units. As listed above, the first four
kinds of emission points in a SOCMI source are subject to subparts F
and G. However, SOCMI equipment leaks are subject to subparts F and H.
As such, a SOCMI source is subject to three of the HON's four subparts.
3. Other Provisions
Subpart F establishes the compliance dates for new and existing
sources and requires the source be properly operated and maintained at
all times. Sources are required to develop a start-up, shutdown, and
malfunction plan which includes a description of procedures for
managing wastewaters generated during maintenance. Monitoring of
cooling water is also required to detect leaks in heat exchange
equipment. If a leak is detected, the heat exchanger must be repaired
or taken out of service.
Procedures for obtaining permission to use an alternative means of
emission reduction are included in subpart F. The applicability of the
General Provisions in subpart A to sources subject to subparts F, G,
and H is clarified. General performance test requirements are
specified, including the provision that performance tests be conducted
under maximum representative operating conditions for the process. The
General Reporting and Recordkeeping Provisions of subpart F include the
requirement that required records and reports must be maintained for 5
years, and specify where reports must be sent. Reports can be submitted
on electronic media that are compatible with the system used by the
Administrator or the State permitting authority.

B. Summary of Subpart G

1. Overview
The MACT standard for SOCMI sources is expressed as an allowable
emissions level that is determined by means of an equation specified in
subpart G. The allowable emissions level is the sum of the emissions
from all the emission points in the source that would occur after the
required emission reductions are achieved for the emission points
meeting the HON's applicability criteria (Group 1 points) through use
of reference control technologies. Although controls are not required
for Group 2 emission points, both Group 1 emission points and Group 2
emission points are included in the equation defining the source's
allowable emissions level.
Though subpart G is structured as an allowable emissions level,
there is no need for owners or operators to actually calculate
emissions estimates for every emission point at the source. Actual
emissions estimates are only required for emission points that are
included in emissions averages.
The owner or operator can utilize two methods, or a combination of
them, to demonstrate compliance with the HON. The primary method that
owners or operators will use to determine compliance with the HON is
the application of the reference control technologies (or equivalent
controls) at Group 1 emission points. This compliance approach is
described in sections 2 through 5 below. Owners or operators may also
use emissions averaging to demonstrate compliance at a limited number
of emission points. Emissions averaging is described in section 6
below. Section 7 describes the HON's recordkeeping and reporting
provisions.
2. Process Vent Provisions
A process vent means a gas stream that is continuously discharged
during the operation of the unit from an air oxidation reactor, other
reactor, or distillation unit within a SOCMI chemical manufacturing
process unit. Process vents include vents from distillate receivers and
product separators. Process vents include gas streams that are
discharged directly to the atmosphere and gas streams discharged to the
atmosphere after diversion through a product recovery device. The rule
applies only to process vents that are associated with continuous (non-
batch) processes and emit process vent streams containing more than
0.005 weight-percent HAP.
A Group 1 process vent is defined as a process vent with a flow
rate greater than or equal to 0.005 scmm, an organic HAP concentration
greater than or equal to 50 ppmv, and a TRE index value less than or
equal to 1.0. The process vent provisions require the owner or operator
of a Group 1 process vent stream to:
(1) Reduce the emissions of organic HAP using a flare;
(2) Reduce emissions of organic HAP by 98 weight-percent or to a
concentration of 20 ppmv or less; or
(3) Achieve and maintain a TRE index above 1. Performance test
provisions are included for Group 1 process vents to verify that the
control device achieves the required performance.
The organic HAP reduction is based on the level of control achieved
by the reference control technology. Group 2 process vent streams with
TRE index values between 1.0 and 4.0 are required to monitor those
process vent streams to ensure those streams do not become Group 1,
which require control. The owner or operator can calculate a TRE index
value to determine whether each process vent is a Group 1 or Group 2
process vent or the owner or operator can elect to comply directly with
the control requirements without calculating the TRE index. The TRE
index value is determined after the final recovery device in the
process or prior to venting to the atmosphere. The TRE calculation
involves an emissions test or engineering assessment and use of the TRE
equations in section 63.115 of subpart G.
The rule encourages pollution prevention through product recovery
because an owner or operator of a Group 1 process vent may add recovery
devices or otherwise reduce emissions to the extent that the TRE
becomes greater than 1.0 and the Group 1 process vent becomes a Group 2
process vent.
Group 1 halogenated streams controlled using a combustion device
must vent the emissions from the combustor to an acid gas scrubber or
other device to limit emissions of halogens prior to venting to the
atmosphere. The control device must reduce the overall emissions of
hydrogen halides and halogens by 99 percent (95 percent for control
devices installed prior to the December 31, 1992 proposal) or reduce
the outlet mass emission rate of total hydrogen halides and halogens to
less than 0.45 kg/hr. Monitoring, reporting, and recordkeeping
provisions necessary to demonstrate compliance are also included in the
process vent provisions.
3. Storage Vessel Provisions
A storage vessel means a tank or other vessel associated with a
SOCMI chemical manufacturing process unit that stores a liquid
containing one or more of the organic HAP's listed in table 2 of
subpart F. The final rule specifies assignment procedures for
determining whether a storage vessel is associated with a SOCMI
chemical manufacturing process unit. The storage vessel provisions do
not apply to the following: (1) vessels permanently attached to motor
vehicles, (2) pressure vessels designed to operate in excess of 204.9
Kpa (29.7 psia), (3) vessels with capacities smaller than 38 m\3\
(10,000 gal), (4) wastewater tanks, and (5) vessels storing liquids
that contain organic HAP's only as impurities. An impurity is produced
coincidentally with another chemical substance and is processed, used,
or distributed with it.
The EPA is not taking final action at this time regarding
provisions for storage vessels of 76 m\3\ (20,000 gallons) to 151 m\3\
(40,000 gallons). The reason is that, through a separate Federal
Register notice, the EPA is soliciting additional public comment
regarding the appropriate interpretation of the language in section
112(d)(3)(A) of the Act concerning establishment of the MACT floor and
the effect of that interpretation on the control requirements for these
storage vessels. The EPA intends to evaluate the public comments
received in response to that action promptly and intends to proceed to
take final action on provisions for storage vessels of 76 m\3\ to 151
m\3\ within 90 days of the publication of the separate notice.
The storage provisions require that one of the following control
systems be applied to Group 1 storage vessels: (1) An internal floating
roof with proper seals and fittings; (2) an external floating roof with
proper seals and fittings; (3) an external floating roof converted to
an internal floating roof with proper seals and fittings; or (4) a
closed vent system with a 95-percent efficient control device. The
storage provisions give details on the types of seals and fittings
required. Monitoring and compliance provisions include periodic visual
inspections of vessels, roof seals, and fittings, as well as internal
inspections. If a closed vent system and control device is used, the
owner or operator must establish appropriate monitoring procedures.
Reports and records of inspections, repairs, and other information
necessary to determine compliance are also required by the storage
provisions. No controls are required for Group 2 storage vessels.
4. Transfer Operations Provisions
Transfer operations are defined as the loading of liquid products
that are on the list of organic HAP's in subpart F from a transfer rack
into a tank truck or railcar. Transfer rack means the collection of
loading arms and loading hoses at a single system that is assigned to a
SOCMI chemical manufacturing process unit and is used to fill tank
trucks and railcars with liquid products that are on the list of
organic HAP's in subpart F. Transfer rack includes the associated
pumps, meters, shutoff valves, relief valves, and other piping and
valves necessary to load tank trucks or railcars. The transfer
provisions do not apply to the loading of liquid organic HAP's at an
operating pressure in excess of 204.9 Kpa (29.7 psia); loading of
marine vessels; racks loading liquids that contain organic HAP's only
as impurities; or racks loading liquid organic HAP's if emissions are
returned to a storage vessel in a vapor balancing system.
The transfer provisions require control of Group 1 transfer racks
to achieve 98-percent organic HAP reduction or an outlet concentration
of 20 ppmv. Combustion devices or product recovery devices may be used
to comply with this requirement. Alternatively, vapor balancing systems
may be used.
The transfer provisions include design specifications for vapor
collection systems. Specifically, vapor collection systems are required
to route the organic vapors to a control device or to a vapor balancing
system and are required to operate without detectable emissions. In
addition, the provisions require that liquid organic HAP's be loaded
only into DOT-certified vehicles or vehicles that have been determined
to be vapor tight according to Method 27 of 40 CFR part 60, appendix A.
Group 1 halogenated streams controlled using a combustion device
must vent the emissions from the combustor to an acid gas scrubber or
other device to limit emissions of halogens, prior to venting to the
atmosphere. The control device must reduce the overall emissions of
hydrogen halides and halogens by 99 percent or reduce the outlet mass
emission rate of total hydrogen halides and halogens to less than 0.45
kg/hr.
Initial performance tests of control device efficiency are required
for racks loading at least 11.8 million liters per year. Design
evaluations are allowed in other cases. Monitoring, reporting, and
recordkeeping provisions are specified. Controls are not required for
Group 2 racks.
5. Wastewater Provisions
The final rule applies to any organic HAP-containing water, raw
material, intermediate, product, by-product, co- product, or waste
material that exits any chemical manufacturing process unit equipment
and has either (1) a total volatile organic HAP concentration of 5 ppmw
or greater and a flow rate of 0.02 lpm or greater; or (2) a total
volatile organic HAP concentration of 10,000 ppmw or greater at any
flow rate. ``Wastewater,'' as defined in Sec. 63.101 of subpart F,
encompasses both maintenance wastewater, which is regulated by subpart
F, and process wastewater, which is regulated by subpart G. The process
wastewater provisions in subpart G also apply to organic HAP-containing
residuals that are generated from the management and treatment of Group
1 wastewater streams. Examples of process wastewater streams include,
but are not limited to, wastewater streams exiting process unit
equipment (e.g., decanter water, such as condensed steam used in the
process), product tank drawdown, feed tank drawdown, and residuals
recovered from waste management units. Examples of maintenance
wastewater streams are those generated by descaling of heat exchanger
tubing bundles, cleaning of distillation column traps, and draining of
pumps into an individual drain system.
In the final rule, an owner or operator may determine the VOHAP
concentration and flow rate of a wastewater stream either (1) at the
point of generation; or (2) downstream of the point of generation. If
wastewater stream characteristics are determined downstream of the
point of generation, an owner or operator must make corrections for
losses by air emissions; reduction of VOHAP concentration or changes in
flow rate by mixing with other water or wastewater streams; and
reduction in flow rate or VOHAP concentration by treating or otherwise
handling the wastewater stream to remove or destroy HAP's. An owner or
operator must determine whether a wastewater stream is a Group 1 or
Group 2 wastewater stream by determining the flow rate and VOHAP
concentration for the point of generation by (1) sampling; (2) using
engineering knowledge; or (3) using pilot-scale or bench-scale test
data. An owner or operator who elects to use the process unit
alternative in Sec. 63.138(d) or the 95-percent biological treatment
option in Sec. 63.138(e) is not required to make a Group 1/Group 2
determination. Both the applicability determination and the Group 1/
Group 2 determination must reflect the wastewater characteristics
before losses due to volatilization, a concentration differential due
to dilution, or a change in VOHAP concentration or flow rate due to
treatment.
To provide greater flexibility to owners or operators, the EPA has
added to the final rule an additional option in Sec. 63.144 of subpart
G for determining applicability in lieu of a Group 1/Group 2
determination. This option allows an owner or operator to designate a
wastewater stream or mixture of wastewater streams to be a Group 1
wastewater stream without actually determining the flow rate and VOHAP
concentration for the point of generation. This option helps those
SOCMI plants that already have emission suppression systems in place
from the point of generation to a location downstream. Using this
option, an owner or operator can simply declare that a wastewater
stream or mixture of wastewater streams is a Group 1 wastewater stream
and that the emissions from the stream(s) are controlled from the point
of generation through treatment. An owner or operator is required to
determine the wastewater stream characteristics (i.e., VOHAP
concentration and flow rate) for the designated Group 1 wastewater
stream in order to establish the treatment requirements in Sec. 63.138.
Controls must be applied to Group 1 wastewater streams, unless the
source complies with the source-wide mass flow rate provisions of
Sec. 63.138(c)(5) or (c)(6) of subpart G; or implements process changes
that reduce emissions as specified in Sec. 63.138(c)(7) of subpart G.
Control requirements include (1) suppressing emissions from the point
of generation to the treatment device; (2) recycling the wastewater
stream or treating the wastewater stream to the required Fr values for
each HAP as listed in table 9 of subpart G; (3) recycling any residuals
or treating any residuals to destroy the total combined HAP mass flow
rate by 99 percent or more; and (4) controlling the air emissions
generated by treatment processes. While emission controls are not
required for Group 2 wastewater streams, owners or operators may opt to
include them in management and treatment options.
Suppression of emissions from the point of generation to the
treatment device will be achieved by using covers and enclosures and
closed vent systems to collect organic HAP vapors from the wastewater
and convey them to treatment devices. Air emissions routed through
closed-vent systems from covers, enclosures, and treatment processes
must be reduced by 95 percent for combustion or recovery devices; or to
a level of 20 ppmv for combustion devices.
The treatment requirements are designed to reduce the HAP content
in the wastewater prior to placement in units without air emissions
controls, and thus reduce the HAP emissions to the atmosphere. The
required Fr values in table 9 of subpart G are based on steam
stripping. The final rule provides several compliance options,
including percent reduction, effluent concentration limitations, and
mass removal.
For demonstrating compliance with the various requirements, owners
or operators have a choice of using a specified design, conducting
performance tests, or documenting engineering calculations. Appropriate
compliance, monitoring, reporting, and recordkeeping provisions are
included in the regulation.
6. Emissions Averaging
Under subpart G, only owners or operators of existing sources may
use emissions averaging. A change to the rule prohibits new sources
from using emissions averaging to comply with the rule. Any process
vents, storage vessels, or transfer racks in the source can be included
in an emissions average. However, only wastewater streams that are not
treated in a biological treatment unit are eligible for emissions
averaging. Equipment leaks are regulated under a separate subpart and
are also not eligible for emissions averaging.
a. Credit/Debit System. In general, the system for accumulating and
quantifying credits and debits remains the same as described at
proposal. The owner or operator must identify all the emission points
that would be included in an emissions average and estimate their
allowable and actual emissions using the reference efficiencies of the
reference control technologies for each kind of emission point.
For each Group 1 point, the allowable emissions level is the
emissions remaining after application of a reference control
technology. As a result, all Group 1 emission points that are not being
controlled with the reference control technology or a control measure
achieving an equivalent reduction are emitting more than their
allowable emissions. These points are generating emission ``debits.''
Emission debits are calculated by subtracting the amount of emissions
allowed by the standard for a given emission point from the amount of
actual emissions for that point. If a Group 1 emission point is
controlled by a device or a pollution prevention measure that does not
achieve the control level of the reference control technology, the
amount of emission debits will be based on the difference between the
actual control level being achieved and what the reference control
would have achieved. Equations for calculating debits are provided in
Sec. 63.150 of subpart G.
The owner or operator must control other emission points to a level
more stringent than what is required for that kind of point to generate
emission ``credits.'' Emission credits are calculated by subtracting
the amount of emissions that actually exist for a given emission point
from the amount of emissions that would be allowed under subpart G, and
then applying a 10-percent discount factor. If credits are generated
through the use of a pollution prevention measure, no discount factor
is applied. These provisions for a discount factor were added for the
final rule. Equations for calculating credits are also provided in
Sec. 63.150 of subpart G. To be in compliance, the owner or operator
must be able to show that the source's emission credits were greater
than or equal to its emission debits.
Credits may come from:
(1) Control of Group 1 emission points using technologies that the
EPA has rated as being more effective than the appropriate reference
control technology;
(2) Control of Group 2 emission points; and
(3) Pollution prevention projects that result in control levels
more stringent than what the standard requires for the relevant point
or points.
A reference control technology cannot be used to generate credits
beyond its assigned efficiency. For a new control technology or work
practice, either the EPA or the permit authority must determine its
control efficiency before it can be used to generate credits.
b. Compliance. The rule requires that emissions averaging plans be
reviewed as part of a source's Implementation Plan or operating permit
application. The controls in the averaging plan would then be cited in
a source's Implementation Plan or operating permit. Thus, to show
compliance using emissions averaging, the owner or operator must prove
both:
(1) The appropriate controls have been applied and maintained; and
(2) That the amount of emission credits and debits meet certain
quarterly and annual requirements.
c. Significant Changes. Significant changes were made to the
emissions averaging provision. One change is that the number of
emission points that can be included in an average has been limited to
no more than 20 points or 25 points if pollution prevention is used.
Another notable addition is the requirement that sources must
demonstrate that their emissions average will not result in greater
risk or hazard than compliance without averaging. Also, State or local
agencies have been granted the discretion to not include emissions
averaging in their implementation of the rule without having to go
through the Sec. 112(l) rule delegation process. Summaries of
significant comments and associated changes are discussed in section
V.D of this preamble. All comments regarding emissions averaging are
summarized and responded to in the BID, volume 2C.
7. Recordkeeping and Reporting
The rule requires sources complying with subpart G to keep records
and submit reports of information necessary to document compliance.
Records must be kept for 5 years. For emission points where continuous
monitoring is required, the final rule requires retention of hourly
average data values rather than the 15-minute average values specified
in the proposed rule. However, 15-minute values must be retained for
operating days when the daily average value of the monitored parameter
is outside the permitted range.
The following five types of reports must be submitted to the
Administrator: (1) Initial Notification, (2) Implementation Plan (if an
operating permit application has not been submitted), (3) Notification
of Compliance Status, (4) Periodic Reports, and (5) other reports. The
requirements for each of the five types of reports are summarized
below.
a. Initial Notification. The Initial Notification is due 120 days
after the date of promulgation for existing sources. For new sources
that have an initial start-up more than 90 days after promulgation, the
application for approval of construction or reconstruction required
under the General Provisions must be submitted in lieu of the Initial
Notification. The application is due as soon as practicable before
commencement of construction or reconstruction, or 90 days after
promulgation of subpart G, whichever is later. For new sources that
have an initial start-up prior to 90 days after promulgation, no
application for approval of construction is required and the Initial
Notification is due within 90 days after promulgation.
The Initial Notification must list the chemical manufacturing
process units that are subject to subpart G, and which provisions may
apply (e.g., process vents, transfer operations, storage vessels, and/
or wastewater provisions). A detailed identification of emission points
is not necessary for the Initial Notification. However, the
notification must include a statement of whether the source expects
that it can achieve compliance by the specified compliance date.
b. Implementation Plan. The Implementation Plan details how the
source plans to comply with subpart G. An Implementation Plan is
required only for sources that have not yet submitted an operating
permit application.
Existing sources must submit the Implementation Plan at different
times for emission points included in averages and emission points not
included in averages. The Implementation Plan for emission points
included in an average is due 18 months prior to the date of
compliance. The Implementation Plan for emission points not included in
an emissions average is due 12 months prior to the date of compliance.
For new sources that have an initial start-up more than 90 days after
promulgation, the Implementation Plan must be submitted with the
application for approval of construction or reconstruction. For new
sources that have an initial start-up prior to 90 days after
promulgation, the Implementation Plan is due within 90 days after
promulgation (at the same time as the Initial Notification). This
timing for new source submittals is slightly different than in the
proposed rule.
The information in the Implementation Plan should be incorporated
into the source's operating permit application. The terms and
conditions of the plan, as approved by the permitting authority, would
then be incorporated into the operating permit.
For points included in an emissions average, the Implementation
Plan must include: An identification of all points in the planned
average and whether they are Group 1 or Group 2 points; the specific
control technique or pollution prevention measure that will be applied
to each point; the control efficiency for each control used in the
average; the projected credit or debit generated by each point; and the
overall expected credits and debits. The Implementation Plan must also
state that the same types of testing, monitoring, reporting, and
recordkeeping that are required by the proposed rules for Group 1
points will be done for all points (both Group 1 and Group 2) included
in an emissions average.
For emission points not included in an average, the Implementation
Plan must include a list of emission points subject to the process
vents, storage vessels, transfer operations, and wastewater provisions
and whether each point is Group 1 or Group 2. The control technology or
method of compliance planned for each Group 1 point must be specified.
The plan must also state that appropriate testing, monitoring,
reporting, and recordkeeping will be done for each Group 1 point.
If an owner or operator wishes to monitor a unique parameter or use
a unique recordkeeping and reporting system for any emission point in
their source, the request, including a rationale, must be submitted
with the Implementation Plan, unless this information has already been
included in their operating permit application.
c. Notification of Compliance Status. The Notification of
Compliance Status must be submitted within 150 days after the source's
compliance date. It contains information on Group 1 points and all
points in emissions averages that is necessary to demonstrate that
compliance has been achieved, such as: The results of any performance
tests for process vents, transfer operations, and wastewater emission
points; one complete test report for each test method used for a
particular kind of emission point; TRE determinations for process
vents; design analyses for storage vessels and wastewater emission
points; site-specific ranges for each monitored parameter for each
emission point and the rationale for the range; and values of all
parameters used to calculate emission credits and debits for emissions
averaging.
d. Periodic Reports. Generally, Periodic Reports must be submitted
semiannually. However, there are two exceptions. Quarterly reports must
be submitted for all points included in an emissions average. In
addition, if monitoring results show that the parameter values for an
emission point are outside the established range for more than the
number of excused excursions, the implementing agency may request that
the owner or operator submit quarterly reports for that emission point.
After 1 year, semiannual reporting can be resumed, unless the
implementing agency requests continuation of quarterly reports.
All Periodic Reports must include information required to be
reported under the recordkeeping and reporting provisions for each
emission point. For emission points involved in emissions averages, the
report must include the results of the calculations of credits and
debits for each month and for the quarter. For continuously monitored
parameters, the data on those daily periods when the parameters are
outside their established ranges are included in the reports. Periodic
Reports must also include results of any performance tests conducted
during the reporting period and reports of equipment failures, leaks,
or improper work practices that are discovered during required
inspections. Additional information the source is required to report
under its operating permit or Implementation Plan would also be
described in Periodic Reports.
e. Other Reports. Other reports must be submitted as required by
the provisions for each kind of point. Other reports include: reports
of start-up, shutdown, and malfunction; notifications of inspections
for storage vessels; and information about sources requesting approval
for a nominal control efficiency for use in calculating credits for an
emissions average.

C. Summary of Subpart H

The applicability and provisions of subpart H generally have not
changed since proposal. Minor changes have been made, however, to
clarify the EPA's intent in some provisions and some revisions were
made to recordkeeping and reporting provisions to reduce unproductive
efforts. The following is a brief summary of the requirements of the
provisions in subpart H of the final rule.
1. Applicability
The standards would apply to equipment in organic HAP service 300
or more hours per year that is associated with a process subject to
subpart F or I of part 63. The provisions apply to valves, pumps,
connectors, compressors, pressure relief devices, open-ended valves or
lines, sampling connection systems, instrumentation systems, surge
control vessels, bottoms receivers, and agitators. The provisions of
subpart H also apply to closed vent systems and control devices used to
control emissions from any of the listed equipment.
For SOCMI processes, compliance with the provisions of subpart H is
phased in by type of chemical manufacturing process. Subpart F divides
the regulated processes into five distinct groups to which the
provisions of subpart H apply beginning 6 months after publication of
the final rule in the Federal Register. Thereafter, subpart H applies
to another group of processes every 3 months. Table 1 of subpart F
lists the group to which each chemical manufacturing process subject to
this rule is assigned. Processes listed in subpart I must comply with
the provisions of subpart H 6 months after publication of the final
standard in the Federal Register.
a. Pumps and Valves. The standard requires leak detection and
repair for pumps in light liquid service and for valves in gas or light
liquid service. Standards for both are implemented in three phases. The
first and second phases for both types of equipment consist of an LDAR
program, with lower leak definitions in the second phase. The LDAR
program involves a periodic check for organic vapor leaks with a
portable instrument; if leaks are found, they must be repaired within a
certain period of time. In the third phase, the periodic monitoring (a
work practice standard) is combined with a performance requirement for
an allowable percent leaking components.
The standard requires monthly monitoring of pumps using an
instrument and weekly visual inspections for indications of leaks. In
the first two phases of the valve standard, quarterly monitoring is
required. In phase three, semiannual or annual monitoring may be used
by process units with less than 1 percent and less than 0.5 percent
leaking valves, respectively.
In phase three, if the base performance levels for a type of
equipment are not achieved, owners or operators must, in the case of
pumps, enter into a QIP, and in the case of valves may either enter
into a QIP or implement monthly LDAR. The QIP is a concept that enables
plants exceeding the base performance levels to eventually achieve the
desired levels without incurring penalty or being in a noncompliance
status. As long as the requirements of the QIP are met, the plant is in
compliance. The basic QIP consists of information gathering,
determining superior performing technologies, and replacing poorer
performers with the superior technologies until the base performance
levels are achieved.
b. Connectors. The rule also requires leak detection and repair of
connectors in gas or light liquid service. The monitoring frequency for
connectors is determined by the percent leaking connectors in the
process unit and the consistency of performance. Process units that
have 0.5 percent or greater leaking connectors are required to monitor
all connectors annually. Units that have less than 0.5 percent may
monitor biannually and units that show less than 0.5 percent for two
monitoring cycles may monitor once every 4 years.
c. Other Equipment. Standards for compressors, open-ended lines,
pressure relief devices, and sampling connection systems remain
essentially unchanged from the proposed standard and other existing
equipment regulations (See 40 CFR part 61, subpart V). The provisions
for closed vent systems were revised to make them consistent with the
provisions in subpart G, and to clarify intent. Agitators must be
monitored for leaks or better designed systems, such as dual mechanical
seals, must be installed. Pumps, valves, connectors, and agitators in
heavy liquid service; instrumentation systems; and pressure relief
devices in liquid service are subject to instrument monitoring only if
evidence of a potential leak is found through sight, sound, or smell.
Instrumentation systems consist of smaller pipes and tubing that carry
samples of process fluids to be analyzed to determine process operating
conditions or systems for measurement of process conditions.
2. Delay of Repair
Under certain conditions delay of repair beyond the required 15
days may be acceptable. Examples of these situations include where: (1)
A piece of equipment cannot be repaired without a process unit
shutdown, (2) equipment is taken out of organic HAP service, (3)
emissions from repair will exceed emissions from delay of repair until
the next shutdown, and (4) equipment with better leak performance such
as pumps with SMS are replaced with DMS.
3. Alternative Standards
Specific alternative standards have been written for batch
processes and enclosed buildings. For batch processes, the owner or
operator can choose either to meet similar standards to those for
continuous processes, with monitoring frequency prorated to time in use
of organic HAP, or to periodically pressure test the entire system. For
enclosed buildings, the owner or operator may forego monitoring if the
building is kept under a negative pressure and emissions are routed
through a closed vent system to an approved control device.
4. Test Methods and Procedures
The standards require the use of Method 21 of appendix A of part 60
to detect leaks. Method 21 requires a portable organic vapor analyzer
to monitor for leaks from equipment in use. Test procedures using
either a gas or a liquid for pressure testing the batch system are
specified to detect for leaks.
5. Recordkeeping and Reporting
The standards require certain records to demonstrate compliance
with the standard and the records must be retained in a readily
accessible recordkeeping system. Subpart H requires that records be
maintained of equipment that would be subject to the standards, testing
associated with batch processes, design specifications of closed vent
systems and control devices, test results from performance tests, and
information required by equipment in QIP. Other recordkeeping
requirements are specified in Sec. 63.181 of subpart H.
Subpart H requires owners and operators to submit three types of
reports: (1) An Initial Notification; (2) a Notification of Compliance
Status; and (3) Periodic Reports. Owners or operators subject to the
requirements of subpart G as well as subpart H may submit one Initial
Notification for both requirements. Owners or operators of sources
subject to subparts I and H must submit an Initial Notification that
lists the units subject to subpart H and the location of the source.
The Notification of Compliance Status must be submitted within 90 days
after the compliance date for process units in the first group.
Thereafter, the owner or operator must submit a Periodic Report every 6
months that contains summary information on the leak detection and
repair program, changes to the process unit, changes in monitoring
frequency or monitoring alternatives, and/or initiation of a QIP. The
Periodic Report will also include any Notification of Compliance Status
for any process units that had compliance dates in the previous 6-month
period. Reports can be submitted on electronic media that are
compatible with the system used by the Administrator or the State
permitting authority.

D. Summary of Subpart I

In contrast to the sources in the SOCMI source category, sources in
the non-SOCMI processes would be covered by subparts I and H only. For
these processes, the source would include only pumps, compressors,
agitators, pressure relief devices, sampling connection systems, open-
ended valves or lines, valves, connectors, and instrumentation systems.
As explained in the Source Category Schedule for Standards (58 FR
63941), the EPA is considering regulating the other kinds of emission
points in these processes in future section 112 standards. The
processes subject to subpart H of the HON are included in 20 different
source categories or subsets of source categories. The exact
relationship of the HON's equipment leak processes to the source
categories listed for section 112 standards is specified in table 1 of
the Source Category Schedule for Standards (58 FR 63941).

IV. Impacts

This section presents the environmental, energy, cost, and economic
impacts resulting from the control of HAP emissions under the rule. It
is estimated that approximately 370 sources and 940 chemical
manufacturing processes would be required to apply controls by the
standards.
Impacts are presented relative to a baseline set at the level of
control in the absence of the rule. The estimates include the impacts
of applying control to: (1) Existing emission points and (2) additional
emission points from SOCMI process units that are expected to begin
operation over a 5-year period. Thus, the estimates represent annual
impacts occurring in the fifth year. Assuming a SOCMI-wide growth rate
of 3.5 percent each year over a 5-year period, national impacts for the
emission points that will be added in the first 5 years of the rule are
estimated to be 19 percent of total national impacts in the fifth year.

A. Environmental Impacts

Environmental impacts include the reduction of HAP and VOC
emissions, increases in other air pollutants, and decreases in water
pollution and solid waste resulting from the proposed rule.
Under the rule, it is estimated that emissions of HAP would be
reduced by 460,000 Mg/yr (510,000 tons/yr) and the emissions of VOC's
would be reduced by 950,000 Mg/yr (1,000,000 tons/yr) (see table 1).
Estimates of baseline emissions are presented in conjunction with
emissions reductions estimates to better illustrate the level of
control being achieved by the rule. Baseline emissions take into
account the current estimated level of emissions control, based on
State and Federal regulations, for each SOCMI emission point. As a
result, baseline emissions reflect the level of control that would be
achieved in the absence of the rule.
The baseline emission estimates in table 1 include the
extrapolation of estimates for well-characterized processes to account
for processes that could not be characterized. Consequently, the table
1 estimates contain considerable uncertainty and are presented only to
provide an estimate of the total nationwide impact of the rule.
Decisions were based on information from the well-characterized
processes only. As discussed in section III.B.3 of this preamble, the
EPA has deferred the final decision regarding control of medium-sized
storage vessels at existing sources. Therefore, emission reductions for
storage vessels shown in table 1, and consequently the total, may be
slightly overstated.
On average, SOCMI sources generate over twice as much VOC emissions
as HAP emissions. Although the intent of the rule is to reduce HAP
emissions, the control of HAP's also results in the control of non-HAP
VOC's. The control requirements of the HON would result in reduction of
88 percent of HAP emissions and 79 percent of VOC emissions beyond the
baseline control level.
There would be a very slight increase in emissions of CO and
NOX, relative to other sources of these pollutants, resulting from
the on-site combustion of fossil fuels as part of control device
operations. Additional emissions of NOX and CO (and other
pollutants) resulting from increased electricity demand are not
included in the impacts presented. Under the rule, estimates of
increased emissions of CO and NOX are 1,700 Mg/yr (1,900 tons/yr)
and 17,000 Mg/yr (19,000 tons/yr), respectively (see table 2). The
impacts for process vents and transfer operations are based on the
assumptions that incinerators or flares are used to combust emission
streams. To the extent noncombustion controls are used to achieve
compliance with the standards, the actual CO and NOX emissions
would be lower.
Impacts for water pollution and solid waste were judged to be
negligible and were not quantified as part of the impacts analysis. The
basis for judging these impacts to be negligible is discussed in
chapter 5.0 of proposal BID volume 1A.

B. Energy Impacts

Increases in energy use were estimated for steam, natural gas, and
electricity. These three types of energy were compared and totaled on a
BOE basis. Table 3 shows the estimated individual and total energy use
increases. Estimates for total energy use are 290 million kw-hr/yr of
electricity, 6,900 billion Btu/yr of natural gas, and 3,000 billion
Btu/yr of steam. This equates to 13,000 TJ/yr (2.1 million BOE/yr).

C. Cost Impacts

Cost impacts include the capital costs of new control equipment,
the cost of energy (supplemental fuel, steam, and electricity) required
to operate control equipment, and operation and maintenance costs.
Generally, cost impacts also include cost savings generated by reducing
the loss of valuable product in the form of emissions. Average cost
effectiveness P($/Mg of pollutant removed) is also presented as part of
cost impacts. Average cost effectiveness is determined by dividing the
annual cost by the annual emission reduction.
For the final rule, it is estimated that total capital costs for
installation of controls would be $450 million (1989 dollars), and
total annual costs of this control, excluding the cost savings
attributable to equipment leaks, would be $160 million (1989 dollars)
per year (see table 4). Because of the EPA's deferral of a final
decision on control of medium-sized storage vessels at existing
sources, as discussed in section III.B.3 of this preamble, the cost
impacts for storage vessels, and consequently the total cost impacts,
may be slightly overstated. The estimated cost of the monitoring,
recordkeeping and reporting requirements for the rule is $70 million/
yr. The total nationwide annual cost of this rule is, therefore, $230
million/yr.
It is expected that the actual compliance cost of the rule would be
less than those presented, but it is not possible to quantify the
amount. This is because cost estimates for some kinds of emission
points were made assuming a separate control device would be
constructed for each emission point. In reality, some operators will
duct emissions from several of these emission points to a common
control device, upgrade an existing control device, use other less
expensive control technologies, implement pollution prevention
technologies, or use emissions averaging. Additionally, owners or
operators of sources may develop more efficient monitoring and
recordkeeping systems. All of these options would reduce the estimated
costs while achieving the same emission reductions. The effect of such
practices on the national costs could not be estimated because the
ability to use any of these practices is highly site-specific and data
were not available to estimate how often the lower cost compliance
practices could be utilized.

D. Economic Impacts

Because many SOCMI chemicals are used as raw materials in the
production of other SOCMI chemicals, the economic impact analysis
looked at cumulative costs of control for each of the SOCMI chemicals
listed in subparts F and H. About 94 percent of the chemicals are
estimated to have a production cost increase of less than 10 percent;
more than 88 percent have cost increases less than 3 percent.
Approximately 6 percent of the chemicals analyzed incur a cost increase
of over 10 percent. Almost all of the chemicals with a product cost
increase exceeding 10 percent have annual national production of less
than 10 million kilograms (11,000 tons) and are therefore low volume
chemicals. [Two-thirds of the SOCMI chemicals have production over 10
million kilograms (11,000 tons).]
Market analyses for a subset of 21 of the chemicals estimated price
increases from 0.1 percent to 3.9 percent and quantity decreases from
0.1 percent to 4 percent. The market analyses lead to the conclusion
that percentage quantity decreases will be less than the percentage
cost increases due to the regulation. The market analyses indicate that
severe disruption of the industry is an unlikely result.
The diversity of chemical producers (most sources are involved in
the production of several chemicals) decreases the likelihood of plant
closure as a result of the regulation. A more likely consequence of the
regulation is a change from a chemical manufacturing process with a
higher cumulative control cost to a process with a lower control cost.
The impact for the low volume chemicals is the most uncertain. The
cost estimates for these chemicals involve more uncertainty and, in
many cases, industry profile information specific to the manufacturers
of these chemicals was not available. Many of the low volume chemicals
can be considered specialty chemicals. Generally, there is a lack of
viable substitutes for specialty chemicals. In addition, the production
cost of specialty chemicals is usually only a small portion of the cost
of the final goods made with the specialty chemical. For these two
reasons, a price increase for a specialty chemical is less likely to
lead to a business closure or a production cutback than a price
increase for a large volume chemical. This decreases the likelihood of
large quantity impacts or closures.
The RIA addresses the benefits, costs, and economic impact of the
regulation. Because benefits could only be addressed qualitatively, the
RIA is not able to provide guidance as to which regulatory option
optimizes net benefits. However, the RIA does summarize the types of
benefits associated with the reduction of HAP's, VOC's, and particulate
matter formed from VOC's.

V. Summary of Significant Comments and Associated Changes to the
Proposed Subparts F and G

A. Selection of Source Category and Source

1. Definition of SOCMI
Public comments have indicated confusion regarding the definition
of the source category covered by the HON. Several commenters
misinterpreted the definition to include activities that were not
intended to be regulated with this rule such as marine vessel loading
and refinery processes. Thus, the commenters asserted that the proposed
rule contained too many exemptions and loopholes. The commenters
concluded that the EPA should broaden the scope of the HON.
Section 112(c) of the Act requires the EPA to publish a list of all
categories of major sources of listed HAP's (and such categories of
area sources as the Administrator determines warrant regulation), then
to establish rules for each of these categories of sources of HAP
emissions. As such, the HON was not intended to require controls for
all operations in the chemical industry. Rather, the HON sets section
112(d) standards for the SOCMI source category. The SOCMI source
category includes only the part of the chemical industry that produces
the major industrial chemicals. Other parts of the chemical industry
use SOCMI chemicals to produce pesticides, agricultural chemicals,
pharmaceuticals, polymers, and specialty chemicals. These operations
are substantially different than the SOCMI and were outside the scope
of the impact analysis for the HON. Accordingly, these other segments
of the chemical industry are separate source categories, and will be
subject to separate MACT or GACT standards at a later date.
The EPA acknowledges that some integrated facilities will have
operations from multiple source categories on the same plant site
(e.g., refinery units, SOCMI production, and pesticide production).
However, to include all emission points at these facilities in the
scope of the HON is inappropriate because it is not consistent with
Congressional intent to regulate categories of HAP emissions. Further,
such an undertaking would make implementation of the rule an
insurmountable task. Instead, the HON provides comprehensive coverage
of the emissions of 112 organic HAP's from five kinds of emission
points in 385 SOCMI production processes. Emissions from processes in
other source categories will be covered by separate MACT standards. In
conclusion, the EPA does not believe it would be practical or
appropriate to broaden the applicability of the HON, as suggested by
some commenters, to include emissions from other source categories.
In previous rules and in the proposed HON, the EPA defined the
SOCMI source category with lists of chemical products. In the proposed
HON, there were two lists of SOCMI chemicals. One listed chemicals that
would be subject to subpart G and the other listed chemicals that would
be subject to subpart H. The two differed because the subpart H list
had been agreed to by the negotiating committee before all technical
analyses were complete.
Commenters suggested simplifying the applicability of the HON by
making the lists identical or by combining them into a single list.
Other commenters asserted that there were non-SOCMI chemicals (e.g.,
phthalate esters) on the proposed lists and that these chemicals should
be removed from the final rule.
The EPA agrees with the commenters that the applicability of the
rule will be clearer if there is only one list of SOCMI chemicals.
Thus, the EPA has combined the two lists and placed the resulting list
in table 1 of subpart F of part 63.
The EPA re-evaluated several chemicals that some commenters had
claimed were not SOCMI chemicals. In several cases the EPA disagreed
with the commenters because the chemicals met the criteria that EPA has
used to define the SOCMI. However, the EPA agreed with the commenters
regarding phthalate esters. These chemicals are primarily used as
plasticizers, not as building blocks for other chemical manufacturing,
and will be regulated under a separate source category called
``Phthalate Plasticizer Production.'' Because the production of these
chemicals will be covered by a future section 112(d) standard, the EPA
felt that it would be inappropriate to include them under the HON.
Thus, phthalate esters were deleted from the list of SOCMI chemicals in
the final rule.
The EPA added a chemical to the HON SOCMI list that had previously
been listed as a separate source category. The dodecanedioic acid
process shares equipment with an adiponitrile process which is subject
to the provisions of the HON. The EPA determined that it would be more
appropriate to regulate production of dodecanedioic acid as part of the
HON rather than prepare a separate standard. Thus, this chemical has
been added to the list of SOCMI chemicals in the HON.
Several commenters have alleged that the applicability provisions
in the proposed HON are confusing, especially when applied to plant
sites with integrated operations. To address the confusion, the EPA has
clarified the provisions in the final rule to simplify the
determination of applicability for facilities with integrated
operations. Several commenters suggested that the term ``chemical
manufacturing process'' be clarified regarding where the coverage of
the HON begins and ends. The commenters described situations where:
(1) Unit operations produce a SOCMI chemical as part of an overall
non-SOCMI process;
(2) Solvent is recovered or reclaimed;
(3) Unit operations, storage vessels, and transfer racks are shared
by two or more processes; and
(4) The intended product is less than a by-product on a mass basis.
In the final rule, the EPA has changed the term ``chemical
manufacturing process'' to ``chemical manufacturing process unit'' and
provided additional clarification on the boundary of a process subject
to the HON. The term is now defined as follows:

Chemical manufacturing process unit means the equipment
assembled and connected by pipes or ducts to process raw materials
and to manufacture an intended product. For the purpose of this
subpart, chemical manufacturing process unit includes air oxidation
reactors and their associated product separators and recovery
devices; reactors and their associated product separators and
recovery devices; distillation units and their associated distillate
receivers and recovery devices; associated unit operations; and any
feed, intermediate and product storage vessels, product transfer
racks, and connected ducts and piping. A chemical manufacturing
process unit includes pumps, compressors, agitators, pressure relief
devices, sampling connection systems, open-ended valves or lines,
valves, connectors, instrumentation systems, and control devices or
systems. A chemical manufacturing process unit is identified by its
primary product.

Additionally, the final rule provides a comprehensive assignment
procedure for distillation units, storage vessels, and transfer racks
that are shared among processes. This assignment procedure is based on
the predominant use of the equipment. The EPA has also clarified the
term ``source'' by consolidating the definition into two adjacent
paragraphs and wording it more in terms of equipment having specific
functions. These and other clarifications should remove the confusion
on the limits of a chemical manufacturing process unit subject to the
HON.
Commenters also asserted that the proposed definition of ``flexible
operation unit'' was inadequate because it addressed only feedstock
changes, and not operating changes to accommodate different products or
specifications. Because changes in these units could be frequent, the
commenters suggested basing applicability on the previous year's
production.
In the final rule, the EPA has changed the definition of ``flexible
operation unit'' to include operating changes. Additionally, the EPA
reevaluated the proposed requirement that a flexible operation unit
would be subject to the HON only during times when the unit was
producing a SOCMI product. The EPA decided that, due to the frequent
product changes associated with flexible operation units, such a
provision could complicate compliance determinations for sources and
enforcement agencies. The EPA considered the commenters' suggestion to
base applicability on the previous year's production but decided
against this because the year preceding promulgation of the final rule
might not have been representative of typical operation of the unit.
Therefore, in the final rule flexible operation units are assigned to a
specific chemical manufacturing process unit based on the anticipated
use of the unit. For existing sources, assignment is based on the
expected use over the first five years following promulgation, and for
new sources, assignment is based on expected use in the first five
years after start-up.
2. Definition of Major Source
The EPA received a number of comments regarding a source's
potential to emit. The EPA's policy on potential to emit is enunciated
in the General Provisions. The reader is directed to those provisions
for guidance.
Public comments have indicated confusion on the applicability of
the HON to a SOCMI chemical manufacturing process unit at a plant site
where the predominant activity is part of another source category
(e.g., a petroleum refinery). Some commenters pointed out that the
permit rule (40 CFR 70.2) narrowed the basis for determination of major
source status to include only the emission points within a single two-
digit SIC code. The commenters argued that this change would mean that
the HON would apply only if a source was major due to its SOCMI
processes. In other words, if the SOCMI processes at a source did not
exceed the 10/25 tons per year HAP emission threshold, then the HON
would not apply.
The EPA maintains that, although 40 CFR 70.2 defines major source
for the purpose of permitting, it does not alter the statutory
definition under section 112. The permit rule applies to sources
subject to a section 112(d) standard regardless of whether they are
major sources as defined by 40 CFR 70.2.
The EPA's position remains that if a plant site is a major source
within the section 112 definition, the HON applies to the HAP-emitting
SOCMI processes, and that the applicability of the HON to the SOCMI
portion of the plant site is not limited by the principal activity at
the site. This is consistent with the intent of the Act to regulate
categories of HAP emission sources. The part 70 definition may result
in more than one permit being issued for a major source of HAP
emissions, but does not affect the applicability of MACT standards.
3. Exclusion of Area Sources
In the preamble to the proposed HON, the EPA requested information
on the existence and characteristics of any area sources in the SOCMI
in order to determine if a separate MACT standard should be prepared.
Because the comments did not indicate any reasons to develop an area
source standard, the EPA maintains that the HON applies to major
sources only. Area sources are not subject to the HON.
4. Determining New Source Status
The EPA received a number of comments regarding the process for
determining if new or existing source requirements would apply to a
particular SOCMI emission point or process unit. In response to those
comments the EPA has clarified the relevant section of subpart F. The
requirements and definitions used by the HON to distinguish new and
existing sources are consistent with section 112(a) and the related
components of the General Provisions. As a result, the following could
be subject to the HON's requirements for new sources: (1) Chemical
manufacturing process units constructed after the date of proposal of
the HON (December 31, 1992); (2) existing sources reconstructed after
that date; and (3) ``greenfield'' HON chemical manufacturing process
units that constitute all or part of a major source constructed after
that date. (New source requirements would not be triggered by the
addition of an individual emission point, such as a storage vessel.) In
addition, a newly constructed chemical manufacturing process unit must
also have the potential to emit major quantities (10 tons per year of
any HAP or 25 tons per year of any combination of HAP's) in order to be
subject to new source requirements for the HON. Thus, any change or
addition to an existing SOCMI plant site must meet the same three
criteria as a ``greenfield'' plant to be considered a new source. The
EPA selected this approach for determining what is subject to new
source requirements to avoid providing an incentive for SOCMI owners
and operators to construct processes as area sources. Also, EPA wanted
to ensure that new sources built at existing plant sites are subject to
the same requirements as new sources that are ``greenfield'' sites.
Additions to an existing plant that do not meet the requirements of
being a chemical manufacturing process unit and do not have the
potential to emit major amounts, will be subject to existing source
requirements.
B. Selection of Pollutants
In selecting the HAP's that would be regulated by the HON, the EPA
started with the list of 189 HAP's in the Act. Because the HON was
intended to reduce emissions from organic chemical manufacturing, the
EPA studied the processes used to manufacture SOCMI chemicals and
narrowed the list to those organic HAP's that would be emitted from
SOCMI processes.
In the proposed rule, there were two lists of organic HAP's--one
that applied to subpart G and another that applied to subpart H. The
lists differed by 37 HAP's because the subpart H list had been agreed
to by the negotiating committee before all technical analyses were
complete. These technical analyses indicated that 37 of the organic
HAP's on the list approved by the committee should be removed from the
list because they would not be emitted from SOCMI production processes.
In public comments received on the proposed rule, it was suggested that
the EPA combine the two lists to simplify implementation of the rule.
The EPA decided that it was appropriate to include only one list of
organic HAP's in the final rule. The list is located in table 2 of
subpart F and contains 112 compounds. Keeping the shorter of the two
proposed lists will not result in greater emissions because the
additional 37 HAP's on the longer list would not be emitted from SOCMI
processes. Also, because the non-SOCMI processes in subpart I are only
subject to the standard for the designated pollutants, combining the
organic HAP lists does not affect emissions from those processes.

C. Selection of Rule

1. Floor Determination
a. Background on impacts estimates. As explained in the preamble to
the proposed rule (57 FR 62621), the EPA developed the information on
control costs and emissions for SOCMI using a model emission point
approach to represent the broad range of characteristics of SOCMI
operations. The EPA elected to use the model emission point approach in
part because of the limited time provided by the statutory requirement
to regulate 40 source categories (which legislative history states
should be the priority elements of the chemical industry) by 1992 and
to establish regulations for all initially listed source categories by
2000. Because a generic model emission point approach allows one
regulation to cover a large number of different chemical processes, it
was considered more resource efficient and the only practical way to
develop regulations on the schedule mandated by Congress.
The impacts estimation methodology involved three steps: (1)
Development of a data base characterizing the SOCMI, (2) development
and assignment of model emission points for each kind of emission
point, and (3) calculation of emissions and control impacts. The
characterization of the SOCMI primarily involved identifying the
specific routes, reactants, and process technologies used to produce a
chemical and the corresponding SOCMI chemical manufacturing process
units. In addition, information on existing State and Federal
regulations was compiled for each kind of emission point to determine
the baseline control requirements applicable to SOCMI chemical
manufacturing process units.
Model emission points were developed to represent each kind of
emission point in the SOCMI. The models were developed to emphasize
those characteristics that most influence emissions, control costs,
energy needs, and secondary environmental impacts. These models were
applied to individual chemical manufacturing process units in the SOCMI
data base using decision rules based on the level of information in the
data base and the specificity of a given model. These models are
representative of average, representative, or typical emissions for the
specific process or reaction type. Thus, the estimates do not reflect
actual emissions that would occur at any particular chemical
manufacturing process unit because process design and operation
characteristics vary from plant to plant.
Estimates of existing controls were developed by compiling
information in existing state and Federal regulations applicable to
SOCMI processes. In this analysis, the EPA used data on the control
requirements in existing State and Federal regulations to identify
those emission points that must be controlled in the absence of this
rule and to identify the required controls. It was assumed that all
chemical manufacturing process units would be in compliance with
applicable air pollution regulations.
The data base and model emission points used to estimate the
impacts of the HON are based on published literature and information
that the EPA has collected during other rulemaking efforts including
NSPS for air oxidation processes, distillation operations, reactor
processes, volatile organic liquid storage, and equipment leaks; and
NESHAP for vinyl chloride and benzene. Some additional information was
obtained on wastewater operations and transfer loading operations by
requesting it from the industry under authority of section 114 of the
Act.
In development of the proposed rule, the EPA recognized that the
data base developed to provide estimates of nationwide costs and
emission reductions did not provide site-specific emission and control
information and these limitations needed to be considered in the
determination of the floor for the category. The EPA developed the
floor from an analysis of the information for each kind of emission
point. The information the EPA used in determining the source-wide
floor consisted of the estimates of the number and characteristics of
the model emission points, the emission control requirements currently
in place for each point based on information available to the EPA, and
the expected control efficiencies for the control technology. To
determine the source-wide floor for existing sources at proposal, the
EPA examined the supporting information to identify the emission
characteristics of the emission points which had at least 12 percent of
the points controlled by the reference control technology. This
analysis was done for each kind of emission point. The characteristics
used to identify groups of emission points were physical parameters
such as flow rate, HAP concentration, and vapor pressure. The source-
wide floor was determined by the combination of the control levels for
all four kinds of emission points.
A similar method was used to determine the source-wide floor for
new sources. For each kind of emission point, the characteristics of
the smallest emission point controlled by the reference control
technology were identified as the means for determining the best
controlled similar source. Again, the source-wide floor was determined
by the combination of control levels for all emission points.
b. Public comment issues. Commenters raised three basic issues on
the approach used to determine the floor for SOCMI sources:
(1) Information used to predict existing control understated actual
control present;
(2) The methodology used to estimate the floor overstated the
floor; and
(3) The ranking criterion used for process vents introduced cost
considerations into the floor.
Data base understates actual control. A number of commenters argued
that the approach, or the information, the EPA used understated actual
control in the SOCMI. Some of these commenters thought that the EPA
should have gathered site-specific data on emissions and controls to
properly establish the floors. Other commenters argued that the EPA
should have used state air toxics and new source review permits to
determine actual control levels, since many air toxics programs are
implemented through permit programs.
While the EPA would have preferred to have developed site-specific
information on emissions and controls for processes subject to this
rule, it was not possible to do so given the deadlines applicable to
this rulemaking. Section 112(e)(1) of the CAA required that the EPA
promulgate emission standards for at least 40 source categories and
subcategories by November 15, 1992. Having failed to meet that
statutory deadline, the EPA entered into a consent decree requiring the
promulgation of the HON by February 28, 1994. Neither that deadline nor
the statutory deadline for the rules covering 40 source categories and
subcategories could have been met if the EPA used the alternative
approach suggested by the commenters. The EPA's past experience in
developing the data base for the previous section 112 program and for
NSPS standards demonstrates the great length of time necessary to
develop and analyze the data for development of emission standards to
control emissions from the SOCMI. The data base developed for this
rulemaking used the results of more than 10 years of data gathering and
analysis of SOCMI sources. Developing an entirely new data base as
suggested by the commenters is expected to require anywhere from 4 to
10 years depending on the degree of evaluation of performance and
whether permits are reviewed for all SOCMI sources. Consequently, the
EPA elected to use information readily available to it to determine the
floor for the SOCMI standard under section 112(d) of the CAA. In light
of the EPA's prior experience with regulation of the SOCMI, the EPA
believes that this decision was entirely reasonable.
Furthermore, the EPA does not believe that the method used by the
EPA to determine existing control levels and the floor understated
actual control levels in SOCMI. The EPA holds this view because other
assumptions used in the analysis introduced a positive bias. Examples
of assumptions that would introduce an upward bias to the analysis
include: (1) All sources are in compliance with all applicable control
requirements for air emissions; and (2) sources would be in compliance
with recently established requirements such as 40 CFR part 61 subpart
BB. Thus, the EPA believes that taken as a whole the uncertainties
should balance out, and the control level is not understated. It should
be noted also that other commenters thought that the floor was
overstated.
Methodology overstated floor. In contrast, another group of
commenters argued that the point-by-point approximation of the floor
introduced a positive bias in the source-wide floor. These commenters
explained that the assumption that the best controlled of each kind of
point are co-located is invalid. They noted that in practice different
sources have the better controls on the different kinds of points.
These commenters argued that the EPA should have considered this bias
in decisions to require control beyond the floor. Some of these
commenters also questioned inclusion of requirements in recent NESHAP
in the assessment of the floor control and the estimates of control
efficiency achieved by some control devices. None of the commenters
provided data or suggested methodologies that could be used to improve
the EPA data base to develop better estimates of the source-wide floor.
The EPA maintains that, given the uncertainties in the data base,
the procedure used to determine the floors in the proposal (and in this
final rule) is a reasonable approach to the determination of the floor.
As explained above, the EPA could not develop actual site-specific data
in the time available for this rulemaking. Thus, the EPA had to rely on
existing data sources to develop model emission points characteristics
for sources subject to this rule. Where data were available for the
specific process, the model emission points characteristics reflected
average or representative operations for the specific process. In cases
where no data were available for a specific process, the model emission
point characteristics were derived from average characteristics for the
generic reaction type (e.g., hydrogenation, halogenation, etc.). Thus,
the estimates cannot be viewed as reflecting actual emissions and
controls at any particular process unit or plant site. The EPA
considered whether to develop floors using estimates of site-specific
emissions and controls and rejected that approach as introducing
additional assumptions and such large uncertainties as to render the
analysis meaningless. For example, due to incomplete information, it is
probable that not all process units at each plant site were properly
identified. In fact, locations of some chemical production processes
are unknown. Site specific differences in process unit design could not
be taken into account in assigning model emission points and baseline
control levels. Thus, there is uncertainty about the existence of any
particular emission point, as well as its assigned emission and control
level at any particular plant site. Furthermore, independent assignment
procedures were used for each kind of emission point. In consideration
of these factors, the EPA believes that the uncertainties introduced by
the assumptions made in assigning emission point characteristics to
specific sites are so large as to undermine the validity of the
analysis. The EPA believes that the approach it used of developing
point-by-point approximations of the source-wide floor was the most
appropriate use of the available data base to determine the floors.
Moreover, the EPA does not believe that its methodology, when all
aspects are considered, did overstate the source-wide floor. While the
assumption of collocation of the best controlled points does introduce
an upward bias in the analysis, there are other aspects of the analysis
that work in the opposite direction. For example, the use of
information from State regulations instead of site-specific control and
operation information would be likely to understate the degree of
control present in some sources. As previous commenters noted, site-
specific controls that may have been included in new source permits or
applied voluntarily could not be accounted for in the data base. Thus,
the EPA expects these factors are likely to balance out. It should be
noted also that other commenters thought that the floor was
understated.
The EPA also believes that its choice of methodology was reasonable
since it provided additional assurance that, not withstanding the
uncertainties inherent in the data base, the floor determined by the
EPA would be no less stringent than the actual source-wide floor. As
some of the uncertainties present, such as the reliance on analyses of
State regulations rather than actual permitted levels of emissions,
would lead to a less stringent floor in the absence of countervailing
factors, the EPA believes it was reasonable to provide a safety factor
by determining the floor on the basis of a point-by-point approximation
that assumed the co-location of the best-controlled points.
In any event, even if the EPA's point-by-point methodology may have
overstated the floor, such an overstatement does not invalidate the
emission standard since the overall source-wide standard exceeds the
floor determined by the EPA.
A second issue raised regarding the methodology and information was
whether it was appropriate to consider the Benzene Transfer (40 CFR
part 61, subpart BB) or Benzene Waste (40 CFR part 61, subpart FF)
NESHAP as applicable control requirements. These commenters questioned
whether section 112(d)(3)(A) of the Act required that these control
requirements not be considered in the floor determination. (See section
II.C of this notice.)
The EPA maintains that it was appropriate to consider the control
requirements of Benzene Transfer since these controls were required
more than 30 months before promulgation of this rule. Furthermore,
information collected in the section 114 surveys shows that a few
sources were steam stripping wastewater containing chemicals with
volatilities similar to benzene. Because the new source floor is
determined based on the best controlled similar source, the
requirements were included in the determination of the floor for new
sources. In addition, the Vinyl Chloride NESHAP, which was issued in
1977, also requires treatment of wastewater streams containing greater
than 10 ppm. Consideration of the Benzene Waste NESHAP did not affect
the existing source floor because fewer than 1 percent of the
wastewater streams in the HON data base are expected to be subject to
Benzene Waste NESHAP control requirements, and the floor is determined
to be no control for wastewater streams at existing sources.
Ranking criterion used for process vents analysis. Some commenters
thought that the EPA had introduced cost considerations into the floor
by the ranking procedure used for process vents. These commenters noted
that considering cost in determining the floor was contrary to
Congressional intent.
The EPA does not believe that the procedure used to rank process
vents did introduce cost into the determination of characteristics of
process vents controlled at the floor. The reasons EPA holds this view
can be best explained by restating the process used and comparing it to
other ways of analyzing the process vent data.
To determine the source-wide floor, the EPA ranked the data base
for the specific emission point by a characteristic that would affect
the likelihood for control. For existing sources, the proposed floor
was defined as the emission characteristics where at least 12 percent
of the points were controlled by the reference control technology. For
new sources, the proposed floor was defined by the characteristics of
the point with the smallest emission rate that was controlled. By
analyzing the ranked data, it could be determined that emission points
with certain physical characteristics are currently controlled, while
emission points with other characteristics are not controlled. Storage
vessels, for example, were ranked by vapor pressure because vapor
pressure is one of the three major factors that influence emissions and
potential emission reductions. The ranking clearly showed that vessels
storing liquids above a certain vapor pressure are controlled at the
best controlled sources, so the source-wide floor would require control
of such vessels; whereas, vessels storing liquids with lower vapor
pressures are not currently controlled and would not require control
under the source-wide floor.
Process vents were ranked using cost effectiveness of control (or
TRE) as a surrogate measure because this can be used to reflect all
possible combinations of various factors that affect emission rates and
likelihood of current control (flow rate, HAP concentration, net
heating value, and corrosion properties). Use of a single criterion of
cost effectiveness results in a more easily understood parameter and is
consistent with the format of the process vent provisions. The cost-
effectiveness values were used only to rank the vents in the data base
and as a characteristic to identify controlled vent characteristics
(similar to the way in which vapor pressure was used to identify the
characteristics of the best controlled storage vessels). In determining
the process vent component of the source-wide floor, no judgements were
made about the reasonableness of the characteristics of the controlled
vents.
Because of the opinions expressed by commenters, the EPA also
reevaluated the process vent control level associated with the floor
using emissions as the ranking parameter. Emissions correlate with
likelihood of control, but the correlation is weaker because other
factors (such as concentration and flow) also influence it. The process
vent data base was ranked by vent from lowest to highest emission rate.
The characteristics of the process vent where at least 12 percent of
the process vents are controlled is 64 Mg/yr (71 tons/yr) and the cost-
effectiveness value is $1,620/Mg ($1,460/ton). Thus, essentially
identical results are obtained by both ranking procedures.
As discussed in section V.C.1.c of this preamble, comment has been
requested in other rulemakings on the meaning of the statutory language
``the average emission limitation achieved by the best performing 12
percent of the existing sources.'' Because of this, the average
characteristics of the top 12 percent of the process vents were
determined using the emissions ranking of the data base. This analysis
showed that vents with 27 Mg/yr (30 tons/yr) emissions would have to be
controlled at the floor. When these average characteristics are used to
derive the comparable TRE value, the result is about $2,900/Mg ($2,600/
ton). The discussion of the control levels selected for existing
process vents demonstrates that in this case the interpretation of the
statutory floor language is not relevant. This is the case because,
when cost and environmental and energy impacts are considered, as
required by the statute, the appropriate control level for process
vents is equal to the more stringent floor calculation. Thus any
ambiguity in the floor language and methodology does not affect the
regulatory alternative selected for this rule.
Analysis of expected control efficiency at floor for storage
vessels at existing sources. Several commenters questioned the
assessment of the performance capabilities of actual controls on
existing storage vessels. As discussed in section V.C.3 of this
preamble, the performance was reassessed considering the comments. This
reevaluation determined that for existing storage vessels best control
systems are:
(1) A 90-percent efficient control device; or
(2) An IFR or EFR with a continuous seal, but without controlled
fittings.
Also in the reexamination of existing control level, it was
determined that an error had been made in assignment of applicability
of the Benzene Storage NESHAP (40 CFR part 60, subpart Y) to storage
vessels in the data base. Upon examination of the data base, it was
found that some vessels had been assumed to be controlled due to
subpart Y, but the liquids stored did not meet the applicability
criteria of subpart Y. The Benzene Storage NESHAP applies only to
vessels storing liquids that meet the specifications of ASTM D-836-84
for industrial grade benzene, or refined benzene -485, -535, or -545.
After correction of the data base, 2 percent of the small vessels, 6
percent of the medium vessels, and 12 percent of the large vessels were
found to be controlled. The effect of this on the assessment of the
floor for existing sources is discussed in the next section of this
preamble.
c. Interpretation of statutory language for existing source floors.
In recent Federal Register notices of proposed rulemakings (Pulp and
Paper and Chromium Electroplating), the EPA has requested comment on
the EPA's interpretation of the meaning of ``the average emission
limitation achieved by the best performing 12 percent of the existing
sources'' and the methodology for determining the MACT floor. Comments
have been specifically requested in these proposed rulemakings on
whether the MACT floor for existing sources should be set at the 88th
percentile or at the level reflecting the median or mean level of
control achieved by the best performing 12 percent of sources.
Questions have been raised on how the methodology used in determination
of the floors for the HON relates to floors being determined using
alternative procedures.
With the exception of process vents and medium-sized storage
vessels, the two methodologies result in the same control level for the
floor. This results because for most of the HON data base there is
little variation in the physical characteristics of the emission points
in the top 12 percent of the population. The average or mean is equal
to the median value of the distribution as well as the 88th percentile
value. Thus, for this data base, whether the floor is determined using
the characteristics of the median, mean or 88th percentile does not
matter. The assessment of the average characteristics of the best
performing 12 percent of each kind of point is described below.
As described earlier in the discussion of the process vent ranking
criterion, the average characteristics of the top 12 percent of the
process vents was equivalent to about $3,000/Mg ($2,700/ton). The
characteristics of process vents where at least 12 percent are
controlled by the reference control technology is equivalent to $1,500/
Mg ($1,360/ton).
For small storage vessels, the revised data base showed that only 2
percent of the vessels were controlled. Thus, the median
characteristics of the top 12 percent of the vessels is no control.
This control level is the same as the level predicted by
characteristics where at least 12 percent are controlled.
As mentioned earlier, the EPA is not taking final action at this
time concerning the provisions applicable to medium storage vessels.
The reason is to take comments on the difference in the floor
determination that would result from the application of the two
interpretations discussed above. For medium storage vessels, 6 percent
of the vessels are controlled with either a 90-percent efficient
control device or an IFR or EFR with a continuous seal. All of the
controlled medium-sized vessels contained liquids with vapor pressures
of 13.1 kPa (1.9 psia). The arithmetic average, or mean characteristics
of the top 12 percent of the medium vessels would not represent the
performance of any known technology. If the EPA used the median as the
average for these vessels, however, the floor determined by the average
characteristics of the top 12 percent of the sources would require
control of vessels storing liquids with vapor pressures of 13.1 kPa
(1.9 psia) by either a 90-percent efficient control device or an IFR or
EFR with a continuous seal. This is the same vapor pressure that was
identified at proposal. With the revised data base, the floor
determined by the characteristics where at least 12 percent of the
points are controlled would require no control.
For large storage vessels, the revised data base showed that 12
percent of the vessels were controlled and essentially all controlled
vessels in the top 12 percentile of each size range of vessels stored
liquids with vapor pressures of 13.1 kPa (1.9 psia). So the median or
average characteristics of the top 12 percent of the vessels is the
same as the characteristics where at least 12 percent of the vessels
were controlled. Both procedures show the floor to require control of
vessels containing liquids with vapor pressures of 13.1 kPa (1.9 psia)
and higher.
The data base information for transfer racks also showed that all
controlled racks loaded liquids with vapor pressures of 10.3 kPa (1.5
psia) and no racks loading liquids with vapor pressures less than 10.3
kPa (1.5 psia) were controlled. Thus, the two procedures would predict
the same control requirements for the floor.
Fewer than 1 percent of the wastewater streams in the HON data base
were expected to be subject to regulations that required control of air
emissions. Thus, for wastewater the average of the top 12 percent of
streams would represent no control since the median stream is not
controlled and the arithmetic average of the top 12 percent of the
sources does not correspond to any known control measure. The
alternative procedure for determining the floor also shows that the
floor would be no control.
In summary, the outcome of the debate concerning the appropriate
interpretation of the floor language is not pertinent to the final
provisions for process vents, transfer operations, wastewater, small
storage vessels, and large storage vessels. Under either
interpretation, the floor would not alter the regulatory decisions
contained in this rule for those emission points because the standard
is, on the basis of cost and environmental and economic impacts, set at
or above each component of the floor regardless of which interpretation
is chosen. In the case of medium storage vessels, however, the EPA is
deferring final action pending the receipt and review of additional
public comment.
2. Alternative Control Levels
a. Stringency of standard. The proposed standard would have
required control of emission points with characteristics meeting the
criteria listed in table 5 through the use of reference control
technologies. The EPA selected the proposed control requirements from
the alternatives listed in tables 5 and 6 of the proposed notice of
rulemaking (57 FR 62629 and 62630). These alternatives differed only in
the number of emission points that would be controlled by the reference
control technology. The proposed requirements were selected
considering: (1) Magnitude of the emission reduction; (2) cost of the
emission reduction; (3) economic impacts and feasibility; (4)
consistency with previous decisions; (5) other non-air quality health
and environmental impacts; and (6) energy requirements. It was the
EPA's judgement that the proposed requirements would be achievable at
reasonable cost, and with reasonable economic and other impacts.
The proposed control requirements were expected to significantly
reduce HAP emissions from SOCMI sources. The proposed standard was
estimated to reduce HAP emissions from the four kinds of emission
points by 422,000 Mg/yr (464,000 tons/yr) from existing and new
sources. At proposal the total nationwide annual cost associated with
this emission reduction was estimated to be about $182 million/yr, with
$48 million/yr of this cost associated with the monitoring,
recordkeeping, and reporting requirements.
Public comments on the proposed control levels were polarized with
industry groups arguing the proposed standard was too stringent and
environmental and public interest groups arguing the standard did not
require sufficient control. Commenters who argued that the standard was
too stringent thought that in the decisions to go beyond the floor the
EPA should have considered the bias introduced by the procedure used to
determine the floor. Several commenters suggested alternative criteria
which they considered to be more appropriate. These commenters,
however, did not provide supporting rationale for their preferences.
Commenters representing environmental and public interest groups
expressed concern that the proposed standard did not require control of
all emissions, but allowed a large amount of emissions to go
uncontrolled. Several State and local regulatory agency commenters
thought that, at a minimum, the standard should have required control
comparable to existing control requirements for VOC, such as the NSPS
standards for SOCMI process vents (40 CFR part 60, subparts III, NNN,
and RRR).
The EPA considered all of the comments in selecting the final
control requirements of the standard. In considering these comments,
the EPA viewed the concerns in the context that the positions and
concerns were diametrically opposed to one another. Thus, no response
could completely resolve the issues. The EPA's reexamination of the
control requirements of the standard and response to the commenters'
concerns is provided in the following paragraphs of this section of the
preamble.
The final regulatory alternatives for existing and new sources are
shown in tables 6 and 7.

[Note: Regulatory alternatives were developed using information
for the chemical processes that could be characterized sufficiently
to permit assignment of model emission points. The estimates
presented in tables 6 and 7 differ from the estimates summarized in
section IV of this notice because the estimates in section IV
include an extrapolation to account for processes that could not be
modeled.]

The only differences between these alternatives and the
alternatives at proposal are revisions made to the estimates of
wastewater emissions and control costs and the storage vessel control
costs, as discussed in sections V.C.3.b and V.C.3.d of this preamble.
The following discussion of the final selection of control levels
is limited to the primary factors that affected the decision. The
primary factors are the emission reduction, control cost, consistency
with other standards, and economic efficiency. Other factors such as
non-air environmental impacts (solid waste and water) and energy
impacts do not vary significantly among the alternatives. Consequently,
these factors are not discussed in this preamble. Readers should see
the proposed rulemaking (57 FR 62608) for the discussion of these other
factors.
(i) Process vents. In the final rule, the EPA selected Option 3
(TRE cost-effectiveness values of up to $3,000/Mg) as the basis for the
requirements for process vents at existing sources. The EPA's selection
of Option 3 for process vents was principally based on consideration of
the emission reductions, costs, and consistency with other standards.
Specifically, the control level required by this option will reduce
emissions by 2,000 Mg/yr (2,200 tons/yr) more than Option 2, upon which
the proposed requirements were based. This additional emission
reduction is estimated to cost approximately $4 million/yr more than
Option 2 or $2,500 for each additional Mg of emissions ($2,270/ton).
The EPA believes that the control required by Option 3 is
achievable considering the statutory criteria, for the following
reasons. First, EPA has received extensive comment on the proposed
rule. No commenters submitted data or arguments demonstrating that the
costs of the proposed range of options (Options 1 to 4) were
unreasonable. Second, the incremental cost effectiveness of Option 3
compared to Option 2 ($2,500/Mg [$2,275/ton]) is within the cost-
effectiveness values from recent decisions on other standards. Third,
the TRE format of the process vents provisions allows facilities the
flexibility to comply through changes in equipment or operations. As a
result, actual costs could be lower than estimated. Based on the above
considerations, the EPA judged that the control required by Option 3 is
achievable considering the statutory criteria.
Fourth, Option 3 would provide consistency between the HON and the
recently issued CTG for SOCMI process vents, which requires control of
vents with TRE cost-effectiveness values of $2,500/Mg of VOC ($2,270/
ton). Option 3 would also be consistent with the applicability criteria
for the three SOCMI process vents NSPS, which require control of vents
with TRE cost-effectiveness values of $3,000/Mg of VOC ($2,700/ton)
adjusted to 1989 dollars. The EPA believes that consistency among these
requirements would reduce administrative costs and implementation
difficulties for both EPA and permit authorities as well as industry.
An additional consideration in selection of Option 3 was public
comments that the requirements should be at least equivalent to the
requirements of the SOCMI NSPS and CTG.
In addition, Option 3 is consistent with one interpretation of the
statutory language on floors, and thereby arguably is the minimum
statutorily permissible level of control. However, based on the above
analysis, Option 3 would have been selected whether it was equal to or
above the floor.
More stringent control than Option 3 was not selected because the
EPA could not conclude, based on currently available information, that
the additional emission reduction warranted th

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Source: Frix Law Library, https://www.frixlaw.com/law-library/documents/fr%3A94-6043. Public record. Not legal advice.
